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ELASTIC WAVE LOCALIZATION IN TWO-DIMENSIONAL PHONONIC CRYSTALS WITH ONE-DIMENSIONAL QUASI-PERIODICITY AND RANDOM DISORDER 被引量:8
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作者 Ali Chen Yuesheng Wang +2 位作者 Guilan Yu Yafang Guo Zhengdao Wang 《Acta Mechanica Solida Sinica》 SCIE EI 2008年第6期517-528,共12页
The band structures of both in-plane and anti-plane elastic waves propagating in two-dimensional ordered and disordered (in one direction) phononic crystals are studied in this paper. The localization of wave propag... The band structures of both in-plane and anti-plane elastic waves propagating in two-dimensional ordered and disordered (in one direction) phononic crystals are studied in this paper. The localization of wave propagation due to random disorder is discussed by introducing the concept of the localization factor that is calculated by the plane-wave-based transfer-matrix method. By treating the quasi-periodicity as the deviation from the periodicity in a special way, two kinds of quasi phononic crystal that has quasi-periodicity (Fibonacci sequence) in one direction and translational symmetry in the other direction are considered and the band structures are characterized by using localization factors. The results show that the localization factor is an effective parameter in characterizing the band gaps of two-dimensional perfect, randomly disordered and quasi-periodic phononic crystals. Band structures of the phononic crystals can be tuned by different random disorder or changing quasi-periodic parameters. The quasi phononic crystals exhibit more band gaps with narrower width than the ordered and randomly disordered systems. 展开更多
关键词 phononic crystal quasi phononic crystal DISORDER localization factors plane-wavebased transfer-matrix method periodic average structure
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Investigation of a silicon-based one-dimensional phononic crystal plate via the super-cell plane wave expansion method 被引量:4
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作者 祝雪丰 刘盛春 +2 位作者 徐涛 王铁海 程建春 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第4期316-321,共6页
The super-cell plane wave expansion method is employed to calculate band structures for the design of a siliconbased one-dimensional phononic crystal plate with large absolute forbidden bands. In this method, a low im... The super-cell plane wave expansion method is employed to calculate band structures for the design of a siliconbased one-dimensional phononic crystal plate with large absolute forbidden bands. In this method, a low impedance medium is introduced to replace the free stress boundary, which largely reduces the computational complexity. The dependence of band gaps on structural parameters is investigated in detail. To prove the validity of the super-cell plane wave expansion, the transmitted power spectra of the Lamb wave are calculated by using a finite element method. With the detailed computation, the band-gap of a one-dimensional plate can be designed as required with appropriate structural parameters, which provides a guide to the fabrication of a Lamb wave phononic crystal. 展开更多
关键词 Lamb wave phononic crystal super-cell plane wave expansion band structures
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Influence of temperature on the properties of one-dimensional piezoelectric phononic crystals 被引量:3
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作者 Ahmed Nagaty Ahmed Mehaney Arafa H Aly 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第9期342-345,共4页
The current study investigates the influence of temperature on a one-dimensional piezoelectric phononic crystal using tunable resonant frequencies. Analytical and numerical examples are introduced to emphasize the inf... The current study investigates the influence of temperature on a one-dimensional piezoelectric phononic crystal using tunable resonant frequencies. Analytical and numerical examples are introduced to emphasize the influence of temperature on the piezoelectric phononic crystals. It was observed that the transmission spectrum of a one-dimensional phononic crystal containing a piezoelectric material(0.7 PMN-0.3 PT) can be changed drastically by an increase in temperature.The resonant peak can be shifted toward high or low frequencies by an increase or decrease in temperature, respectively.Therefore, we deduced that temperature can exhibit a large tuning in the phononic band gaps and in the local resonant frequencies depending on the presence of a piezoelectric material. Such result can enhance the harvesting energy from piezoelectric materials, especially those that are confined in a phononic crystal. 展开更多
