Enzymatic synthesis, antioxidant ability and oil-water distribution coefficient of troxerutin fatty acid esters

Troxerutin fatty acid esters were prepared using troxerutin and fatty acid vinyl esters as substrates in pyridine through enzymatic route. The structures of as-prepared compounds were identified by FT-TR, NMR, and ESI-HRMS. Using alkaline protease(≥30 mg/mL) as enzyme, maximum yields reached 58% at 3:1(vinyl hexanoate to troxerutin) in pyridine(water content ≤1%). The yields gradually declined as chain length of acyl donors rose. The antioxidation abilities of the as-obtained compounds were confirmed by both DPPH free radical scavenging and potassium ferricyanide reduction methods. The antioxidation ability of troxerutin fatty acid esters was found lower than that of troxerutin. However, the logP values of troxerutin fatty acid esters varied from 0.15 to 1.94, suggesting that troxerutin fatty acid esters had better lipophilicity than troxerutin(logP =-2.12) when compared to their oil-water distribution coefficients. Overall, these findings look promising as reference for further development of future troxerutin.

Determination of Equilibrium Distribution Coefficients of Impurities in Phosphorus by Vertical Zone-melting Technique

12 杂质的平衡分发系数(作为， Fe ， Ca ，公司，艾尔， Cr ， Cu ， Mg ， Mn ， Ni ， Pb ， Zn )被测量他们在地区旅行的系数 3 评估的有效分发在磷获得， 5 ， 10 ， 15 ，并且 20

Method for acquiring part load distribution coefficient of air conditioning system

This paper presents a method to acquire runtime distribution ratio of building air conditioning system under part load condition (part load coefficient of system) through practical energy consumption data. By utilizing monthly energy consumption data of the entire year as the analysis object,this paper identifies data distribution,verifies distribution characteristics and analyzes distribution probability density for the issue of running time distribution ratio of air conditioning system in part load zones in the whole operation period,thus providing a basic calculation basis for an overall analysis of energy efficiency of air conditioning system. In view of the general survey of public building energy consumption carried by the government of Chongqing,this paper takes the governmental office building as an example,the part load ratio coefficient corresponding to practical running of air conditioning system of governmental office building in Chongqing is obtained by utilizing the above probability analysis and the solving method of probability density function. By utilizing the ratio coefficient obtained using this method,the part load coefficient with any running ratio of air conditioning system can be obtained according to the requirement of analysis,which can be used in any load ratio for analyzing running energy efficiency of air conditioning system.

Vertical Distribution of Momentum Exchange Coefficient and Sediment Concentration in Estuarine and Coastal Waters

Vertical structures of momentum exchange coefficient and sediment concentration are the keys in the research on estuarine and coastal suspended sediment transport. Based on the parabolic mixing length distribution pattern,the distribution pattern of vertical momentum exchange coefficient which is suitable for estuarine and coastal waters is constructed. A comparison with steady flow and measured momentum exchange coefficient during one tidal cycle in the Menai Strait of England shows that the result of this pattern is closer to the measured values than those of commonly used Rouse's and van Rijn's patterns,and the pattern is also suitable for estuarine and coastal waters. Successively,based on the precondition that momentum exchange coefficient is equivalent to sediment turbulent diffusion coefficient,and combining with the Diffusion Theory,we obtain the exponential vertical distribution pattern of sediment concentration,which is also suitable for estuarine and coastal waters. Thereby,using measured vertical stratified sediment concentration data of the South and the North Passages of the Yangtze Estuary and Zhoushan archipelago waters for fitting calculation,and comparing the results with those from Rouse's (1938) and Zhang et al.'s (1989) formulas,the results show that the exponential vertical distribution pattern of sediment concentration obtained in the present study not only overcomes the defect of Rouse's formula that the surface sediment concentration will be 0,but also has a holistic higher precision along the vertical lines than those of Rouse's and Zhang et al.'s formulas.

A COMPUTATIONAL APPROACH FOR PRESSURE DISTRIBUTION AND ROTORDYNAMIC COEFFICIENTS OF JOURNAL BEARINGS WITH COMBINED RADIAL AND MISALIGNMENT MOTIONS

A computational approach is presented to handle an enlarged linear rotordynamic model whichsimultaneously includes both radial and misalignment motions.The interactive force and momentbetween the rotating and non-rotating members are modeled using an adaptation of the classicalReynolds lubrication equation for incompressible laminar isoviscous films.First,the governingequation is derived and the method of solution is introduced based on a 2-dimension,9-point cen-tral difference.Second,force and moment components are computed by numerical integration ofthe film pressure distribution.Finally,the rotordynamic coefficients are yielded according to thegeneralized force gradients.

