New insights into the deposition of natural gas hydrate on pipeline surfaces:A molecular dynamics simulation study

Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low temperatures.Reducing hydrate adhesion on pipelines is viewed as an efficient way to prevent NGH blockages.Previous studies suggested the water film can greatly increase hydrate adhesion in gas-dominant system.Herein,by performing the molecular dynamics simulations,we find in water-dominant system,the water film plays different roles in hydrate deposition on Fe and its corrosion surfaces.Specifically,due to the strong affinity of water on Fe surface,the deposited hydrate cannot convert the adsorbed water into hydrate,thus,a water film exists.As water affinities decrease(Fe>Fe_(2)O_(3)>FeO>Fe_(3)O_(4)),adsorbed water would convert to amorphous hydrate on Fe_(2)O_(3)and form the ordered hydrate on FeO and Fe_(3)O_(4)after hydrate deposition.While absorbed water film converts to amorphous or to hydrate,the adhesion strength of hydrate continuously increases(Fe<Fe_(2)O_(3)<FeO<Fe_(3)O_(4)).This is because the detachment of deposited hydrate prefers to occur at soft region of liquid layer,the process of which becomes harder as liquid layer vanishes.As a result,contrary to gas-dominant system,the water film plays the weakening roles on hydrate adhesion in water-dominant system.Overall,our results can help to better understand the hydrate deposition mechanisms on Fe and its corrosion surfaces and suggest hydrate deposition can be adjusted by changing water affinities on pipeline surfaces.

Geochemical prerequisites for the formation of oil and gas accumulation zones in the South Turgay basin,Kazakhstan

This study predicts favorable oil and gas source-rock formation conditions in the Aryskum Depression of the South Turgay Basin,Kazakhstan.This study assesses the thermal maturity and characteristics of organic matter by determining its environmental conditions using data from geochemical analysis of core(pyrolysis)and oil(biomarkers and carbon isotopic compositions)samples.According to the geochemical parameters obtained by pyrolysis,the oil generation potential of the original rocks of most studied samples varies from poor to rich.The facies–genetic organic matter is predominantly humic and less frequently humus–sapropel,indicating organic matter accumulation in the studied samples were under moderately reducing conditions(kerogenⅢand Ⅱ types)and coastal–marine environments(kerogen typeⅠ).The carbon isotopic compositions of oils derived from the Jurassic deposits of the Aryskum Depression also indicate the sapropelic and mixed humic–sapropelic type of organic matter(kerogenⅡandⅠ).Biomarker analysis of oils indicates original organic matter formation in an anoxic environment.

Prediction on Failure Pressure of Pipeline Containing Corrosion Defects Based on ISSA-BPNNModel

Oil and gas pipelines are affected by many factors,such as pipe wall thinning and pipeline rupture.Accurate prediction of failure pressure of oil and gas pipelines can provide technical support for pipeline safety management.Aiming at the shortcomings of the BP Neural Network(BPNN)model,such as low learning efficiency,sensitivity to initial weights,and easy falling into a local optimal state,an Improved Sparrow Search Algorithm(ISSA)is adopted to optimize the initial weights and thresholds of BPNN,and an ISSA-BPNN failure pressure prediction model for corroded pipelines is established.Taking 61 sets of pipelines blasting test data as an example,the prediction model was built and predicted by MATLAB software,and compared with the BPNN model,GA-BPNN model,and SSA-BPNN model.The results show that the MAPE of the ISSA-BPNN model is 3.4177%,and the R2 is 0.9880,both of which are superior to its comparison model.Using the ISSA-BPNN model has high prediction accuracy and stability,and can provide support for pipeline inspection and maintenance.

Miscibility of light oil and flue gas under thermal action

The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and high pressure,the miscible displacement of flue gas and light oil is possible.At the same temperature,there is a linear relationship between oil displacement efficiency and pressure.At the same pressure,the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature.The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature.Moreover,at the same pressure,the lighter the oil,the lower the minimum miscibility temperature between flue gas and oil,which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection.The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state,and it is different from the contact extraction miscibility of CO_(2) under conventional high pressure conditions.