关键词 phononic crystals resonant modes piezoelectric material thermal properties and temperature
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Propagation behavior of elastic waves in one-dimensional piezoelectric/piezomagnetic phononic crystal with line defects 被引量:2
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作者 Y.Pang F.-Y.Jiao J.-X.Liu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2014年第5期703-713,共11页
Using a stiffness matrix method, we in- vestigate the propagation behaviors of elastic waves in one-dimensional (1D) piezoelectric/piezomagnetic (PE/PM) phononic crystals (PCs) with line defects by calculating e... Using a stiffness matrix method, we in- vestigate the propagation behaviors of elastic waves in one-dimensional (1D) piezoelectric/piezomagnetic (PE/PM) phononic crystals (PCs) with line defects by calculating energy reflection/transmittion coefficients of quasi-pressure and quasi-shear waves. Line defects are created by the re- placement of PE or PM constituent layer. The defect modes existing in the first gap are considered and the influences on defect modes of the material properties and volume fraction of the defect layers, the type of incident waves, the location of defect layer and the number of structural layers are discussed in detail. Numerical results indicate that defect modes are the most obvious when the defect layers are inserted in the middle of the perfect PCs; the types of incidence wave and material properties of the defect layers have important effects on the numbers, the location of frequencies and the peaks of defect modes, and the defect modes are strongly de- pendent on volume fraction of the defect layers. We hope this paper will be found useful for the design of PE/PM acoustic filters or acoustic transducer with PCs structures. 展开更多
关键词 1D phononic crystal Piezoelectric/piezomag- netic. Elastic wave Line defect Stiffness matrix method
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Propagation Characteristics of Flexural Wave in One-Dimensional Phononic Crystals Based on Lattice Dynamics Model 被引量:2
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作者 Hao Wu Youdi Kuang 《Journal of Applied Mathematics and Physics》 2022年第5期1416-1431,共16页
In this paper, we establish discrete flexural lattice chain models of Bragg and locally resonant phononic crystals by setting mass defect atoms and local resonant elements on the flexural lattice chain. The bandgap ch... In this paper, we establish discrete flexural lattice chain models of Bragg and locally resonant phononic crystals by setting mass defect atoms and local resonant elements on the flexural lattice chain. The bandgap characteristics of flexural wave in phononic crystals are studied by establishing the governing equations of the model. The results from models show that with the change of the mass ratio of defective atoms to normal atoms, the bandgap of the flexural wave produced by Bragg scattering shows a certain rule. When the local resonant bandgap and Bragg scattering bandgap are close to each other, the two bandgaps will be coupled to form a wider flexural wave bandgap. The effect of axial strain on bending wave propagation is only the shift of bandgap position. The effect of material damping on the propagation of a bending wave is only energy dissipation at high frequency. In addition, we use finite element simulation to calculate the bandgap of flexural wave in phononic crystals with mass defects, and the results are consistent with lattice chain model. This shows that lattice chain model can effectively guide the bandgap design of phononic crystals. This comprehensive study may help to elucidate the rule of bandgap generation of flexural wave in one-dimensional phononic crystals. 展开更多
关键词 phononic crystals Local Resonance Bragg Scattering DAMPING STRAIN Flexural Wave
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Phonons near Peierls Structural Transition in Quasi-One-Dimensional Organic Crystals of TTF-TCNQ 被引量:2
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作者 Silvia Andronic Anatolie Casian 《Advances in Materials Physics and Chemistry》 2016年第4期98-104,共7页
The Peierls structural transition in quasi-one-dimensional organic crystals of TTF-TCNQ is investigated in the frame of a more complete physical model. The two most important electron-phonon interaction mechanisms are... The Peierls structural transition in quasi-one-dimensional organic crystals of TTF-TCNQ is investigated in the frame of a more complete physical model. The two most important electron-phonon interaction mechanisms are taken into account simultaneously. One is similar of that of deformation potential and the other is of polaron type. For simplicity, the 2D crystal model is considered. The renormalized phonon spectrum and the phonon polarization operator are calculated in the random phase approximation for different temperatures. The effects of interchain interaction on renormalized acoustic phonons and on the Peierls critical temperature are analyzed. 展开更多