Study on Pressure Coefficient Distribution of the Airship Zhiyuan-1

A wind tunnel tests with different configurations,pitch and yaw angles were performed to study the wind load characteristics of the rigid model of the airship Zhiyuan-1. The rigid model was aimed to simulate a technical demonstrating stratospheric airship named Zhiyuan-1 according to the similarity principle of geometric and Reynolds number. Based on the results of wind tunnel test,the features of pressure coefficient distributions on the surface of the airship were described. It was indicated that the fins and the gondola of airship hardly have the effect on the pressure distribution on the surface of airship,but have obviously effect on the local areas near the fins and the gondola.

Study on Distribution Coefficient of Traction Return Current in High-Speed Railway

The distribution coefficient of return current network is an important method to decrease the rail potential. In order to resolve the problem of high rail potential in high-speed railway based on EN50122-1 and Pr EN50170 the distribution coefficient of longitudinal traction return current conductors is calculated through changing the interval of transverse connection. Based on field data and theoretical analysis, the parameters of longitudinal traction return current conductors are calculated. Results indicate that the best distance of the transverse connection is 400 m – 600 m.

Inversion method of bubble size distribution based on acoustic nonlinear coefficient measurement

Measurements of bubble size distribution require the understanding of the acoustic characteristics of the medium.The bubbles show highly nonlinear properties under finite amplitude acoustic excitation,so the acoustic fields from bubble population are easily observed at the second harmonics as well as at the fundamental frequency,which shows that the nonlinear coefficient increases obviously.The inversion method of bubble size distribution based on nonlinear acoustic effects can peel off the influence of complex environment and obtain the size distribution coefficient information of bubbles more accurately.The previous nonlinear inversion methods of bubble size distribution are mostly based on the nonlinear scattering cross-section characteristics of bubbles.However,the stability of inversion is not high enough.In this paper,we introduce a new acoustic inversion method for bubble size distribution,which is based on the nonlinear coefficients of bubble medium.Compared with other inversion methods based on linear or nonlinear scattering cross section,the inversion method based on nonlinear coefficients of bubble medium proposed in this paper shows good robustness in both simulation and experiment.

Effect of current density on distribution coefficient of solute at solid-liquid interface

When current passes through the solid-liquid interface, the growth rate of crystal, solid-liquid interface energy and radius of curvature at dendritic tip will change. Based on this fact, the theoretical relation between the distribution of solute at solid-liquid interface and current density was established, and the effect of current on the distribution coefficient of solute through effecting the rate of crystal growth, the solid-liquid interface energy and the radius of curvature at the dendritic tip was discussed. The results show that as the current density increases, the distribution coefficient of solute tends to rise in a whole, and when the former is larger than about 400 A/cm 2, the latter varies significantly.

Theoretical calculation and experimental study on the load distribution coefficient (LDC) of three-ring gear reducer

In this paper, primary manufacturing and assembling errors of three-ring gear reducer (TRGR) are analyzed. TRGR is a new transmission type whose eccentric phase difference between middle ring plate and side ring plates is 120°. Its mass of middle ring plate is equal to that of side ring plate or 180°, and its mass of middle ring plate is twice of that of side ring plate, which affects load distribution between ring plates. The primary manufacturing and assembling errors include eccentric error of eccentric sheath E_m, internal gear plate E_r and output external gear E_w. A new theoretical method is presented in this paper, which converts load on ring plates into the dedendum bending stress of ring plate to calculate load distribution coefficient (LDC), by means of gap element method(GEM), one of finite element method (FEM). The theoretical calculation and experimental study, which measures ring plate dedendum bending stress by means of sticking strain gauges on the dedendum of middle ring plate internal gear and side ring plate internal gears, are presented. The theoretical calculation and comparison with experiment result of LDC are implemented on two kinds of three-ring gear reducers whose eccentric phase difference between eccentric sheaths is 120° and 180° respectively. The research indicates that the result of theoretical calculation is consistent with that of experimental study. That is to say, the theoretical calculation method is feasible.

