The reaction behavior of oil sand from Inner Mongolia（China） were studied in a fluidizedbed pyrolysis process,and a comparative study was conducted on the properties of the liquid products obtained through fluidized...The reaction behavior of oil sand from Inner Mongolia（China） were studied in a fluidizedbed pyrolysis process,and a comparative study was conducted on the properties of the liquid products obtained through fluidized-bed pyrolysis of oil sand and the native bitumen obtained by solvent extraction.The results indicated that the fluidized-bed pyrolysis,a feasible carbon rejection process,can be used to upgrade oil sand.The reaction temperature and time were found to be the key operating parameters affecting the product distribution and yields in fluidized-bed pyrolysis of oil sand.The optimal temperature was 490℃ and the most suitable reaction time was 5 min.Under these operation conditions,the maximum yield of liquid product was 80wt%.In addition,the pyrolysis kinetics of oil sand at different heating rates of 5,10,20 and 30℃/min was investigated using a thermogravimetric analyzer（TGA）.展开更多
The characteristics and kinetics of coal and oil shale pyrolysis were comparatively studied by using a micro fluidized bed reaction analyzer(MFBRA).The isothermal differential model was first applied to calculate the ...The characteristics and kinetics of coal and oil shale pyrolysis were comparatively studied by using a micro fluidized bed reaction analyzer(MFBRA).The isothermal differential model was first applied to calculate the kinetic parameters of activation energy and frequency factor according to the major gas components during pyrolysis.The results showed that the major gas components released from coal and oil shale under the isothermal condition had different initiating and ending time points,and the difference was more significant under the programmed heating conditions.The shrinking core model allowed better fitting relevance for the coal pyrolysis,while the three-dimension model was more suitable for oil shale pyrolysis,indicating that the gases from the pyrolysis process of coal and oil shale might go through different reaction paths.The activation energy of oil shale pyrolysis was 36.96 kJ·mol^(−1),larger than the value of pyrolysis of the two coals,which was 21.16 and 32.17 kJ·mol^(−1),respectively.The above results justified that the oil shale pyrolysis with high ash contents was somehow more difficult to take place in terms of higher activation energy and the MFBRA could be a useful tool to give some insight into the intrinsic kinetics and reaction mechanisms of coal and oil shale pyrolysis.展开更多
采用美国Perk in E lm er公司生产的Pyris1 TGA热重分析仪,对桦甸油页岩半焦进行燃烧特性试验研究,得到3种不同升温速率下的油页岩半焦燃烧特性曲线,并使用平均质量反应性指数和燃烧稳定性指数对半焦反应性加以评价。油页岩半焦燃烧分...采用美国Perk in E lm er公司生产的Pyris1 TGA热重分析仪,对桦甸油页岩半焦进行燃烧特性试验研究,得到3种不同升温速率下的油页岩半焦燃烧特性曲线,并使用平均质量反应性指数和燃烧稳定性指数对半焦反应性加以评价。油页岩半焦燃烧分燃烧快速段、过渡段和燃烧慢速段3个阶段进行。随着升温速率的提高,在燃烧快速段,表观活化能为133.901 3—100.204 2 kJ/mol;在燃烧慢速段,表观活化能为146.317 1—211.409 3 kJ/mol。利用Coats-Redfern法确定了燃烧快速段反应级数为3,而燃烧慢速段则为5.5,从而得到油页岩半焦燃烧化学反应的动力学参数,为油页岩半焦的有效开发与经济利用提供了理论依据。展开更多
基金the financial support provided by the National Science Foundation of China (21176252)the China National Petroleum Science Research Program (2011B-2404-01)
文摘The reaction behavior of oil sand from Inner Mongolia（China） were studied in a fluidizedbed pyrolysis process,and a comparative study was conducted on the properties of the liquid products obtained through fluidized-bed pyrolysis of oil sand and the native bitumen obtained by solvent extraction.The results indicated that the fluidized-bed pyrolysis,a feasible carbon rejection process,can be used to upgrade oil sand.The reaction temperature and time were found to be the key operating parameters affecting the product distribution and yields in fluidized-bed pyrolysis of oil sand.The optimal temperature was 490℃ and the most suitable reaction time was 5 min.Under these operation conditions,the maximum yield of liquid product was 80wt%.In addition,the pyrolysis kinetics of oil sand at different heating rates of 5,10,20 and 30℃/min was investigated using a thermogravimetric analyzer（TGA）.
基金The study was conducted with the research programs financed by the National Natural Science Foundation of China(U1862107,21406264)Science Foundation of China University of Petroleum-Beijing(Grant No.2462018BJC003)R&D Program of China National Petroleum Corporation(LH-17-08-55-05).
文摘The characteristics and kinetics of coal and oil shale pyrolysis were comparatively studied by using a micro fluidized bed reaction analyzer(MFBRA).The isothermal differential model was first applied to calculate the kinetic parameters of activation energy and frequency factor according to the major gas components during pyrolysis.The results showed that the major gas components released from coal and oil shale under the isothermal condition had different initiating and ending time points,and the difference was more significant under the programmed heating conditions.The shrinking core model allowed better fitting relevance for the coal pyrolysis,while the three-dimension model was more suitable for oil shale pyrolysis,indicating that the gases from the pyrolysis process of coal and oil shale might go through different reaction paths.The activation energy of oil shale pyrolysis was 36.96 kJ·mol^(−1),larger than the value of pyrolysis of the two coals,which was 21.16 and 32.17 kJ·mol^(−1),respectively.The above results justified that the oil shale pyrolysis with high ash contents was somehow more difficult to take place in terms of higher activation energy and the MFBRA could be a useful tool to give some insight into the intrinsic kinetics and reaction mechanisms of coal and oil shale pyrolysis.
