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Molecular Mechanism and Molecular Design of Lubricating Oil Antioxidants 被引量:1
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作者 Su Shuo Long Jun +2 位作者 Duan Qinghua Zhou Han Zhao Yi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期135-145,共11页
To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular me... To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions. 展开更多
关键词 lubricating oil antioxidant molecular mechanism molecular design antioxidant performance
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Enzymatic synthesis, antioxidant ability and oil-water distribution coefficient of troxerutin fatty acid esters 被引量:1
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作者 Yongmei Xiao Ming Li +2 位作者 Pu Mao Liangru Yang Lingbo Qu 《Grain & Oil Science and Technology》 2019年第3期78-84,共7页
Troxerutin fatty acid esters were prepared using troxerutin and fatty acid vinyl esters as substrates in pyridine through enzymatic route. The structures of as-prepared compounds were identified by FT-TR, NMR, and ESI... Troxerutin fatty acid esters were prepared using troxerutin and fatty acid vinyl esters as substrates in pyridine through enzymatic route. The structures of as-prepared compounds were identified by FT-TR, NMR, and ESI-HRMS. Using alkaline protease(≥30 mg/mL) as enzyme, maximum yields reached 58% at 3:1(vinyl hexanoate to troxerutin) in pyridine(water content ≤1%). The yields gradually declined as chain length of acyl donors rose. The antioxidation abilities of the as-obtained compounds were confirmed by both DPPH free radical scavenging and potassium ferricyanide reduction methods. The antioxidation ability of troxerutin fatty acid esters was found lower than that of troxerutin. However, the logP values of troxerutin fatty acid esters varied from 0.15 to 1.94, suggesting that troxerutin fatty acid esters had better lipophilicity than troxerutin(logP =-2.12) when compared to their oil-water distribution coefficients. Overall, these findings look promising as reference for further development of future troxerutin. 展开更多
关键词 TROXERUTIN ENZYMATIC synthesis FATTY acid ESTERS ANTIOXIDATION oil-water distribution COEFFICIENT
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Wheat Germ: An Overview on Nutritional Value, Antioxidant Potential and Antibacterial Characteristics 被引量:8
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作者 Awad A. Mahmoud Adel A. A. Mohdaly Nady A. A. Elneairy 《Food and Nutrition Sciences》 2015年第2期265-277,共13页
Wheat germ is a by-product derived from the wheat milling industry. Defatted wheat germ is the main by-product of the wheat germ in the oil extraction process. This study aims at development of efficient and low cost ... Wheat germ is a by-product derived from the wheat milling industry. Defatted wheat germ is the main by-product of the wheat germ in the oil extraction process. This study aims at development of efficient and low cost processing methods to transform these residues in added value co-product. In this study, wheat germ was analysed for its proximate composition, fatty acid composition, physical and chemical characteristics of wheat germ oil. The basic chemical composition analyses revealed high values of dry matter (87.37 g/100g FW), significant amounts of total protein and fat (27.69 and 8.99 g/100g FW, respectively) content and low ash content (3.08 g/100g FW). The quality of the extracted oils was assessed in terms of acid value, iodine value, saponification value, peroxide value, refractive index, and unsaponifiable matter. The fatty acid profile was found to be made up of linoleic followed by palmitic and oleic as the major fatty acids. Antioxidant properties and in vitro antibacterial activity of defatted wheat germ (DWG) extract were also determined. DWG, as a source of natural antioxidants and antibacterial, could be used to formulate nutraceuticals with potential applications to reduce the level of oxidative stress. The antioxidant potency of the DWG extracts could be the basis for its health promoting potential. The results showed that these by-products could be used as a source of bioactive compounds beneficial for health. 展开更多
关键词 ANTIBACTERIAL Activity antioxidant Properties Defatted WHEAT GERM FATTY acid WHEAT GERM oil
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Retardation of 4-Hydroxy-2-Transnonenal (HNE), a Toxic Aldehyde Formation by Antioxidants in Heat-Treated Corn Oil at Frying Temperature 被引量:1
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作者 Wei Jin D. W. Shoeman +1 位作者 Vijai K. S. Shukla A. Saari Csallany 《Food and Nutrition Sciences》 2020年第7期669-683,共15页