Distributed Lagrange Multiplier/Fictitious Domain Finite Element Method for a Transient Stokes Interface Problem with Jump Coefficients

The distributed Lagrange multiplier/fictitious domain(DLM/FD)-mixed finite element method is developed and analyzed in this paper for a transient Stokes interface problem with jump coefficients.The semi-and fully discrete DLM/FD-mixed finite element scheme are developed for the first time for this problem with a moving interface,where the arbitrary Lagrangian-Eulerian(ALE)technique is employed to deal with the moving and immersed subdomain.Stability and optimal convergence properties are obtained for both schemes.Numerical experiments are carried out for different scenarios of jump coefficients,and all theoretical results are validated.

Spatial-temporal distribution of debris flow impact pressure on rigid barrier

Grain composition plays a vital role in impact pressure of debris flow. Current approaches treat debris flow as uniform fluid and almost ignore its granular effects. A series of flume experiments have been carried out to explore the granular influence on the impact process of debris flow by using a contact surface pressure gauge sensor(Tactilus~?, produced by Sensor Products LLC). It is found that the maximum impact pressure for debris flow of low density fluctuates drastically with a long duration time while the fluctuation for flow of high density is short in time, respectively presenting logarithmic and linear form in longitudinal attenuation. This can be ascribed to the turbulence effect in the former and grain collisions and grainfluid interaction in the latter. The horizontal distribution of the impact pressure can be considered as the equivalent distribution. For engineering purposes, the longitudinal distribution of the pressure can be generalized to a triangular distribution, from which a new impact method considering granular effects is proposed.

Examining Inequality in the Public Health Workforce Distribution in the Centers for Disease Control and Prevention(CDCs) System in China, 2008–2017

Objective Allocation of human resources to address inequalities in the public health system has increasingly attracted societal and political attention.Using the Centers for Disease Control and Prevention(CDCs)system of China as an example,we evaluated inequality in the public health workforce distribution across different regions in China between 2008 and 2017,with the aim of providing information for policymakers to support resource allocation and address growing health inequities.Methods We used three standard public health workforce inequality indices-Gini coefficient,Theil L,and Theil T-and spatial autocorrelation analysis to explore spatial clusters of the workforce in different provinces,visualized with geographical tools.Results The aggregate workforce-to-population ratio decreased from 1.47 to 1.42 per 10,000 population from 2008 to 2017,and was consistently lower than the National Health Commission’s(NHC)recommended critical shortage threshold of 1.75.The workforce distribution inequality indices varied by regional socioeconomic and health system development.Geographic clustering of CDCs workforce distribution was evident,with H–H and L–L clusters in western China and the Guangdong-Fujian region,respectively.Conclusions Our study addressed key issues for government and policymakers in allocation of public health human resources.There is an urgent need for careful identification of analytic questions that will help carry out public health functions in the new era,alongside policy implications for an equitable distribution of the public health workforce focusing on the western region and low–low cluster areas.

SORTING RADAR SIGNAL BASED ON WAVELET CHARACTERISTICS OF WIGNER-VILLE DISTRIBUTION

Common sorting method have low sorting rates and is sensitive to the Signal-to-Noise Ratio(SNR),wavelet characteristics of Wigner-Ville distribution are applied to sort unknown complicated radar signal,high sorting accuracy can be got.The Wigner-Ville distribution of received signal is calculated,then it is predigested to two-dimensional characteristics.Using wavelet transformation to extract characteristics from two-dimensional of Wigner-Ville distribution,the best characteristics are selected to be used as sorting parameters.Experiment results demonstrated that the characteristics of eight typical radar emitter signals extracted by this method showed good performance of noise-resistance and clustering at large-scale SNR.

On the Origin of the Apparent Volume of Distribution and Its Significance in Pharmacokinetics

The apparent volume of distribution was defined for the first time as the phase volume that can hold the total amount of a substance at the measured phase substance concentration, in a system composed of two immiscible media that are in contact under conditions of constant phase volumes, at equilibrium. Its value is not affected by the total system solute mass and it only depends on the total system volume, the phase volumes and the affinity of the solute for the two phases in the system. Using this new concept of the apparent volume of distribution, we were able to demonstrate that under certain conditions compartment volumes in multi-compartment and multi-phasic pharmacokinetic models represent the actual physiological volumes of body fluids accessible by drugs. The classical pharmacokinetic models are now fully explained and can be used to provide accurate estimation of the pharmacokinetic parameters for hydrophilic drugs. In contrast, in the absence of tissue-plasma partition coefficients, lipophilic drugs that do not follow a one-compartment model are unlikely to be adequately described with classical multi-compartment pharmacokinetic models.