关键词 Quasi-one-dimensional Organic crystals TTF-TCNQ Peierls Transition Interchain Interaction Renormalized phonons
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Design of(GO/TiO2)N one-dimensional photonic crystal photocatalysts with improved photocatalytic activity for tetracycline degradation 被引量:5
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作者 Huan-huan Wang Wen-xiu Liu +4 位作者 Jing Ma Qian Liang Wen Qin Patrick Osei Lartey Xiao-jiang Feng 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2020年第6期830-839,共10页
(GO/TiO2)N(GO represents graphene oxide,and N represents the period number of alternate superposition of two dielectrics)onedimensional photonic crystal with different lattice constants was prepared via the sol–gel t... (GO/TiO2)N(GO represents graphene oxide,and N represents the period number of alternate superposition of two dielectrics)onedimensional photonic crystal with different lattice constants was prepared via the sol–gel technique,and its transmission characteristics for photocatalysis were tested.The results show that the lattice constant,filling ratio,number of periodic layers,and incident angle had effects on the band gap.When the lattice constant,filling ratio,number of periodic layers,and incident angle were set to 125 nm,0.45,21,and 0°,respectively,a gap width of 53 nm appeared at the central wavelength(322 nm).The absorption peak of the photocatalyst at 357 nm overlapped the blue edge of the photonic band gap.A slow photon effect region above 96%reflectivity appeared.The degradation rate of tetracycline in(GO/TiO2)N photonic crystal was enhanced to 64%within 60 min.Meanwhile,the degradation efficiency of(GO/TiO2)N one-dimensional photonic crystal was effectively improved compared with those of the GO/TiO2 composite film and GO/TiO2 powder. 展开更多
关键词 one-dimensional photonic crystal translight software transmission characteristics photocatalytic performance slow photon effect
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Ultrasonic scalpel based on fusiform phononic crystal structure
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作者 Sha Wang Junjie Shan Shuyu Lin 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期302-310,共9页
In response to the ultrasonic scalpels with the vibrational modal coupling which leads to a decrease in efficiency,an ultrasonic scalpel based on fusiform phononic crystals(PnCs)is proposed.An accurate theoretical mod... In response to the ultrasonic scalpels with the vibrational modal coupling which leads to a decrease in efficiency,an ultrasonic scalpel based on fusiform phononic crystals(PnCs)is proposed.An accurate theoretical model is constructed,which is mainly composed of electromechanical equivalent circuit models to analyze the frequency response function and the frequency response curves of the admittance.Bragg band gaps exist in the fusiform PnCs owing to the periodic constraint,which can suppress the corresponding vibrational modes.The vibration characteristics(vibration mode,frequency,and displacement distribution)of the ultrasonic scalpel are analyzed,and the validity of the electromechanical equivalent circuit method is verified.The results indicate that other vibration modes near the working frequency can be isolated.In addition,blades based on fusiform PnCs have a function akin to that of the horn,which enables displacement amplification. 展开更多
关键词 phononic crystals ultrasonic scalpel bandgap vibration characteristics
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Inverse design of nonlinear phononic crystal configurations based on multi-label classification learning neural networks
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作者 Kunqi Huang Yiran Lin +1 位作者 Yun Lai Xiaozhou Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期295-301,共7页
Phononic crystals,as artificial composite materials,have sparked significant interest due to their novel characteristics that emerge upon the introduction of nonlinearity.Among these properties,second-harmonic feature... Phononic crystals,as artificial composite materials,have sparked significant interest due to their novel characteristics that emerge upon the introduction of nonlinearity.Among these properties,second-harmonic features exhibit potential applications in acoustic frequency conversion,non-reciprocal wave propagation,and non-destructive testing.Precisely manipulating the harmonic band structure presents a major challenge in the design of nonlinear phononic crystals.Traditional design approaches based on