The antioxidative properties of four antioxidants such as rosemary extracts (RE), <span style="font-family:Verdana;">tert</span><b><span style="font-family:Verdana;">-</s... The antioxidative properties of four antioxidants such as rosemary extracts (RE), <span style="font-family:Verdana;">tert</span><b><span style="font-family:Verdana;">-</span></b><span style="font-family:Verdana;">butylhydroquinone</span><b> </b><span style="font-family:Verdana;">(TBHQ), ascorbyl palmitate (AP), citric acid (CA) and their mixtures were investigated on the formation of 4-hydroxy-2-transnonenal (HNE) in commercial corn oil heated at 185</span><span style="font-family:Verdana;">°</span><span style="font-family:;" "=""><span style="font-family:Verdana;">C</span><span style="font-family:Verdana;"> for up to 6 hours. Among the antioxidants 100 ppm RE and a mixture of 200 ppm tertiary butylated hydroquinone (TBHQ) + 100 ppm ascorbyl palmitate (AP) + 50 ppm citric acid (CA) exhibited excellent antioxidative activity, as determined by the thiobarbituric acid reaction (TBARS) assay, measuring the formations of the secondary lipid oxidation products and by high-performance liquid chromatography (HPLC), measuring the formation of the toxic </span></span><span style="font-family:Verdana;"><i></i></span><i><i><span style="font-family:Verdana;">α</span></i><i><span style="font-family:Verdana;"></span></i></i><span style="font-family:Verdana;">, </span><span style="font-family:Verdana;"><i></i></span><i><i><span style="font-family:Verdana;">β</span></i><i><span style="font-family:Verdana;"></span></i></i><span style="font-family:Verdana;">-unsaturated hydroxyaldehyde HNE after heat treatment of corn oil at 185</span><span style="font-family:Verdana;">°</span><span style="font-family:Verdana;">C up to 6 hours. TBHQ, AP and CA alone did not show much protective properties. The synergistic effects of TBHQ + AP + CA mixture shown to reduce the formation of HNE after 6 hours heat-treated corn oil by 27%. RE 100 ppm was also found to be a very effective antioxidant, reducing the formation of HNE after 6 hours heat-treated corn oil in the same condition by 29%.</span> 展开更多
关键词 antioxidantS Ascorbyl Palmitate Citric acid Corn oil HNE Rosemary Extracts TBHQ
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Plant phenolic extracts for the quality protection of frying oil during deep frying:Sources,effects,and mechanisms
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作者 Fa Wang Yixi Sun +4 位作者 Shanshan Li Jing Yan Wen Qin Ahmed S.M.Saleh Qing Zhang 《Grain & Oil Science and Technology》 CAS 2023年第3期148-161,共14页
Protection of frying oil from deterioration by adding plant phenolic extracts to guarantee the quality of fried foods becomes the primary approach to promote the sustainable development of deep frying.Therefore,source... Protection of frying oil from deterioration by adding plant phenolic extracts to guarantee the quality of fried foods becomes the primary approach to promote the sustainable development of deep frying.Therefore,sources,antioxidant effects,and mechanisms of plant phenolic extracts recently applied in the quality protection of frying oil as well as challenges for the actual use of these extracts are comprehensively reviewed in this study.Spices,herbs,berries,tea leaves,and fruit and vegetable wastes are common sources for preparing phenolic extracts showing comparative antioxidant capacity referring to the synthetic antioxidants.The general effect of using these natural antioxidants is the improvement of thermal stability to extend the shelf life of frying oil and thus the modification of edible quality of fried foods.Specifically,the increases in common quality attributes and amount of hazardous products and the oxidative reduction of unsaturated triacylglycerols without negatively influencing the sensory quality are inhibited when suitable plant extracts are applied.The incorporation of plant phenolic extracts other than synthetic counterparts in frying oil has been demonstrated as a potential method to improve the frying performance of oils.However,challenges for the scale application of plant phenolic extracts,such as the purity,thermal stability,and antioxidant timing,are still needed to be further investigated. 展开更多
关键词 Frying oil Phenolic antioxidants Plant extract Physicochemical properties antioxidant mechanisms
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Palm oil and the heart:A review
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作者 Osaretin J Odia Sandra Ofori Omosivie Maduka 《World Journal of Cardiology》 CAS 2015年第3期144-149,共6页
Palm oil consumption and its effects on serum lipid levels and cardiovascular disease in humans is still a subject of debate. Advocacy groups with varying agenda fuel the controversy. This update intends to identify e... Palm oil consumption and its effects on serum lipid levels and cardiovascular disease in humans is still a subject of debate. Advocacy groups with varying agenda fuel the controversy. This update intends to identify evidence-based evaluations of the influence of palm oil on serum lipid profile and cardiovascular disease. Furthermore, it suggests a direction for future research. The sources of information were based on a Pub Med, Google Scholar, African Journal online and Medline search using key words including: palm oil, palmitic acid, saturated fatty acids and heart disease. Published animal and human experiments on the association of palm oil and its constituents on the serum lipid profile and cardiovascular disease were also explored for relevant information. These papers are reviewed and the available evidence is discussed. Most of the information in mainstream literature is targeted at consumers and food companies with a view to discourage the consumption of palm oil. The main argument against the use of palm oil as an edible oil is the fact that it contains palmitic acid, which is a saturated fatty acid and by extrapolation should give rise to elevated total cholesterol and low-density lipoprotein cholesterol levels. However, there are many scientific studies, both in animals and humans that clearly show that palm oil consumption does not give rise to elevated serum cholesterol levels and that palm oil is not atherogenic. Apart from palmitic acid, palm oil consists of oleic and linoleic acids which are monounsaturated and polyunsaturated respectively. Palm oil also consists of vitamins A and E, which are powerful antioxidants. Palm oil has been scientifically shown to protect the heart and blood vessels from plaques and ischemic injuries. Palm oil consumed as a dietary fat as a part of a healthy balanced diet does not have incremental risk for cardiovascular disease. Little or no additional benefit will be obtained by replacing it with other oils rich in mono or polyunsaturated fatty acids. 展开更多
