Based on the experience and achievement of the＂China Digital Ocean＂, the classification plan for Marine data elements is made, which can be classified into five, including marine point elements, marine line elements...Based on the experience and achievement of the＂China Digital Ocean＂, the classification plan for Marine data elements is made, which can be classified into five, including marine point elements, marine line elements, marine polygon elements, marine grid elements and marine dynamic elements. In this paper, the technology of features and object-oriented method, a spatial-temporal data model is proposed, which can be applied in the large information system engineering like the ＂Digital Ocean＂, and this paper discusses the application of spatial data model, marine three-dimensional raster data model and relation data model in the building of Data Warehouse in ＂China Digital Ocean＂, and concludes the merits of these models.展开更多
Polychlorinated biphenyls （PCBs） were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteris-tics of P...Polychlorinated biphenyls （PCBs） were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteris-tics of PCBs and their gas/particle partitioning. The mean concentration of 26 PCBs （vapor plus particulate phase） （∑PCBs） was 19.116 pg/m^3with a standard deviation of 13.833 pg/m^3. Three most abundant conge-ners were CB-28, -52 and -77, accounting for 43.0% to∑PCBs. The predominance of vapor PCBs （79.0% to∑PCBs） in the atmosphere was observed.∑PCBs were negative correlated with the latitudes and inverse of the absolute temperature （1/T）. The significant correlation for most congeners was also observed between the logarithm of gas/particle partition coefficient （logKp） and 1/T. Shallower slopes （from ∑0.15 to ∑0.46, average ∑0.27） were measured from the regression of the logarithm of sub-cooled liquid vapor pressures （logpoL） and logKP for all samples. The difference of the slopes and intercepts among samples was insignifi-cant （p〉0.1）, implying adsorption and/or absorption processes and the aerosol composition did not differ significantly among different samples. By comparing three models, the J-P adsorption model, the octanol/air partition coefficient （KOA） based model and the soot-air model, the gas/particle partitioning of PCBs in the Arctic atmosphere was simulated more precisely by the soot-air model, and the adsorption onto el-emental carbon is more sensitive than the absorption into organic matters of aerosols, especially for low-chlorinated PCB congeners.展开更多
Colored dissolved organic matter(CDOM)is an important optically active substance in marine environment.Its biochemical conservatism makes it an important indicator to offshore pollution process.Monitoring the content,...Colored dissolved organic matter(CDOM)is an important optically active substance in marine environment.Its biochemical conservatism makes it an important indicator to offshore pollution process.Monitoring the content,composition,and diffusion process of CDOM is a good approach to analyze the terrestrial input,optical properties,and ecological environment of offshore areas.The spatiotemporal characteristics of CDOM around the Leizhou Peninsula were analyzed based on field observation data collected in the autumn 2020 and spring 2021,and an empirical inversion model of the ag(355)(absorption coefficient at 355 nm)and spectral slope(Sg)(g stands for gelbstoff/gilvin,which is called CDOM)based on Sentinel-3A ocean and land color instrument(OLCI)images was constructed.The results show(1)the order of average ag(355)value around the Leizhou Peninsula was east coast(0.503/m)>Qiongzhou Strait(0.502/m)>west coast(0.365/m);(2)the best band combinations of CDOM inversion in spring and autumn were(B4+B11)/B3 and(B7-B1)/B6(B stands for the band of spectral images),and the final inversion results are close to the measured results,indicating that the model has good accuracy;(3)the S_(g)value of the CDOM absorption spectrum was fitted to the hyperbolicexponential model.The fitting accuracy of the model was higher than those of the exponential model and the hyperbolic model,and the best S_(g)inversion model was constructed by selecting Sg(275-295)and Sg(250-295)in spring and autumn;(4)the spatial distributions of ag(355)and S_(g)were inverted,and CDOM in the waters around the Leizhou Peninsula originated from terrestrial organic matter carried by coastal aquaculture zones and runoff in the northeast Zhanjiang and the northern Beibu Gulf.展开更多
文摘Based on the experience and achievement of the＂China Digital Ocean＂, the classification plan for Marine data elements is made, which can be classified into five, including marine point elements, marine line elements, marine polygon elements, marine grid elements and marine dynamic elements. In this paper, the technology of features and object-oriented method, a spatial-temporal data model is proposed, which can be applied in the large information system engineering like the ＂Digital Ocean＂, and this paper discusses the application of spatial data model, marine three-dimensional raster data model and relation data model in the building of Data Warehouse in ＂China Digital Ocean＂, and concludes the merits of these models.
