Bi_2WO_6 was modified by two-dimensional g-C_3N_4(2D g-C_3N_4)via a hydrothermal method.The structure,morphology,optical and electronic properties were investigated by multiple techniques,including X-ray diffraction(X...Bi_2WO_6 was modified by two-dimensional g-C_3N_4(2D g-C_3N_4)via a hydrothermal method.The structure,morphology,optical and electronic properties were investigated by multiple techniques,including X-ray diffraction(XRD),X-ray photoelectron spectroscopy spectra(XPS),Fourier transform infrared spectroscopy(FT-IR),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Ultravioletvisible diffuse reflection spectroscopy(DRS),photocurrent and electrochemical impedance spectroscopy(EIS),electron spin resonance(ESR),respectively.Rhodamine B(Rh B)was used as the target organic pollutant to research the photocatalytic performance of as-prepared composites.The Bi_2WO_6/2D g-C_3N_4exhibited a remarkable improvement compared with the pure Bi_2WO_6.The enhanced photocatalytic activity was because the photogenerated electrons and holes can quickly separate by Z-Scheme passageway in composites.The photocatalytic mechanism was also researched in detail through ESR analysis.展开更多
The films of photocatalysts have been widely used in decomposition pollutants. In this study, the films were successfully prepared from Bi2MoO6 and g-C3N4/Bi2MoO6 by a simple method, respectively. The samples were cha...The films of photocatalysts have been widely used in decomposition pollutants. In this study, the films were successfully prepared from Bi2MoO6 and g-C3N4/Bi2MoO6 by a simple method, respectively. The samples were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, Fourier transform infrared spectroscopy（FTIR）, photoluminescence（PL）, UV-Vis diffuse reflectance spectroscopy（DRS） and electrochemical experiments to investigate crystalline structure, morphology, composition and properties. The photocatalytic activity of the photocatalyst films for the pollutants was evaluated by degradation of methylene blue（MB） in aqueous solution under visible light irradiation. Experiments revealed that the film of g-C3Na/Bi2MoO6 exhibited higher photocatalytic ability compared to the single-component photocatalyst, and proved its stability. The superior catalytic performance can be attributed to the effective separation of electron-hole pairs and the reduced rate of recombination. This work is of great value for the preparation of photocatalysts films.展开更多
基金supported by National Nature Science Foundation of China (21476097, 21776118)Six talent peaks project in Jiangsu Province (2014-JNHB-014)Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Bi_2WO_6 was modified by two-dimensional g-C_3N_4(2D g-C_3N_4)via a hydrothermal method.The structure,morphology,optical and electronic properties were investigated by multiple techniques,including X-ray diffraction(XRD),X-ray photoelectron spectroscopy spectra(XPS),Fourier transform infrared spectroscopy(FT-IR),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Ultravioletvisible diffuse reflection spectroscopy(DRS),photocurrent and electrochemical impedance spectroscopy(EIS),electron spin resonance(ESR),respectively.Rhodamine B(Rh B)was used as the target organic pollutant to research the photocatalytic performance of as-prepared composites.The Bi_2WO_6/2D g-C_3N_4exhibited a remarkable improvement compared with the pure Bi_2WO_6.The enhanced photocatalytic activity was because the photogenerated electrons and holes can quickly separate by Z-Scheme passageway in composites.The photocatalytic mechanism was also researched in detail through ESR analysis.
基金Supported by the National Natural Science Foundation of China（No.21276036）, the National Key Technology Support Program of China（No.2014BAB 12B06）, the Program for Liaoning Excellent Talents in University, China（No.LJQ2015013） and the Fundamental Research Funds for the Central Universities, China（Nos.3132014323, 3132015085）.
文摘The films of photocatalysts have been widely used in decomposition pollutants. In this study, the films were successfully prepared from Bi2MoO6 and g-C3N4/Bi2MoO6 by a simple method, respectively. The samples were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, Fourier transform infrared spectroscopy（FTIR）, photoluminescence（PL）, UV-Vis diffuse reflectance spectroscopy（DRS） and electrochemical experiments to investigate crystalline structure, morphology, composition and properties. The photocatalytic activity of the photocatalyst films for the pollutants was evaluated by degradation of methylene blue（MB） in aqueous solution under visible light irradiation. Experiments revealed that the film of g-C3Na/Bi2MoO6 exhibited higher photocatalytic ability compared to the single-component photocatalyst, and proved its stability. The superior catalytic performance can be attributed to the effective separation of electron-hole pairs and the reduced rate of recombination. This work is of great value for the preparation of photocatalysts films.