Discovery and inspiration of large-and medium-sized glutenite-rich oil and gas fields in the eastern South China Sea:An example from Paleogene Enping Formation in Huizhou 26 subsag,Pearl River Mouth Basin

Based on the practice of oil and gas exploration in the Huizhou Sag of the Pearl River Mouth Basin,the geochemical indexes of source rocks were measured,the reservoir development morphology was restored,the rocks and minerals were characterized microscopically,the measured trap sealing indexes were compared,the biomarker compounds of crude oil were extracted,the genesis of condensate gas was identified,and the reservoir-forming conditions were examined.On this basis,the Paleogene Enping Formation in the Huizhou 26 subsag was systematically analyzed for the potential of oil and gas resources,the development characteristics of large-scale high-quality conglomerate reservoirs,the trapping effectiveness of faults,the hydrocarbon migration and accumulation model,and the formation conditions and exploration targets of large-and medium-sized glutenite-rich oil and gas fields.The research results were obtained in four aspects.First,the Paleogene Wenchang Formation in the Huizhou 26 subsag develops extensive and thick high-quality source rocks of semi-deep to deep lacustrine subfacies,which have typical hydrocarbon expulsion characteristics of"great oil generation in the early stage and huge gas expulsion in the late stage",providing a sufficient material basis for hydrocarbon accumulation in the Enping Formation.Second,under the joint control of the steep slope zone and transition zone of the fault within the sag,the large-scale near-source glutenite reservoirs are highly heterogeneous,with the development scale dominated hierarchically by three factors(favorable facies zone,particle component,and microfracture).The(subaqueous)distributary channels near the fault system,with equal grains,a low mud content(<5%),and a high content of feldspar composition,are conducive to the development of sweet spot reservoirs.Third,the strike-slip pressurization trap covered by stable lake flooding mudstone is a necessary condition for oil and gas preservation,and the NE and nearly EW faults obliquely to the principal stress have the best control on traps.Fourth,the spatiotemporal configuration of high-quality source rocks,fault transport/sealing,and glutenite reservoirs controls the degree of hydrocarbon enrichment.From top to bottom,three hydrocarbon accumulation units,i.e.low-fill zone,transition zone,and high-fill zone,are recognized.The main area of the channel in the nearly pressurized source-connecting fault zone is favorable for large-scale hydrocarbon enrichment.The research results suggest a new direction for the exploration of large-scale glutenite-rich reservoirs in the Enping Formation of the Pearl River Mouth Basin,and present a major breakthrough in oil and gas exploration.

Oil Spill Risk Assessment of Offshore Pipeline in the Bohai Sea Under the Perspective of Ecological Protection

In recent decades,the exploration and development of marine oil and gas resources have increased significantly to meet the increasing energy demand of mankind.The Bohai Sea is a semi-closed continental sea that has a weak water exchange capacity and high ecological fragility.However,at present,more than 200 oil platforms have been built in the Bohai Sea,with more than 270 offshore oil pipelines having a length exceeding 1600 km.The oil spill pollution of offshore platforms has a great impact on the marine environment and ecosystems.Therefore,a comprehensive assessment of its risks is of great practical significance.This paper systematically constructs a comprehensive oil spill risk assessment model that combines the oil spill risk probability model and the ocean hydrodynamic model.This paper uses the Bohai Sea offshore pipeline as an example to assess its oil spill risk.The high-risk-value areas of the Bohai Sea offshore pipeline are mainly distributed at the bottom of Liaodong Bay,the bottom of Bohai Bay,near the Caofeidian area,and the northern part of the Yellow River Estuary.

Development of a Low-Cost Prototype System for Pipeline Operational and Vandalism Spillage Detection and Validation Framework

Crude oil spillage is a major challenge in Nigeria. It affects the environment, health, life, and livelihood of residents of the Niger Delta region, where oil is explored, processed, and transported via a network of pipelines. Oil spillage is primarily caused by vandalization/sabotage and operational issues such as corrosion, equipment failure, operation, and maintenance errors. Thus, prompt response is required to mitigate the impact of oil spills. In this study, we deployed low-cost Arduino systems, including sensors (vibration and flow), modules (GPS and Wifi) and an IoT platform (ThingSpeak) to detect spillage caused by vandalism and operational inefficiencies proactively. The results demonstrate that low-cost sensors can detect changes in the flow volume between the inflow and outflow attributable to spillage, and vibration shocks caused by vandalism can be detected and linked to the cause of the spillage and communicated in real time to inform response action. Moreover, we proposed a framework for field validation utilizing KoboToolBox (a crowdsourcing/citizen science platform). The prototype system designed and programmed showed promising results, as it could detect spillage for vandalism and operational scenarios in real-time, quantify the volume of spillage, and identify the location and time of spillage occurrence;indicators relevant for response planning to minimize the impact of oil spillage. A video demonstration of the prototype system developed is accessible via: https://youtu.be/wKa9MZvYf1w. .