parameter adjustments to meet specific application requirements are inefficient and often yield suboptimal performance.Therefore,this paper develops a design methodology using Softmax logistic regression and multi-label classification learning to inversely design the material distribution of nonlinear phononic crystals by exploiting information from harmonic transmission spectra.The results demonstrate that the neural network-based inverse design method can effectively tailor nonlinear phononic crystals with desired functionalities.This work establishes a mapping relationship between the band structure and the material distribution within phononic crystals,providing valuable insights into the inverse design of metamaterials. 展开更多
关键词 multi-label classification learning nonlinear phononic crystals inverse design
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Sensing the heavy water concentration in an H_(2)O-D_(2)O mixture by solid-solid phononic crystals
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作者 Mohammadreza Rahimi Ali Bahrami 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期493-498,共6页
A new method based on phononic crystals is presented to detect the concentration of heavy water(D_(2)O)in an H_(2)O-D_(2)O mixture.Results have been obtained and analyzed in the concentration range of 0%-10%and 90%-10... A new method based on phononic crystals is presented to detect the concentration of heavy water(D_(2)O)in an H_(2)O-D_(2)O mixture.Results have been obtained and analyzed in the concentration range of 0%-10%and 90%-100%D_(2)O.A proposed structure of tungsten scatterers in an aluminum host is studied.In order to detect the target material,a cavity region is considered as a sound wave resonator in which the target material with different concentrations of D_(2)O is embedded.By changing the concentration of D_(2)O in the H_(2)O-D_(2)O mixture,the resonance frequency undergoes a frequency shift.Each 1%change in D_(2)O concentration in the H_(2)O-D_(2)O mixture causes a frequency change of about 120 Hz.The finite element method is used as the numerical method to calculate and analyze the natural frequencies and transmission spectra of the proposed sensor.The performance evaluation index shows a high Q factor up to 1475758 and a high sensitivity up to 13075,which are acceptable values for sensing purposes.The other figures of merit related to the detection performance also indicate high-quality performance of the designed sensor. 展开更多
关键词 phononic crystals sensor H_(2)O-D_(2)O mixture CAVITY
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Application and optimization design of non-obstructive particle damping-phononic crystal vibration isolator in viaduct structure-borne noise reduction
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作者 SHI Duo-jia ZHAO Cai-you +3 位作者 ZHANG Xin-hao ZHENG Jun-yuan WEI Na-chao WANG Ping 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2513-2531,共19页
The problems associated with vibrations of viaducts and low-frequency structural noise radiation caused by train excitation continue to increase in importance.A new floating-slab track vibration isolator-non-obstructi... The problems associated with vibrations of viaducts and low-frequency structural noise radiation caused by train excitation continue to increase in importance.A new floating-slab track vibration isolator-non-obstructive particle damping-phononic crystal vibration isolator is proposed herein,which uses the particle damping vibration absorption technology and bandgap vibration control theory.The vibration reduction performance of the NOPD-PCVI was analyzed from the perspective of vibration control.The paper explores the structure-borne noise reduction performance of the NOPD-PCVIs installed on different bridge structures under varying service conditions encountered in practical engineering applications.The load transferred to the bridge is obtained from a coupled train-FST-bridge analytical model considering the different structural parameters of bridges.The vibration responses are obtained using the finite element method,while the structural noise radiation is simulated using the frequency-domain boundary element method.Using the particle swarm optimization algorithm,the parameters of the NOPD-PCVI are optimized so that its frequency bandgap matches the dominant bridge structural noise frequency range.The noise reduction performance of the NOPD-PCVIs is compared to the steel-spring isolation under different service conditions. 展开更多
关键词 non-obstructive particle damping phononic crystal vibration isolator band gap optimization floating-slab track bridge structure-borne noise control particle swarm optimization