关键词 PALM oil SERUM LIPID profile HEART disease Palmitic acid antioxidantS
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Chia (<i>Salvia hispanica</i>L.) Seed Oil Rich in Omega-3 Fatty Acid: A Healthy Alternative for Milk Fat in Ice Milk
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作者 Amany M. Basuny Shaker M. Arafat Dalia M. Hikal 《Food and Nutrition Sciences》 2021年第6期479-493,共15页
Chia seed oil (</span><span style="font-family:Verdana;"><i></span><i><span style="font-family:""><span style="font-family:Verdana;">Salvia ... Chia seed oil (</span><span style="font-family:Verdana;"><i></span><i><span style="font-family:""><span style="font-family:Verdana;">Salvia </span><span style="font-family:Verdana;">hispanica</span></span></i><i><span style="font-family:Verdana;"></i></span></i><span style="font-family:""><span style="font-family:Verdana;"> L.) contains polyunsaturated omega-3 fatty acids and natural antioxidants that have many health effects. Consequently, the chief purpose of the present study was the outcome of various attentiveness of chia seed oil on </span><span style="font-family:Verdana;">quality</span><span style="font-family:Verdana;"> and sensory evaluation of ice milk. In treatments T</span><sub><span style="font-family:Verdana;">1</span></sub><span style="font-family:Verdana;">, T</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">, T</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">, and T</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;">, the milk fat was moderately swapped with chia seed oil at 10%, 20%, 30%, and 40%, respectively, and compared with the control treatment (100% </span><span style="font-family:Verdana;">milk fat</span><span style="font-family:Verdana;">). All treatments were stored at </span></span><span style="font-family:Verdana;">-</span><span style="font-family:Verdana;">18</span><span style="font-family:Verdana;">&deg;</span><span style="font-family:Verdana;">C for 30 days. Samples were analyzed fortnightly and monthly to determine the shelf life during the storage period by acidity and peroxide value. Physicochemical properties of fatty acids, total polyphenols, and total flavonoids of chia seed oil and ice milk samples were determined. Also, the overrun and sensory evaluation of ice milk samples were studied. Results indicated an increase in the absorption of omega-3 fatty acids (linolenic acid, eicosapentaenoic acid, docosapentaenoic acid, and docosahexaenoic “in the samples of” ice milk supplemented with chia seed oil compared with control. Furthermore, there has been an increase in natural antioxidants (total phenolic and total flavonoid contents) levels in the supplemented ice milk samples as compared to control. Furthermore, an increase in the shelf life of the supplemented ice milk samples was also noticed. Generally, fortification of ice milk with chia seed oil increased the concentration of omega-3 fatty acids and also improved the antioxidant properties of ice milk. 展开更多
关键词 Chia Seed oil Omega-3 Fatty acids Natural antioxidants Ice Milk
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Effects of Microwave Pre-treatment on the Quality of Kenaf (Hibiscus cannabinus L.) Seed Oil
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作者 Kar-Lin Nyam Hui-Wan Lau 《Journal of Food Science and Engineering》 2015年第1期14-21,共8页
The main aim of this study was to explore the effects of microwave pre-treatment on quality of kenaf seed oil by observing the changes in oil yield, oxidative stability, fatty acid components, tocopherols, antioxidant... The main aim of this study was to explore the effects of microwave pre-treatment on quality of kenaf seed oil by observing the changes in oil yield, oxidative stability, fatty acid components, tocopherols, antioxidant activities and color intensity of kenaf seed oil. Microwave pre-treatment on kenaf seeds did affect the quality of the extracted oils. Microwave pre-treatment increased the extracted oil yields significantly (P 〈 0.05). Moreover, the roasted oils showed a significant increase in oxidative stability, antioxidant stability and colour of kenaf seed oils. In terms of fatty acids composition, microwave roasting had greater effect on oleic acids (C18:1) and linoleic acids (C18:2), as roasting increased the oleic acid content but decreased linoleic acid. There was no significant difference in the palmitic acids (C16:0) and stearic acids (C18:0) (P 〉 0.05). A significant decrease (P 〈 0.05) in the iodine value of the oils was found. In conclusion, kenaf seed oil roasted for 2 min had better oil quality if compared to the unroasted oil, as microwave pre-treatment improved the oil yield, oxidative stability and antioxidant activities of kenaf seed oil. 展开更多
关键词 Fatty acid composition TOCOPHEROL antioxidant activity oxidative stability oil yield.