Safety Length Simulation of Natural Gas Pipeline Subjected to Transverse Landslide

The safety of natural gas pipeline is often severely threatened by the transverse landslide. At home and abroad, it is the first time to study the safe length of the pipeline when affected by landslide, and take the safe length of the pipeline as an engineering practical index. Therefore, it is of great significance to study the influence of transverse landslide affecting the safety of natural gas pipeline when a certain length of pipeline is thrusted, and to establish practical index and simulation method for prediction and prevention of the landslide hazards to gas pipeline. Based on the current research results, this study could be divided into three steps: First of all, with the help of ANSYS finite element software, the model of transverse landslide acting on the gas pipeline can be set up, then the length value of gas pipeline safely withstanding transverse landslide can be calculated;Secondly, using the strength reduction method, which is commonly used in the research of landslide stability, can establish three-dimensional model of the landslide and pipes in the ABAQUS finite element software, next, under the same landslide pushed length, the calculation results will be obtained;Finally, to draw reliable conclusions, all calculated results of the former two methods will be linked to synthetically and comparatively analyze, then the length value of common X80 gas pipeline safely bearing transverse landslide can be got. All results can provide some references for engineering and design.

MECHANICAL PROPERTIES OF LONGITUDINAL SUBMERGED ARC WELDED STEEL PIPES USED FOR GAS PIPELINE OF OFFSHORE OIL

Since the development of offshore oil and gas, increased submarine oil and gas pipelines were installed. All the early steel pipes of submarine pipelines depended on importing because of the strict requirements of comprehensive properties, such as, anti-corrosion, resistance to pressure and so on. To research and develop domes- tic steel pipes used for the submarine pipeline, the Longitudinal-seam Submerged Arc Welded （LSAW） pipes were made of steel plates cut from leveled hot rolled coils by both the JCOE and UOE （the forming process in which the plate like the letter “J”, “C”, “0” or “U” shape, then expansion） forming processes. Furthermore, the mechanical properties of the pipe base metal and weld metal were tested, and the results were in accordance with the corresponding pipe specification API SPEC 5L or DNV- OS-FI01, which showed that domestic LSAW pipes could be used for submarine oil and gas pipelines.

Improved AHP–TOPSIS model for the comprehensive risk evaluation of oil and gas pipelines

A comprehensive and objective risk evaluation model of oil and gas pipelines based on an improved analytic hierarchy process(AHP)and technique for order preference by similarity to an ideal solution(TOPSIS)is established to identify potential hazards in time.First,a barrier model and fault tree analysis are used to establish an index system for oil and gas pipeline risk evaluation on the basis of five important factors:corrosion,external interference,material/construction,natural disasters,and function and operation.Next,the index weight for oil and gas pipeline risk evaluation is computed by applying the improved AHP based on the five-scale method.Then,the TOPSIS of a multi-attribute decision-making theory is studied.The method for determining positive/negative ideal solutions and the normalized equation for benefit/cost indexes is improved to render TOPSIS applicable for the comprehensive risk evaluation of pipelines.The closeness coefficient of oil and gas pipelines is calculated by applying the improved TOPSIS.Finally,the weight and the closeness coefficient are combined to determine the risk level of pipelines.Empirical research using a long-distance pipeline as an example is conducted,and adjustment factors are used to verify the model.Results show that the risk evaluation model of oil and gas pipelines based on the improved AHP–TOPSIS is valuable and feasible.The model comprehensively considers the risk factors of oil and gas pipelines and provides comprehensive,rational,and scientific evaluation results.It represents a new decision-making method for systems engineering in pipeline enterprises and provides a comprehensive understanding of the safety status of oil and gas pipelines.The new system engineering decision-making method is important for preventing oil and gas pipeline accidents.

Dynamical Mechanisms of Effects of Landslides on Long Distance Oil and Gas Pipelines

According to the investigations on the oil and gas pipelines such as the Lan-Cheng-Chong pipeline and the Southwest pipeline, there are two ways of laying pipeline： pipelines paralleling （approximately） to the main slide direction and pipelines perpendicular （approximately） to the main slide direction. If earth-retaining walls have been built for pipelines paralleling to the main slide direction, they will prevent the lands from sliding; On the contrary, without earth-retaining walls, the sharp broken rocks in the backfilling soil will scratch the safeguard of the pipeline when the landslides take place. Pipelines perpendicular to the main slide direction can be classified into four types according to the relative positions between pipelines and landslides： Pipelines over the slide planes, pipelines inside the fracture strips of slide planes, pipelines below the slide planes and pipelines behind the backsides of landslides. The different dynamical mechanisms of the process in which landslide acts against pipelines are analyzed based on whether the pipelines are equipped with fixed frusta, because the sliding resistance depends on whether and how many fixed frusta are equipped and the distance between frusta.