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Photonic Band Modulation in a Two-Dimensional Photonic Crystal with a One-Dimensional Periodic Dielectric Background 被引量:1
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作者 ZHANG Yan SHI Jun-Jie 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第3期747-752,共6页
A two-dimensional photonic crystal with a one-dimensional periodic dielectric background is proposed. The photonic band modulation effects due to the periodic background are investigated based on the plane wave expans... A two-dimensional photonic crystal with a one-dimensional periodic dielectric background is proposed. The photonic band modulation effects due to the periodic background are investigated based on the plane wave expansion method. We find that periodic modulation of the dielectric background greatly alters photonic band structures, especially for the E-polarization modes. The number, width and position of the photonic band gaps (PBGs) sensitively depend on the structure parameters (the layer thicknesses and dielectric constants) of the one-dimensional periodic background, 展开更多
关键词 photonic band structures two-dimensional photonic crystal one-dimensional periodic dielectric background
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Description and reconstruction of one-dimensional photonic crystal by digital signal processing theory
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作者 张娟 付文鹏 +1 位作者 张荣军 王阳 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第10期200-204,共5页
A method of describing one-dimensional photonic crystals (1DPCs) based on Z-domain digital signal processing theory is presented. The analytical expression of the target band gap spectrum in the digital domain is ob... A method of describing one-dimensional photonic crystals (1DPCs) based on Z-domain digital signal processing theory is presented. The analytical expression of the target band gap spectrum in the digital domain is obtained by the autocorrelation of its impulse response. The feasibility of this method is verified by reconstructing two simple 1DPC structures with a target photonic band gap obtained by the traditional transfer matrix method. This method provides an effective approach to function-guided designs of interference-based band gap structures for photonic applications. 展开更多
关键词 one-dimensional photonic crystal digital signal processing Z-TRANSFORM
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Synthesis, Characterization and Crystal Structure Determination of a Thiocyanato Bridged One-dimensional Polymeric Complex of Cadmium(Ⅱ)
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作者 潘晓静 +2 位作者 党东宾 尚伟丽 王敬平 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第6期673-676,共4页
A new one-dimensional polymeric complex [Cd(SCN)2(H2O)]L (L = N,N′-bis(furan- 2-ylmethylene)hydrazine) has been synthesized and characterized by IR, UV spectra, TG-DTA technique and single-crystal X-ray diffr... A new one-dimensional polymeric complex [Cd(SCN)2(H2O)]L (L = N,N′-bis(furan- 2-ylmethylene)hydrazine) has been synthesized and characterized by IR, UV spectra, TG-DTA technique and single-crystal X-ray diffraction analysis. It crystallizes in triclinic, pace group P1^- with a = 5.9268(8), b = 10.8678(15), c = 13.3671(19) A, α = 109.295(2), β = 95.092(2), γ = 97.8580(10)°, V = 796.70(19)A^3, Z = 2, C12H10CdN4O3S2, Mr = 434.76, μ = 1.648 mm^-1, Dc = 1.812 g/cm^3, F(000) = 428, R = 0.0308 and wR = 0.0769. The crystal structure reveals that the structure of [Cd(SCN)2(H2O)]n features di-μ-1,3-thiocyante bridges and 1D chains. The octahedrally coordinated Cd atom is surrounded by one oxygen atom from water molecule, three S atoms and two N atoms from five di-μ-1,3 thiocyanato bridges. The Cd atoms are connected by two di-μ-1,3 thiocyanato bridges with the Cd(1)…Cd(1A) separation of 4.239(1) A and Cd(1)...Cd(1B) of 5.852(1)/~. In addition, the one-dimensional straight chain structure is further connected by multiform intermolecular N-H…O hydrogen bonds and π-π interactions to form a three-dimensional supramolecular structure. 展开更多
关键词 eadmium(Ⅱ) crystal structure one-dimension thioeyanato bridging
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SYNTHESIS AND CRYSTAL STRUCTURE OF A ONE-DIMENSIONAL POLYMERIC CLUSTER[Mo(μ-S)_2Ag(μ-S)_2·α-MePyH]_n
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作者 Ji Guo LI Xin Quan XIN Department of Chemistry,Nanjing University,Nanjing,China Zhong Yuan ZHOU Kai Bei YU Li LIU Chingdu Center of Analysis and Determination,Academia Sinica,Chengdu,China 《Chinese Chemical Letters》 SCIE CAS CSCD 1990年第3期255-256,共2页
Reaction of (NH_4)_2MoS_4 with AgI in α-MePy gives the title com- pound,an X-ray analysis of which shows that the molecule forms a one-dimensional polymeric chain with continuous metal-metal bonds.
