Two oxoperoxomolytxlenum(Ⅵ)complexes,MoO(O_2)(OCH_2CH_2)_2NH.H_2O(5)and MoO(O_2)(OCH(CH_3)CH_2)_2 NH(6)have been synthesized by the reaction of MoO_2(OCH_2CH_2)_2NH·CH_3OH(3)and MoO_2(OCH(CH_3)CH_2)_2NH(4)with t...Two oxoperoxomolytxlenum(Ⅵ)complexes,MoO(O_2)(OCH_2CH_2)_2NH.H_2O(5)and MoO(O_2)(OCH(CH_3)CH_2)_2 NH(6)have been synthesized by the reaction of MoO_2(OCH_2CH_2)_2NH·CH_3OH(3)and MoO_2(OCH(CH_3)CH_2)_2NH(4)with tert-butyl hy- droperoxide,and are active to epoxidize cyclohexene.展开更多
文摘Two oxoperoxomolytxlenum(Ⅵ)complexes,MoO(O_2)(OCH_2CH_2)_2NH.H_2O(5)and MoO(O_2)(OCH(CH_3)CH_2)_2 NH(6)have been synthesized by the reaction of MoO_2(OCH_2CH_2)_2NH·CH_3OH(3)and MoO_2(OCH(CH_3)CH_2)_2NH(4)with tert-butyl hy- droperoxide,and are active to epoxidize cyclohexene.