State of art of seismic design and seismic hazard analysis for oil and gas pipeline system

The purpose of this paper is to adopt the uniform confidence method in both water pipeline design and oil-gas pipeline design.Based on the importance of pipeline and consequence of its failure,oil and gas pipeline can be classified into three pipe classes,with exceeding probabilities over 50 years of 2%,5% and 10%,respectively.Performance-based design requires more information about ground motion,which should be obtained by evaluating seismic safety for pipeline engineering site.Different from a city＇s water pipeline network,the long-distance oil and gas pipeline system is a spatially linearly distributed system.For the uniform confidence of seismic safety,a long-distance oil and pipeline formed with pump stations and different-class pipe segments should be considered as a whole system when analyzing seismic risk.Considering the uncertainty of earthquake magnitude,the design-basis fault displacements corresponding to the different pipeline classes are proposed to improve deterministic seismic hazard analysis（DSHA）.A new empirical relationship between the maximum fault displacement and the surface-wave magnitude is obtained with the supplemented earthquake data in East Asia.The estimation of fault displacement for a refined oil pipeline in Wenchuan MS8.0 earthquake is introduced as an example in this paper.

Criterions and Measures of Route Selection of Shallowly Embedded Long-Distance Oil and Gas Pipeline in Mountain Areas

According to the engineering investigation of long-distance oil and gas pipelines, the criterions and measures of route selection are drawn as follows： the flat landform is the first choice in route alignment. The foot of mountain is the first choice when the route passes by the valley. The route should pass by but the shady and deposited slope and not in sunny and erosive slope as possible as it can. The pipeline should be vertical to contour climbing and descending the mountain except steep slope. Tunnel can be used in crossing foothill. Perpendicularly traversing the river is better than beveling; the worst choice is to put the pipeline along the river. Bypass is the best choice in karsts area. The order of route selection should be pre-choosing, investigation, optimization and adjustment.

The Study of Electromagnetic Stress Testing Method on Oil-Gas Pipelines Based on WT

This paper proposes an effective method for early diagnosis (stress concentrating) of the oil-gas pipeline. Based on the principle of electromagnetic induction Faraday, we have designed and realized the nondestructive testing system for stress concentration area of ferromagnetic materials by means of the research of metal materials inverse magnetostrictive effect mechanism. The system changes the influence degree of the stress in ferromagnetic materials’ magnetic conductance to the corresponding voltage array by using discrete wavelet analysis method to process the data, in which not only the measuring accuracy is improved, but also the stress concentration is more directly reflected. The experiments confirm that the electromagnetic stress testing method is feasible and valid.

A Dual-Parameter Fusion Distributed Optical Fiber Sensor System for Oil and Gas Pipeline Monitoring

For oil and gas pipeline monitoring applications, this paper proposed a dual-parameter fusion distributed fiber optic sensor system that enables distributed temperature and distributed vibration measurements in a single fiber. Through the fiber-scattering spectrum time domain detection combined with coded pulse sequence and Raman scattering spectrum is obtained, which realizes high-resolution temperature measurement and wide-band vibrational wave measurement. The experimental results show that, on 10 km optical fiber measurement, temperature resolution up to 0.1?C and vibration response frequency range 20 Hz - 5 kHz. This sensing system achieves temperature and vibration dual-parameter measurements with fiber optics, greatly simplifying the system and facilitating installation and it can be widely used in oil and gas pipeline monitoring.

Analysing Delay Impact from Potential Risk Factors on Project Delivery of Oil and Gas Pipeline:A Case Study in IRAQ

The aim of this paper is to present the design and specifications of an integrated Delay Analysis Framework(DAF),which could be used to quantify the delay caused by the Risk Factors(RFs)in Oil and Gas Pipelines(OGPs)projects in a simple and systematic way.The main inputs of the DAF are(i)the potential list of RFs in the projects and their impact levels on the projects and the estimated maximum and minimum duration of each task.Monte Carlo Simulation integrated within@Risk simulator was the key process algorithm that used to quantify the impact of delay caused by the associated RFs.The key output of the DAF is the amount of potential delay caused by RFs in the OGP project.The functionalities of the developed DAF were evaluated using a case study of newly developed OGP project,in the south of Iraq.It is found that the case study project might have delayed by 45 days if neglected the consideration of the RFs associated with the project at the construction stage.The paper concludes that identifying the associated RFs and analysing the potential delay in advance will help in reducing the construction delay and improving the effectiveness of the project delivery by taking suitable risk mitigation measures.

Main Indexes of Pipeline Transportation of Crude Oil and Gas

ＭａｉｎＩｎｄｅｘｅｓｏｆＰｉｐｅｌｉｎｅＴｒａｎｓｐｏｒｔａｔｉｏｎｏｆＣｒｕｄｅＯｉｌａｎｄＧａｓ￥／／Ｎｏｔｅ：Ｔｈｅｔｏｔａｌｌｅｎｇｔｈｏｆｃｒｕｄｅａｎｄｇａｓｐｉｐｅｌｉｎｅｒｅａｃｈｅｄ１７５８７ｋｍ，ｉｎｃｌｕｄｉｎｇ９２７２ｋｍｏ...