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电力用油红外光谱检测技术 被引量:1
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作者 王娟 付龙飞 +7 位作者 王笑微 吕秀娟 曹红梅 王垚 张兰庆 康夜雨 潘成福 齐吉锴 《热力发电》 CAS CSCD 北大核心 2024年第2期177-183,共7页
红外光谱检测技术因其检测速度快、对样品无损伤、无污染、易操作等特点,已广泛应用于石油化工、制药等行业的检测中。红外光谱检测方式主要包括定性检测和定量检测,定性检测通常采用比较法,即通过与标准物质对照或查阅标准谱图;定量检... 红外光谱检测技术因其检测速度快、对样品无损伤、无污染、易操作等特点,已广泛应用于石油化工、制药等行业的检测中。红外光谱检测方式主要包括定性检测和定量检测,定性检测通常采用比较法,即通过与标准物质对照或查阅标准谱图;定量检测是通过测量特征吸收谱带强度,结合化学计量学方法计算出对应组份含量。阐述了人工神经网络、偏最小二乘法等化学计量学方法在电力用油酸值、水分、抗氧化剂、糠醛等检测中的应用,并对其在油品检测中的应用给出了建议。 展开更多
关键词 红外光谱 电力用油 酸值 水分 抗氧化剂
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抗坏血酸提高棉花种子萌发耐盐性及其生理机制
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作者 徐建伟 闫紫欣 +3 位作者 朱金成 茹思博 刘文红 李志博 《中国农学通报》 2024年第33期53-60,共8页
本研究以新疆主栽棉花品种‘新陆早61号’为材料,旨在探讨抗坏血酸(AsA)浸种对提高棉花种子萌发期耐盐性的效果及其生理机制。通过分析不同类型盐胁迫(NaCl、Na_(2)SO_(4)和Na_(2)CO_(3)+NaHCO_(3))下,抗坏血酸(AsA)浸种对棉花种子(棉种... 本研究以新疆主栽棉花品种‘新陆早61号’为材料,旨在探讨抗坏血酸(AsA)浸种对提高棉花种子萌发期耐盐性的效果及其生理机制。通过分析不同类型盐胁迫(NaCl、Na_(2)SO_(4)和Na_(2)CO_(3)+NaHCO_(3))下,抗坏血酸(AsA)浸种对棉花种子(棉种)主要发芽特性和生理指标的影响。结果表明,棉种的萌发随盐胁迫浓度升高而下降;但在AsA浸种处理后,棉种萌发特性显著增强,其中发芽率分别比对照提高了55.32%、56.10%和44.0%。最佳AsA浸种浓度分别为0.10 mmol/L(NaCl和Na_(2)SO_(4))和0.15 mmol/L(Na_(2)CO_(3)+NaHCO_(3))。此外,盐胁迫萌发过程中AsA浸种提高了棉种SOD、POD、CAT抗氧化酶的活性,增强了可溶性蛋白和可溶性糖的含量,同时降低了MDA和H_(2)O_(2)的水平。研究表明,AsA浸种通过增强抗氧化酶活性、增加渗透物质含量和减少膜脂过氧化,有效提升了棉花种子的耐盐性。 展开更多
关键词 抗坏血酸 盐胁迫 棉花 种子萌发 生理机制 抗氧化酶
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煎炸过程中树莓籽油的稳定性研究
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作者 乔国华 杨彦丰 +3 位作者 吴隆坤 杨宏黎 巩怀悦 杨晓菲 《食品安全导刊》 2024年第33期162-164,共3页
本文探讨树莓籽油在煎炸过程中的稳定性问题,通过分析其主要营养成分组成及煎炸过程中的物理化学指标变化,确定不饱和脂肪酸含量高、内源抗氧化剂不足及高温条件是影响其稳定性的关键因素。同时,提出采用分步冬化结晶分离工艺降低不饱... 本文探讨树莓籽油在煎炸过程中的稳定性问题,通过分析其主要营养成分组成及煎炸过程中的物理化学指标变化,确定不饱和脂肪酸含量高、内源抗氧化剂不足及高温条件是影响其稳定性的关键因素。同时,提出采用分步冬化结晶分离工艺降低不饱和度、添加天然抗氧化剂及优化温控系统等措施,提高树莓籽油在煎炸过程中的稳定性,延长其使用寿命,为特色植物油的开发应用提供技术支持。 展开更多
关键词 树莓籽油 煎炸 稳定性 不饱和脂肪酸 内源抗氧化剂 高温