关键词 SYNTHESIS AND crystal STRUCTURE OF A one-dimensional POLYMERIC CLUSTER[Mo AG MePyH
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Design and Optimization of Omnidirectional Band Gap for One-Dimensional Periodic and Quasiperiodic Phononic Heterostructures
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作者 陈赵江 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第1期87-90,共4页
A new kind of one-dimensional multilayer phononie heterostructure is constructed to obtain a broad acoustic omnidirectional reflection (ODR) band. The heterostructure is formed by combining finite periodic phononic ... A new kind of one-dimensional multilayer phononie heterostructure is constructed to obtain a broad acoustic omnidirectional reflection (ODR) band. The heterostructure is formed by combining finite periodic phononic crystals (PnCs) and Fibonacci (or Thue-Morse) quasiperiodic PnCs. From the numerical results performed by the transfer matrix method, it is found that the ODR bands can be enlarged obviously by using the combination of periodic and quasi-periodic PnCs. Moreover, an application of particle swarm optimization in designing and optimizing acoustic ODR bands is reported. With regards to different thickness ratios and periodic numbers in the heterostructure, we give some optimization examples and finally achieve phononic heterostructure with a very broad ODR bandwidth. The result provides a new approach to achieve broad acoustic ODR bandwidth, and will be applied in design of omnidirectional acoustic mirrors. 展开更多
关键词 ODR Design and Optimization of Omnidirectional Band Gap for one-dimensional Periodic and Quasiperiodic phononic Heterostructures
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Metal-Insulator Transition of Peierls Type in Quasi-One-Dimensional Crystals of TTT<sub>2</sub>I<sub>3</sub>
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作者 Silvia Andronic Anatolie Casian 《Advances in Materials Physics and Chemistry》 2017年第5期212-222,共11页
We investigate the metal-insulator transition in quasi-one-dimensional organic crystals of tetrathiotetracene-iodide, TTT2I3, in the 2D model. A crystal physical model is applied which takes into account two the most ... We investigate the metal-insulator transition in quasi-one-dimensional organic crystals of tetrathiotetracene-iodide, TTT2I3, in the 2D model. A crystal physical model is applied which takes into account two the most important hole-phonon interaction mechanisms. One is similar to that of deformation potential and the other is of polaron type. The scattering on defects is also considered and it is crucial for the explanation of the transition. The phonon polarization operator and the renormalized phonon spectrum are calculated in the random phase approximation for different temperatures applying the method of Green functions. We show that the transition is of Peierls type. The effect of lattice distortion on the dispersion of renormalized acoustic phonons is analyzed. 展开更多
关键词 QUASI-one-dimensional Organic crystalS TTT2I3 Polarization Operator Metal-Insulator TRANSITION PEIERLS TRANSITION Interchain Interaction Renormalized phonons
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Controlling the Bandgaps of One-Dimensional TiO2/SiO2, TiO2/SnO2, and SiO2/SnO2 Photonic Crystals Using the Transfer Matrix Method
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作者 Fatimah Alamrani Edreese Alsharaeh 《Optics and Photonics Journal》 CAS 2022年第7期171-189,共19页
