To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB（lithium bis（oxalato）borate） and LiTFSI（lithium bis（trifluoromethanesulfonyl）imide）-LiBOB ...To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB（lithium bis（oxalato）borate） and LiTFSI（lithium bis（trifluoromethanesulfonyl）imide）-LiBOB were investigated as alternative lithium salts to LiPF6 in non-aqueous electrolytes.LiFePO4/Li half cells using LiPF6,LiBF4-LiBOB and LiTFSI-LiBOB slats as lithium salts were investigated by galvanostatic cycling,cyclic voltammetry,thermogravimetric analysis.The results show that LiBF4-LiBOB and LiTFSI-LiBOB mixed salts are much more thermally stable than LiPF6.Corrosion of Al foil in the LiTFSI-based electrolytes can be suppressed successfully by the addition of LiBOB as a co-salt.The electrochemical performance of LiBF4-LiBOB and LiTFSI-LiBOB mixed salts based cells are both better than that of LiPF6-based cell.LiTFSI-LiBOB mixed salt based electrolyte is considered to be a very promising electrolyte candidate for Li-ion batteries that will be used in wide-temperature applications.展开更多
基金Project(2013JSJJ027)supported by the Teacher Research Fund of Central South University,China
文摘To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB（lithium bis（oxalato）borate） and LiTFSI（lithium bis（trifluoromethanesulfonyl）imide）-LiBOB were investigated as alternative lithium salts to LiPF6 in non-aqueous electrolytes.LiFePO4/Li half cells using LiPF6,LiBF4-LiBOB and LiTFSI-LiBOB slats as lithium salts were investigated by galvanostatic cycling,cyclic voltammetry,thermogravimetric analysis.The results show that LiBF4-LiBOB and LiTFSI-LiBOB mixed salts are much more thermally stable than LiPF6.Corrosion of Al foil in the LiTFSI-based electrolytes can be suppressed successfully by the addition of LiBOB as a co-salt.The electrochemical performance of LiBF4-LiBOB and LiTFSI-LiBOB mixed salts based cells are both better than that of LiPF6-based cell.LiTFSI-LiBOB mixed salt based electrolyte is considered to be a very promising electrolyte candidate for Li-ion batteries that will be used in wide-temperature applications.