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天然抗氧化剂对玉米油热致异构体的影响 被引量:1
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作者 田莹俏 李甜 +3 位作者 张妤 贺凡 王晶 郭芹 《食品与发酵工业》 CAS CSCD 北大核心 2024年第15期149-154,共6页
玉米油在加工贮藏过程易发生异构化生成反式和共轭脂肪酸异构体,开展玉米油反式和共轭脂肪酸的调控研究对保障消费者安全与营养健康至关重要。人工抗氧化剂由于毒性累积已被许多国家禁用或严格限制,天然抗氧化剂已开始引起人们的高度关... 玉米油在加工贮藏过程易发生异构化生成反式和共轭脂肪酸异构体,开展玉米油反式和共轭脂肪酸的调控研究对保障消费者安全与营养健康至关重要。人工抗氧化剂由于毒性累积已被许多国家禁用或严格限制,天然抗氧化剂已开始引起人们的高度关注。该研究采用气相色谱检测方法研究了天然抗氧化剂对玉米油热致异构体形成的影响。结果表明,玉米油反式和共轭脂肪酸含量随着加热温度和加热时间的增加而增加。天然抗氧化剂具有抑制玉米油反式脂肪酸(0.28%~6.59%)和诱导玉米油共轭脂肪酸(0.53%~16.42%)形成的作用,抑制率为鼠尾草酸>特丁基对苯二酚>L-抗坏血酸棕榈酸酯>茶多酚>维生素E,诱导率为维生素E>茶多酚>特丁基对苯二酚>L-抗坏血酸棕榈酸酯>鼠尾草酸。复配抗氧化剂的抗异构和诱导异构作用低于单独使用抗氧化剂,综合分析鼠尾草酸和L-抗坏血酸棕榈酸酯可作为有效的天然抗异构和诱导异构剂。 展开更多
关键词 天然抗氧化剂 玉米油 反式脂肪酸 共轭脂肪酸 抗异构 诱导异构
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超声辅助水酶法提取花生油脂工艺研究及油脂品质分析 被引量:1
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作者 董艺帆 贾赛阳 +5 位作者 杨鸣 陈复生 段晓杰 布冠好 杨趁仙 朱婷伟 《河南工业大学学报(自然科学版)》 CAS 北大核心 2024年第2期11-18,共8页
为了实现花生油脂的高效提取和利用,采用超声辅助水酶法提取花生油脂,研究超声功率、作用时间、作用温度、料液比及酶用量对花生油脂提取率的影响,采用响应面试验优化提取工艺,并分析花生油脂的脂肪酸组成、酸价、过氧化值和抗氧化能力... 为了实现花生油脂的高效提取和利用,采用超声辅助水酶法提取花生油脂,研究超声功率、作用时间、作用温度、料液比及酶用量对花生油脂提取率的影响,采用响应面试验优化提取工艺,并分析花生油脂的脂肪酸组成、酸价、过氧化值和抗氧化能力。结果表明:花生油脂的最优提取工艺条件为料液比1∶5 g/mL、纤维素酶用量1.0%、超声功率247 W、作用时间41 min、作用温度51℃,此条件下的油脂提取率为92.64%±0.73%;从提取的花生油脂中共检出8种脂肪酸,其中油酸含量最高,为40.44%±0.57%,亚油酸含量为36.97%±0.05%;花生油脂的酸价为(0.38±0.04)mg/g,过氧化值为(0.15±0.00)g/100 g,DPPH和ABTS自由基清除率分别为64.82%±2.51%、82.56%±6.47%。超声辅助水酶法有效缩短了提取时间,降低了酶用量,并且制备的花生油脂中不饱和脂肪酸含量高,具有良好的抗氧化能力。 展开更多
关键词 花生油脂 水酶法 超声 脂肪酸 抗氧化能力
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复配抗氧化剂在牡丹籽油乳液中的抗氧化作用研究 被引量:1
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作者 张子怡 唐林 +5 位作者 郭芷淳 储佳怡 钱文一 刘宇 常明 刘睿杰 《中国油脂》 CAS CSCD 北大核心 2024年第2期18-24,62,共8页