One-dimensional photonic crystals (1D PhCs) have a unique ability to control the propagation of light waves, however certain classes of 1D oxides remain relatively unexplored for use as PhCs. Specifically, there has n... One-dimensional photonic crystals (1D PhCs) have a unique ability to control the propagation of light waves, however certain classes of 1D oxides remain relatively unexplored for use as PhCs. Specifically, there has not been a comparative study of the three different 1D PhC structures to compare the influence of layer thickness, number, and refractive index on the ability of the PhCs to control light transmission. Herein, we use the transfer matrix method (TMM) to theoretically examine the transmission of 1D PhCs composed of layers of TiO<sub>2</sub>/SiO<sub>2</sub>, TiO<sub>2</sub>/SnO<sub>2</sub>, SiO<sub>2</sub>/SnO<sub>2</sub>, and combinations of the three with various top and bottom layer thicknesses to cover a substantial region of the electromagnetic spectrum (UV to NIR). With increasing layer numbers for TiO<sub>2</sub>/SiO<sub>2</sub> and SiO<sub>2</sub>/SnO<sub>2</sub>, the edges became sharper and wider and the photonic bandgap width increased. Moreover, we demonstrated that PhCs with significantly thick TiO<sub>2</sub>/SiO<sub>2</sub> layers had a high transmittance for a wide bandgap, allowing for wide-band optical filter applications. These different PhC architectures could enable a variety of applications, depending on the properties needed. 展开更多
关键词 one-dimensional Photonic crystal Photonic Bandgap Transfer Matrix Method Optical Filter Metal Oxides
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One-dimensional Chain Crown Ether Complexes Synthesis and Crystal Structure of ([K(DB18-crown-6)]_(2)(CH_(3)CN))[Pt(SCN)_(4)]
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作者 LI Da-cheng LIU Ying DOU Jian-rain 《聊城大学学报(自然科学版)》 2003年第2期7-8,71,共3页
The complexe{[K(DB18-crown-6)]_(2)(CH_(3)CN)}[Pt(SCN)_(4)]was synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis.The complexe belongs to monoclinic,space group c2/c with cel... The complexe{[K(DB18-crown-6)]_(2)(CH_(3)CN)}[Pt(SCN)_(4)]was synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis.The complexe belongs to monoclinic,space group c2/c with cell dimensions,a=2.5904(8),6=1.3653(4),c-1.84706(6)nm,β=123.811(4)°,V=5-339(3)nm^(3),Z=4,.Dcalcd=l.577 g/cm^(3),F(000)=2552,R_(1)=0.051 l,wR_(2)=0.1411.The complexe shows one-dimensional chain of{[K(DB18-crown-6)]+complex cation and[Pt(SCN),i]2-complex anion bridged by N atom of CHaCN moleculer between two[K(DB18-crown-6)]_(2)[Pt(SCN)_(4)]groups respectively. 展开更多
关键词 one-dimensional chain Pt complex DB18-crown-6 crystal structure
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Band Structure of Three-dimensional Phononic Crystals 被引量:3
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作者 颜琳 赵鹤平 +2 位作者 王小云 黄国盛 彭秀艳 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第2期155-158,共4页
By using the plane-wave-expansion method, the band structure of three-dimension phononic crystals was calculated, in which the cuboid scatterers were arranged in a host with a face-centered-cubic (FCC) structure.The... By using the plane-wave-expansion method, the band structure of three-dimension phononic crystals was calculated, in which the cuboid scatterers were arranged in a host with a face-centered-cubic (FCC) structure.The influences of a few factors such as the component materials, the filling fraction of scatterers and the ratio (RHL) of the scatterer's height to its length on the band-gaps of phononic crystals were investigated.It is found that in the three-dimension solid phononic crystals with FCC structure, the optimum case to obtain band-gaps is to embed high-velocity and high-density scatterers in a low-velocity and low-density host. The maximum value of band-gap can be obtained when the filling fraction is in the middle value. It is also found that the symmetry of the scatterers strongly influences the band-gaps. For RHL>1, the width of the band-gap decreases as RHL increases. On the contrary, the width of the band-gap increases with the increase of RHL when RHL is smaller than 1. 展开更多
关键词 phononic crystals Band-gap Face-centered-cubic (FCC) Plane wave expansion method
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