With variation of drainage basin environments, desorption of soluble matter has become one of the significant erosion processes in rivers. It has a considerable impact on flow and sediment transport, as well as proces...With variation of drainage basin environments, desorption of soluble matter has become one of the significant erosion processes in rivers. It has a considerable impact on flow and sediment transport, as well as processes of river bed deformation and landform evolution throughout a watershed. In this study, considering influences on sediment movement, especially on cohesive sediment transport, Ca^2＋ and H^＋ were chosen as characteristic ions of soluble matter, and the total desorption quantity of Ca^2＋ and pH value when the desorption equilibrium is reached were employed as two indexes representing the desorption of soluble matter. By means of an indoor experiment, desorption of soluble matter as influenced by cations in static water was investigated. The results show that the total desorption quantity of soluble matter increases with the initial cation concentration until a maximum desorption quantity value is obtained and maintained. The total desorption quantity of soluble matter depends on properties of the specific cations in static water, and the stronger the affinity is between the cation and sediment surface, the higher the total desorption quantity will be. Finally, a strong approximate linear relationship between desorption quantities for different kinds of soluble matters was obtained, which means that variation of pH values can accurately reflect the desorption results of soluble matter.展开更多
In order to enhance coalbed methane recovery, taking a self-developed largecalesimulation system for the platform, a modeling experiment of driving CH_4 by CO_2 gasinjection was studied.The results of experiment indic...In order to enhance coalbed methane recovery, taking a self-developed largecalesimulation system for the platform, a modeling experiment of driving CH_4 by CO_2 gasinjection was studied.The results of experiment indicates that there is a significant lag effectof adsorption and desorption on gas, the gas pressure is changed more rapidly in theprocess of carbon dioxide adsorption of coal than methane adsorption of coal; After theinjection of carbon dioxide, compare with methane single desorption.In an early stage,speed and amount of methane single desorption are greater than the speed and amountof displacement desorption, the speed and amount of displacement desorption becamegreater.In the process of replacement, CH_4 concentration constantly declined, while CO_2concentration constantly rose.In the process of CO_2 gas injection, the temperature of coalhave been significantly increased, it is more beneficial to make CH_4 gas molecules becomefree from the adsorbed state when temperature is increased.Under the pressurestep-down at the same rate, using the method of CO_2 driving CH_4, compared with themethod of conventional pressure step-down, the desorption rate of CH_4 in coal can beraised about 2.13 times, at the same time, a lot of greenhouse gas CO_2 will also be buriedin the ground, there is a very significant environmental benefit.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51209014)the Fundamental Research Funds for the Changjiang River Scientific Research Institute(Grant No.CKSF2013012/TB)
文摘With variation of drainage basin environments, desorption of soluble matter has become one of the significant erosion processes in rivers. It has a considerable impact on flow and sediment transport, as well as processes of river bed deformation and landform evolution throughout a watershed. In this study, considering influences on sediment movement, especially on cohesive sediment transport, Ca^2＋ and H^＋ were chosen as characteristic ions of soluble matter, and the total desorption quantity of Ca^2＋ and pH value when the desorption equilibrium is reached were employed as two indexes representing the desorption of soluble matter. By means of an indoor experiment, desorption of soluble matter as influenced by cations in static water was investigated. The results show that the total desorption quantity of soluble matter increases with the initial cation concentration until a maximum desorption quantity value is obtained and maintained. The total desorption quantity of soluble matter depends on properties of the specific cations in static water, and the stronger the affinity is between the cation and sediment surface, the higher the total desorption quantity will be. Finally, a strong approximate linear relationship between desorption quantities for different kinds of soluble matters was obtained, which means that variation of pH values can accurately reflect the desorption results of soluble matter.
文摘In order to enhance coalbed methane recovery, taking a self-developed largecalesimulation system for the platform, a modeling experiment of driving CH_4 by CO_2 gasinjection was studied.The results of experiment indicates that there is a significant lag effectof adsorption and desorption on gas, the gas pressure is changed more rapidly in theprocess of carbon dioxide adsorption of coal than methane adsorption of coal; After theinjection of carbon dioxide, compare with methane single desorption.In an early stage,speed and amount of methane single desorption are greater than the speed and amountof displacement desorption, the speed and amount of displacement desorption becamegreater.In the process of replacement, CH_4 concentration constantly declined, while CO_2concentration constantly rose.In the process of CO_2 gas injection, the temperature of coalhave been significantly increased, it is more beneficial to make CH_4 gas molecules becomefree from the adsorbed state when temperature is increased.Under the pressurestep-down at the same rate, using the method of CO_2 driving CH_4, compared with themethod of conventional pressure step-down, the desorption rate of CH_4 in coal can beraised about 2.13 times, at the same time, a lot of greenhouse gas CO_2 will also be buriedin the ground, there is a very significant environmental benefit.