为提高牡丹籽油乳液的氧化稳定性,将叔丁基对苯二酚(TBHQ)与天然抗氧化剂(生育酚、抗坏血酸)进行复配,测定不同抗氧化剂对牡丹籽油乳液的抗氧化作用,并分析了不同复配抗氧化剂的相互作用机制。结果表明:在贮藏30 d时,添加和未添加抗氧... 为提高牡丹籽油乳液的氧化稳定性,将叔丁基对苯二酚(TBHQ)与天然抗氧化剂(生育酚、抗坏血酸)进行复配,测定不同抗氧化剂对牡丹籽油乳液的抗氧化作用,并分析了不同复配抗氧化剂的相互作用机制。结果表明:在贮藏30 d时,添加和未添加抗氧化剂牡丹籽油乳液的粒径相较于0 d均略有增加,200 mg/kg TBHQ与800 mg/kg抗坏血酸复配时乳液的Zeta电位绝对值最大,且抗氧化作用最强;TBHQ与抗坏血酸表现出较好的协同抗氧化作用,与生育酚表现出拮抗作用;TBHQ与生育酚之间拮抗作用的原因主要是TBHQ减少了生育酚在牡丹籽油乳液中油水界面的含量,而TBHQ与抗坏血酸之间协同作用主要是由于抗坏血酸增加了TBHQ在牡丹籽油乳液中油水界面的含量。综上,TBHQ与抗坏血酸复配能提高牡丹籽油乳液的氧化稳定性。 展开更多
关键词 牡丹籽油乳液 抗氧化剂 叔丁基对苯二酚 生育酚 抗坏血酸 相互作用
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植物精油与苯甲酸组合对淮北麻鸡生长性能、屠宰性能、肉品质以及肌肉风味组分、质构特性和抗氧化能力的影响 被引量:5
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作者 白俊宇 武慧敏 +2 位作者 阿依姑·苏来曼 胡忠泽 孟玲琳 《动物营养学报》 CAS CSCD 北大核心 2024年第1期295-311,共17页
本试验旨在探究植物精油与苯甲酸组合对淮北麻鸡生长性能、屠宰性能、肉品质以及肌肉风味组分、质构特性和抗氧化能力的影响。试验选取1日龄的淮北麻鸡公鸡360只,随机分为4组,每组6个重复,每个重复15只鸡。空白对照组(CON组)饲喂基础饲... 本试验旨在探究植物精油与苯甲酸组合对淮北麻鸡生长性能、屠宰性能、肉品质以及肌肉风味组分、质构特性和抗氧化能力的影响。试验选取1日龄的淮北麻鸡公鸡360只,随机分为4组,每组6个重复,每个重复15只鸡。空白对照组(CON组)饲喂基础饲粮,试验组分别在基础饲粮中添加300 mg/kg复合植物精油(EO组)、2000 mg/kg苯甲酸钠(BA组)、300 mg/kg复合植物精油+2000 mg/kg苯甲酸钠(EO+BA组)。试验期为90 d。结果表明:1)饲粮中添加植物精油显著降低了料重比(F/G)(P<0.05)。饲粮中添加苯甲酸显著提高了终末体重(FBW)和平均日增重(ADG),显著降低料重比F/G(P<0.05)。饲粮中添加植物精油和苯甲酸对FBW、ADG、平均日采食量(ADFI)和F/G均有显著交互作用(P<0.05)。2)饲粮中添加植物精油对屠宰性能无显著影响(P>0.05)。饲粮中添加苯甲酸显著提高了屠宰率、半净膛率和全净膛率(P<0.05)。饲粮中添加植物精油和苯甲酸对屠宰性能无显著交互作用(P>0.05)。3)饲粮中添加植物精油显著降低了腿肌pH(P<0.05)。饲粮中添加苯甲酸显著降低了胸肌pH(P<0.05)。饲粮中添加植物精油和苯甲酸对胸肌pH、滴水损失和剪切力有显著交互作用(P<0.05)。4)饲粮中添加植物精油对胸肌和腿肌质构特性无显著影响(P>0.05)。饲粮中添加苯甲酸显著提高了腿肌胶着性(P<0.05)。饲粮中添加植物精油和苯甲酸对胸肌硬度以及腿肌弹性、胶着性和咀嚼性有显著交互作用(P<0.05)。5)饲粮中添加植物精油提高了无机硫化物对胸肌和腿肌的第一主成分(PC1)贡献率,提高了有机硫化物对胸肌和腿肌的第二主成分(PC2)贡献率。饲粮中添加苯甲酸提高了无机硫化物对腿肌的PC1贡献率,提高了有机硫化物对胸肌和腿肌的PC2贡献率。饲粮中添加植物精油与苯甲酸提高了无机硫化物对腿肌的PC1贡献率,提高了短链烷烃对胸肌的PC2贡献率,且提高了有机硫化物对腿肌的PC2贡献率。6)饲粮中添加植物精油显著提高了胸肌过氧化氢酶(CAT)活性、腿肌谷胱甘肽过氧化物酶(GSH-Px)活性(P<0.05)。饲粮中添加苯甲酸对胸肌和腿肌抗氧化指标无显著影响(P>0.05)。饲粮中添加植物精油和苯甲酸对胸肌和腿肌CAT活性有显著交互作用(P<0.05)。综上所述,饲粮中添加植物精油与苯甲酸组合能够提高淮北麻鸡生长性能,改善肌肉风味组分,提高肌肉抗氧化能力。 展开更多
关键词 植物精油 苯甲酸 淮北麻鸡 生长性能 屠宰性能 肉品质 风味组分 抗氧化能力
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乳酸菌抗氧化机制研究进展及在食品领域的应用 被引量:1
