To realize cross-wedge rolling of shaft parts without a stub bar in a short process,an axial closed-open-type cross-wedge rolling technique was proposed.Based on the strain characteristics in the rolling,evaluation in...To realize cross-wedge rolling of shaft parts without a stub bar in a short process,an axial closed-open-type cross-wedge rolling technique was proposed.Based on the strain characteristics in the rolling,evaluation indices of deformation uniformity were provided,and the DEFORM-3D software was adopted to conduct numerical simulations of the rolling process.The metal flow and strain distribution in all stages of the rolling process were analyzed.It is shown that the strain value of the rolled piece close to the end is relatively high while the overall strain distribution is uniform in the rolling process.When the percentage reduction in area is smaller,the fluctuation range of the equivalent strain will be lower and the overall uniformity of the rolled piece will be better.A variable angle wedge was implemented to make metal flow inward and eliminate concavity.Finally,rolling experiment was performed,which indicate that the shape of the rolled piece obtained is consistent with the simulation results.Concavity value in the rolling is decreased by 92%as compared to conventional open rolling.The research results lay a theoretical basis for realizing closed-open-type cross-wedge rolling without a stub bar.展开更多
The title compound was prepared by the reaction of Mo_3S_4(dtp)_4(H_2O)[ctp=S_2P(OEt)_2] with NaOAc·3H_2O and C_4H_8NCS_2NH_4.Crystallographic data:[Mo_3(μ_3-S)(μ-S)_2(μ-OAc)- (S_2CNC_4H_8)_3(O)_2]·0.5CH_...The title compound was prepared by the reaction of Mo_3S_4(dtp)_4(H_2O)[ctp=S_2P(OEt)_2] with NaOAc·3H_2O and C_4H_8NCS_2NH_4.Crystallographic data:[Mo_3(μ_3-S)(μ-S)_2(μ-OAc)- (S_2CNC_4H_8)_3(O)_2]·0.5CH_2CI_2·2H_2O,Mr=980.18,triclinic,space group P(?),α=12.360(3),b=16.653(6), c=9.206(2)A,α=101.97(2),β=108.32(2),γ=86.14(3)°.V=1759.6(9)A^3,Z=2,Dc=1.85 g/cm^3, F(000)=962,μ(Mo K_α)=16.53 cm^(-1).Final R=0.044 for 4301 reflections with I≥3σ(I).This compound may be regarded as a mixed-valent trinuclear molybdenum cluster{Mo_2(V)Mo(Ⅳ)(μ_3-S)(μ-S)_2- (μ-OAc)(S_2CNC_4H_8)_3(O)_2}.The Mo-Mo distances are 2.783(1),2.833(1)and 3.374(2)A in the Mo_3 non-equilateral triangle and there exist only two Mo-Mo bonds.The cluster was obtained by oxi- dation and ligand substitution of{Mo_3(μ_3-S)(μ-S)_3[μ-S_2P(OEt_2)][S_2P(OEt)_2]_3(H_2O)}.展开更多
基金conducted within the framework of the project LNG-COMSHIP,Greek General Secretariat of Research and Technology Code:12CHN400,and was funded by the European Regional Development Fund(ERDF) and National Resources
基金The authors gratefully acknowledge the support of K.C.Wong Education Foundation.Hong Kong,the National Natural Science Foundation of China(Grant Number 51975301)the Natural Science Foundation of Zhejiang(Grant Number LZI7EO5OOO1).
文摘To realize cross-wedge rolling of shaft parts without a stub bar in a short process,an axial closed-open-type cross-wedge rolling technique was proposed.Based on the strain characteristics in the rolling,evaluation indices of deformation uniformity were provided,and the DEFORM-3D software was adopted to conduct numerical simulations of the rolling process.The metal flow and strain distribution in all stages of the rolling process were analyzed.It is shown that the strain value of the rolled piece close to the end is relatively high while the overall strain distribution is uniform in the rolling process.When the percentage reduction in area is smaller,the fluctuation range of the equivalent strain will be lower and the overall uniformity of the rolled piece will be better.A variable angle wedge was implemented to make metal flow inward and eliminate concavity.Finally,rolling experiment was performed,which indicate that the shape of the rolled piece obtained is consistent with the simulation results.Concavity value in the rolling is decreased by 92%as compared to conventional open rolling.The research results lay a theoretical basis for realizing closed-open-type cross-wedge rolling without a stub bar.
基金Work supported by the National Natural Science Foundation of China.
文摘The title compound was prepared by the reaction of Mo_3S_4(dtp)_4(H_2O)[ctp=S_2P(OEt)_2] with NaOAc·3H_2O and C_4H_8NCS_2NH_4.Crystallographic data:[Mo_3(μ_3-S)(μ-S)_2(μ-OAc)- (S_2CNC_4H_8)_3(O)_2]·0.5CH_2CI_2·2H_2O,Mr=980.18,triclinic,space group P(?),α=12.360(3),b=16.653(6), c=9.206(2)A,α=101.97(2),β=108.32(2),γ=86.14(3)°.V=1759.6(9)A^3,Z=2,Dc=1.85 g/cm^3, F(000)=962,μ(Mo K_α)=16.53 cm^(-1).Final R=0.044 for 4301 reflections with I≥3σ(I).This compound may be regarded as a mixed-valent trinuclear molybdenum cluster{Mo_2(V)Mo(Ⅳ)(μ_3-S)(μ-S)_2- (μ-OAc)(S_2CNC_4H_8)_3(O)_2}.The Mo-Mo distances are 2.783(1),2.833(1)and 3.374(2)A in the Mo_3 non-equilateral triangle and there exist only two Mo-Mo bonds.The cluster was obtained by oxi- dation and ligand substitution of{Mo_3(μ_3-S)(μ-S)_3[μ-S_2P(OEt_2)][S_2P(OEt)_2]_3(H_2O)}.