基金The Chinese Polar Environment Comprehensive Investigation and Assessment Programs under contract Nos 02-01,03-04,04-01 and 04-03the National Natural Science Fundation of China under contract No.21377032
文摘Polychlorinated biphenyls （PCBs） were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteris-tics of PCBs and their gas/particle partitioning. The mean concentration of 26 PCBs （vapor plus particulate phase） （∑PCBs） was 19.116 pg/m^3with a standard deviation of 13.833 pg/m^3. Three most abundant conge-ners were CB-28, -52 and -77, accounting for 43.0% to∑PCBs. The predominance of vapor PCBs （79.0% to∑PCBs） in the atmosphere was observed.∑PCBs were negative correlated with the latitudes and inverse of the absolute temperature （1/T）. The significant correlation for most congeners was also observed between the logarithm of gas/particle partition coefficient （logKp） and 1/T. Shallower slopes （from ∑0.15 to ∑0.46, average ∑0.27） were measured from the regression of the logarithm of sub-cooled liquid vapor pressures （logpoL） and logKP for all samples. The difference of the slopes and intercepts among samples was insignifi-cant （p〉0.1）, implying adsorption and/or absorption processes and the aerosol composition did not differ significantly among different samples. By comparing three models, the J-P adsorption model, the octanol/air partition coefficient （KOA） based model and the soot-air model, the gas/particle partitioning of PCBs in the Arctic atmosphere was simulated more precisely by the soot-air model, and the adsorption onto el-emental carbon is more sensitive than the absorption into organic matters of aerosols, especially for low-chlorinated PCB congeners.
基金Supported by the Key Projects of the Guangdong Education Department(No.2019KZDXM019)the Fund of Southern Marine Science and Engineering Guangdong Laboratory(Zhanjiang)(No.ZJW-2019-08)+3 种基金the High-level Marine Discipline Team Project of Guangdong Ocean University(No.002026002009)the Guangdong Graduate Academic Forum Project(No.230420003)the“First Class”Discipline Construction Platform Project in 2019 of Guangdong Ocean University(No.231419026)the Innovation Projects of Colleges and Universities in Guangdong Province(No.2021KQNCX028)。
文摘Colored dissolved organic matter(CDOM)is an important optically active substance in marine environment.Its biochemical conservatism makes it an important indicator to offshore pollution process.Monitoring the content,composition,and diffusion process of CDOM is a good approach to analyze the terrestrial input,optical properties,and ecological environment of offshore areas.The spatiotemporal characteristics of CDOM around the Leizhou Peninsula were analyzed based on field observation data collected in the autumn 2020 and spring 2021,and an empirical inversion model of the ag(355)(absorption coefficient at 355 nm)and spectral slope(Sg)(g stands for gelbstoff/gilvin,which is called CDOM)based on Sentinel-3A ocean and land color instrument(OLCI)images was constructed.The results show(1)the order of average ag(355)value around the Leizhou Peninsula was east coast(0.503/m)>Qiongzhou Strait(0.502/m)>west coast(0.365/m);(2)the best band combinations of CDOM inversion in spring and autumn were(B4+B11)/B3 and(B7-B1)/B6(B stands for the band of spectral images),and the final inversion results are close to the measured results,indicating that the model has good accuracy;(3)the S_(g)value of the CDOM absorption spectrum was fitted to the hyperbolicexponential model.The fitting accuracy of the model was higher than those of the exponential model and the hyperbolic model,and the best S_(g)inversion model was constructed by selecting Sg(275-295)and Sg(250-295)in spring and autumn;(4)the spatial distributions of ag(355)and S_(g)were inverted,and CDOM in the waters around the Leizhou Peninsula originated from terrestrial organic matter carried by coastal aquaculture zones and runoff in the northeast Zhanjiang and the northern Beibu Gulf.