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作者 尹树磊 杜香 +3 位作者 张小希 刘璐 易俊洁 王艳菲 《食品科学》 EI CAS CSCD 北大核心 2024年第13期345-355,共11页
乳酸菌不仅有助于改善发酵食品的风味,提高营养价值,还有助于预防由于氧化反应而引发的多种疾病。这些有益功能的发挥与乳酸菌的抗氧化活性密不可分。本文详细阐述了乳酸菌的抗氧化机制,包括调节抗氧化酶类、调控信号通路、清除自由基... 乳酸菌不仅有助于改善发酵食品的风味,提高营养价值,还有助于预防由于氧化反应而引发的多种疾病。这些有益功能的发挥与乳酸菌的抗氧化活性密不可分。本文详细阐述了乳酸菌的抗氧化机制,包括调节抗氧化酶类、调控信号通路、清除自由基系统、抑制脂质过氧化作用及金属离子螯合作用;总结了乳酸菌的抗氧化特性在乳制品、肉制品、水产品和果蔬制品等领域的应用现状;概述了乳酸菌抗氧化活性的体外和体内评估方法,旨在为乳酸菌在食品加工领域的深层次应用提供相关参考。 展开更多
关键词 乳酸菌 抗氧化活性 作用机制 食品加工 评估方法
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超声辅助提取油莎豆油的工艺优化及品质分析 被引量:1
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作者 权煜 刘学强 +3 位作者 赵丹丹 饶欢 吴彤娇 郝建雄 《食品工业科技》 CAS 北大核心 2024年第10期207-216,共10页
为提高油莎豆油的得率且保证成品品质,本研究采用超声辅助正己烷法对油莎豆油的提取工艺进行响应面试验优化,确定最优提取条件后对油莎豆油品质进行分析。在油的品质研究中,采用25℃(常温)、47℃(超声辅助提取最佳温度)、60℃(高温)三... 为提高油莎豆油的得率且保证成品品质,本研究采用超声辅助正己烷法对油莎豆油的提取工艺进行响应面试验优化,确定最优提取条件后对油莎豆油品质进行分析。在油的品质研究中,采用25℃(常温)、47℃(超声辅助提取最佳温度)、60℃(高温)三个温度对比超声作用对油样中总酚含量、总黄酮含量、1, 1-二苯基-2-三硝基苯肼(1,1-diphenyl-2-picrylhydrazyl,DPPH)自由基清除率、脂肪酸组成及含量的影响。结果表明:脱皮油莎豆研磨后在料液比1:15 (g/mL)、超声时间20 min、超声温度47℃、粉碎粒度70目时,油莎豆油的得率为25.01%±0.03%,油样为黄橙色微浊状态,具有豆类特有的香气。油莎豆油对DPPH自由基有一定的清除作用,超声可更好地溶出油莎豆中的营养物质,但对油莎豆中黄酮类物质的破坏效应相对较大,酚酸类物质在高温时含量显著(P<0.05)下降。在25~60℃间超声作用和温度的变化对脂肪酸的种类和含量的影响不大,油酸(C18:1)含量最高,约为73.81%~74.00%。本试验结果可以为油莎豆油脂的开发利用提供一定基础和理论依据。 展开更多
关键词 油莎豆油 超声辅助提取 工艺优化 抗氧化活性 气相色谱 黄酮 多酚 脂肪酸组成
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盾叶木籽油的理化性质、热特性及抗氧化性能
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作者 杨梦 毕荣璐 +5 位作者 张平 王爱民 陆桂蒙 汪海翔 刘祥义 徐娟 《中国油脂》 CAS CSCD 北大核心 2024年第6期53-57,81,共6页
旨在为盾叶木籽油的进一步开发利用提供参考,采用索氏提取法提取带壳和不带壳盾叶木籽中油脂,测定带壳盾叶木籽油(HMGO)和不带壳盾叶木籽油(NMGO)的理化指标、总多酚含量、脂肪酸组成、热特性和抗氧化活性,比较两种盾叶木籽油的性质差... 旨在为盾叶木籽油的进一步开发利用提供参考,采用索氏提取法提取带壳和不带壳盾叶木籽中油脂,测定带壳盾叶木籽油(HMGO)和不带壳盾叶木籽油(NMGO)的理化指标、总多酚含量、脂肪酸组成、热特性和抗氧化活性,比较两种盾叶木籽油的性质差异。