Distribution Characteristics of Air Anions in Beidaihe in Different Ecological Environments

Qinhuangdao is a provincial municipality under the jurisdiction of Hebei Province and a coastal city in China. Beidaihe is a district under the jurisdiction of Qinhuangdao and is a famous seaside scenic area. Alliance Peak, located in Beidaihe seashore scenic West. Jinshan mouth is the peak of the Union Peak, located in the easternmost Beidaihe waterfront. In this paper, we use the observed data of air negative ions in the Beidaihe, Qinhuangdao, Jinshanzui and Lianfeng Mountains for seven years to study the distribution characteristics of negative air ions in different ecological environments through meteorological observation. Research shows that the annual mean of air anion concentration fluctuates less. The annual mean is 1730 ind·cm-3, and the difference between the highest and lowest concentrations is 535 ind·cm-3. The average air anion concentration was the highest in August at 7785 ind·cm-3 and the lowest in January at 365 ind·cm-3. Negative air ions have obvious spatial characteristics, and negative ion concentrations of the sea and forest air are significantly high. The average annual mean of the sea is 3902 ind·cm-3, and that of the forest is 5403 ind·cm-3. The concentration of air anion changes daily, and daytime concentration is significantly lower than nighttime concentration. The highest peak appears at night or in the morning, while the lowest value appears between noon and afternoon. Inter-annual features and concentration of negative air ions, as well as annual rain days, total rainfall, thunderstorm days, and average relative humidity, are negatively related to the annual average temperature and sunshine hours. However, in the average concentration of negative air ions, the average correlation test of meteorological elements was insignificant. The air anion concentration is negatively correlated with the PM2.5 concentration of fine particulate matter. The concentrations of nitrogen dioxide, sulfur dioxide, and carbon monoxide in the fine particulate matter are negatively correlated with the ozone concentration, which is positively correlated with ozone concentration and is tested by significance. Atmospheric discharge (thunderstorm) can produce a considerable amount of air anion. Air negative ions are an important indicator of air quality, which is of great significance to the living environment. The distribution of negative ions in the study space and its influencing factors in order to provide a basis for air quality assessment in the region and provide references for the long-term research on air anion in different urban areas.

Distribution and deposition of polycyclic aromatic hydrocarbons in precipitation in Guangzhou, South China

Polycyclic aromatic hydrocarbons (PAHs) were measured in precipitation from March to August 2005 in Guangzhou, South China. Fourteen PAHs were studied, and their total concentrations varied from 616.6 to 3486.7 ng/L in dissolved phase and from 403.8 to 3125.5 ng/L in particulate phase. The estimated deposition loading of PAHs was 3568 μg/m2 during the monitoring period. The deposition of PAHs was a potential source for Pearl River comparing with the contents of surface water. In addition, the high concentration in precipitation here implied that PAHs pollution was a potential environmental problem in Guangzhou. Most precipitation concentrations of PAHs in March (the last month in winter in Guangzhou) were higher than in the other months (in rainy season). PAHs inclined to be adsorbed to particulate phase with the increase of molecular weight in rainwater. Combustion of fossil fuel and biomass might be the major source of PAHs, while the direct leakage or volatilization from petroleum products might be insignificant.

Spatiotemporal Characteristics of Reference Evapotranspiration and Its Sensitivity Coefficients to Climate Factors in Huang-Huai-Hai Plain,China