结果表明:带壳盾叶木籽含油率略低于不带壳的,NMGO的酸值、过氧化值、总多酚及不皂化物含量低于HMGO的,而其皂化值高于HMGO的;HMGO和NMGO分别检出21种和20种脂肪酸,其中神经酸含量最高(NMGO 43.00%和HMGO41.10%),其次是芥酸(NMGO30.20%和HMGO28.80%);HMGO低温结晶在-4.19℃处熔融,快速热解温度在355~441℃,NMGO低温结晶在-3.68℃处熔融,快速热解温度在363~440℃,两种盾叶木籽油均在407℃质量损失速率达到最大值;盾叶木籽油对DPPH自由基及ABTS自由基均具有不同程度的清除作用,清除能力随着其浓度的升高而增大,且HMGO较NMGO对DPPH自由基及ABTS自由基清除能力强。综上,盾叶木籽油可作为神经酸和芥酸的来源资源进行开发利用。 展开更多
关键词 盾叶木籽油 理化性质 热特性 脂肪酸 抗氧化活性
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没食子酸-磷脂复合物的制备与表征及其对核桃油氧化稳定性的影响
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作者 杜伊晗 何强 董怡 《现代食品科技》 CAS 北大核心 2024年第4期156-166,共11页
没食子酸具有多种生物活性,但较差的脂溶性使其应用受到限制。该实验以没食子酸与大豆卵磷脂为原料,使用溶剂蒸发法制备没食子酸-磷脂复合物。使用单因素实验优化出没食子酸-磷脂复合物的最佳制备条件,使用紫外、红外光谱及差示量热扫... 没食子酸具有多种生物活性,但较差的脂溶性使其应用受到限制。该实验以没食子酸与大豆卵磷脂为原料,使用溶剂蒸发法制备没食子酸-磷脂复合物。使用单因素实验优化出没食子酸-磷脂复合物的最佳制备条件,使用紫外、红外光谱及差示量热扫描对制得复合物进行结构表征,验证其形成;并初步测定其油水分配系数与抗氧化性能。所得最佳制备条件为:以无水乙醇为溶剂,没食子酸质量浓度为1 mg/mL,没食子酸与大豆卵磷脂的投料摩尔比为1:4,45℃下恒温搅拌2 h。该条件下制备的复合物,复合率达94.65%,显著提高没食子酸的油水分配系数,其体外抗氧化活性与没食子酸无显著差异。对加入没食子酸-磷脂复合物的核桃油进行加速氧化实验,测定复合物对核桃油氧化稳定性的影响。结果表明没食子酸-磷脂复合物可有效抑制核桃油氧化,且12 d内抗氧化效果显著优于没食子酸(P<0.05)。该研究制备的没食子酸-磷脂复合物复合率高,脂溶性和抗氧化性良好,可有效提高核桃油的氧化稳定性。 展开更多
关键词 没食子酸 大豆卵磷脂 复合物 核桃油 抗氧化活性
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外源阿魏酸抑制鲜切苹果褐变机制研究
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作者 李钰 娄晋衔 +2 位作者 马银银 王冬梅 刘佩 《保鲜与加工》 CAS 北大核心 2024年第6期9-17,共9页
苹果在鲜切过程中易因遭受机械损伤而引发褐变,严重影响其感官品质、风味和商品价值。采用不同浓度外源阿魏酸溶液对鲜切‘红富士’苹果进行浸泡处理,以研究其抑制鲜切苹果褐变的机制。结果表明:1、5、8、10 g/L的阿魏酸浸泡处理均能有... 苹果在鲜切过程中易因遭受机械损伤而引发褐变,严重影响其感官品质、风味和商品价值。采用不同浓度外源阿魏酸溶液对鲜切‘红富士’苹果进行浸泡处理,以研究其抑制鲜切苹果褐变的机制。结果表明:1、5、8、10 g/L的阿魏酸浸泡处理均能有效抑制鲜切苹果褐变,10 g/L阿魏酸浸泡处理10 min对鲜切苹果褐变的抑制效果最优;10 g/L阿魏酸处理显著提高了鲜切苹果超氧化物歧化酶(SOD)活性及1,1-二苯基-2-三硝基苯肼(DPPH)自由基、2,2-联氨-双-3-乙基苯并噻唑啉-6-磺酸(ABTS)阳离子自由基的清除率,抑制了贮藏后期多酚氧化酶(PPO)活性,降低了表儿茶素等单一酚的含量,提高了对香豆酸的含量;添加5 mg/mL表儿茶素会促进苹果浆液褐变,而添加5、10、20、40 mg/mL对香豆酸均能抑制苹果浆液褐变。综上所述,外源阿魏酸处理可通过提高SOD活性、抗氧化能力、内源褐变抑制物含量以及降低褐变底物含量来减轻鲜切苹果褐变。 展开更多
关键词 阿魏酸 鲜切苹果 褐变机制 抗氧化能力
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