Climate change will have important implications in water shore regions,such as Huang-Huai-Hai(3H)plain,where expected warmer and drier conditions might augment crop water demand.Sensitivity analysis is important in understanding the relative importance of climatic variables to the variation in reference evapotranspiration(ET0).In this study,the 51-yr ET0during winter wheat and summer maize growing season were calculated from a data set of daily climate variables in 40meteorological stations.Sensitivity maps for key climate variables were estimated according to Kriging method and the spatial pattern of sensitivity coefficients for these key variables was plotted.In addition,the slopes of the linear regression lines for sensitivity coefficients were obtained.Results showed that ET0during winter wheat growing season accounted for the largest proportion of annual ET0,due to its long phenological days,while ET0was detected to decrease significantly with the magnitude of 0.5 mm yr-1in summer maize growing season.Solar radiation is considered to be the most sensitive and primarily controlling variable for negative trend in ET0for summer maize season,and higher sensitive coefficient value of ET0to solar radiation and temperature were detected in east part and southwest part of 3H plain respectively.Relative humidity was demonstrated as the most sensitive factor for ET0in winter wheat growing season and declining relativity humidity also primarily controlled a negative trend in ET0,furthermore the sensitivity coefficient to relative humidity increased from west to southeast.The eight sensitivity centrals were all found located in Shandong Province.These ET0along with its sensitivity maps under winter wheat-summer maize rotation system can be applied to predict the agricultural water demand and will assist water resources planning and management for this region.

Vertical root distribution and root cohesion of typical tree species on the Loess Plateau, China

Black locust(Robinia pseudoacacia L.) and Chinese pine(Pinus tabulaeformis Carr.) are two woody plants that are widely planted on the Loess Plateau for controlling soil erosion and land desertification. In this study, we conducted an excavation experiment in 2008 to investigate the overall vertical root distribution characteristics of black locust and Chinese pine. We also performed triaxial compression tests to evaluate the root cohesion(additional soil cohesion increased by roots) of black locust. Two types of root distribution, namely, vertical root(VR) and horizontal root(HR), were used as samples and tested under four soil water content(SWC) conditions(12.7%, 15.0%, 18.0% and 20.0%, respectively). Results showed that the root lengths of the two species were mainly concentrated in the root diameter of 5–20 mm. A comparison of root distribution between the two species indicated that the root length of black locust was significantly greater than that of Chinese pine in nearly all root diameters, although the black locust used in the comparison was 10 years younger than the Chinese pine. Root biomass was also significantly greater in black locust than in Chinese pine, particularly in the root diameters of 3–5 and 5–10 mm. These two species were both found to be deep-rooted. The triaxial compression tests showed that root cohesion was greater in the VR samples than in the HR samples. SWC was negatively related to both soil shear strength and root cohesion. These results could provide useful information on the architectural characteristics of woody root system and expand the knowledge on shallow slope stabilization and soil erosion control by plant roots on the Loess Plateau.

Vertical and temporal distribution of nitrogen and phosphorus and relationship with their influencing factors in aquatic-terrestrial ecotone:a case study in Taihu Lake,China

Vertical and temporal distributions of N and P in soil solution in aquatic-terrestrial ecotone(ATE)of Taihu Lake were investigated,and the relations among N,P,ORP(oxidation reduction potential),TOC,root system biomass and microorganism were studied.As awhole,significant declines in TN,NO3--N,DON(dissolved organic nitrogen)and TP concentration in soil solution have occurred withincrease of the depth,and reached their minima at 60 cm depth,except for NH4+-N,which increased with depth.The concentrationof TP increased gradually from spring to winter in the topsoil,the maximum 0.08 mg/L presented in the winter while the minimum0.03 mg/L in spring.In the deeper layer,the concentration value of TP fluctuated little.As for the NO3--N,its seasonal variation wassignificant at 20 cm depth,its concentration increased gradually from spring to autumn,and decreased markedly in winter.Verticaland temporal distribution of DON is contrary to that of NO3--N.The results also show that the variation of N and P in the percolatebetween adjacent layers is obviously different.The vertical variation of TN,TP,NO3--N,NH4+-N and DON is significant,of which thevariation coeffcient of NO3--N along the depth reaches 100.23%,the highest;while the variation coeffcient of DON is 41.14%,thesmallest.The results of correlation analysis show that the concentration of nitrogen and phosphorus correlate significantly with TOC,ORP,root biomass and counts of nitrifying bacteria.Most nutrients altered much from 20 to 40 cm along the depth.However,DONchanged more between 60 and 80 cm.Results show that soil of 0-60 cm depth is active rhizoplane,with strong capability to removethe nitrogen and phosphorus in ATE.It may suggest that there exists the optimum ecological effciency in the depth of above 60 cm inreed wetland.This will be very significant for ecological restoration and reestablishment.