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Room-temperature operating extended short wavelength infrared photodetector based on interband transition of InAsSb/GaSb quantum well 被引量:1
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作者 孙令 王禄 +7 位作者 鲁金蕾 刘洁 方俊 谢莉莉 郝智彪 贾海强 王文新 陈弘 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第4期396-400,共5页
Here in this paper,we report a room-temperature operating infrared photodetector based on the interband transition of an In As Sb/Ga Sb quantum well.The interband transition energy of 5-nm thick In As(0.91)Sb(0.09... Here in this paper,we report a room-temperature operating infrared photodetector based on the interband transition of an In As Sb/Ga Sb quantum well.The interband transition energy of 5-nm thick In As(0.91)Sb(0.09) embedded in the Ga Sb barrier is calculated to be 0.53 e V(2.35μm),which makes the absorption range of In As Sb cover an entire range from short-wavelength infrared to long-wavelength infrared spectrum.The fabricated photodetector exhibits a narrow response range from 2.0μm to 2.3μm with a peak around 2.1μm at 300 K.The peak responsivity is 0.4 A/W under-500-m Vapplied bias voltage,corresponding to a peak quantum efficiency of 23.8%in the case without any anti-reflection coating.At 300 K,the photodetector exhibits a dark current density of 6.05×10^-3A/cm^2 under-400-m V applied bias voltage and 3.25×10^-5A/cm^2 under zero,separately.The peak detectivity is 6.91×10^10cm·Hz^1/2/W under zero bias voltage at 300 K. 展开更多
关键词 InAsSb/GaSb quantum well interband transition PHOTODETECTOR room temperature operating
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High-sensitive terahertz detection by parametric up-conversion using nanosecond pulsed laser 被引量:1
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作者 王与烨 聂港 +6 位作者 胡常灏 陈锴 闫超 吴斌 朱军峰 徐德刚 姚建铨 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第2期336-341,共6页
A high-sensitive terahertz detector operating at room temperature was demonstrated based on parametric upconversion.A nanosecond 1064-nm Nd:YAG laser was used to pump the parametric up-conversion detector and the upco... A high-sensitive terahertz detector operating at room temperature was demonstrated based on parametric upconversion.A nanosecond 1064-nm Nd:YAG laser was used to pump the parametric up-conversion detector and the upconversion from terahertz wave to NIR laser was realized in a lithium niobate crystal.The minimum detectable terahertz energy of 9 p J was realized with the detection dynamic range of 54 d B,which was three orders of magnitude higher than that of commercial Golay cell.The detectable terahertz frequency range of the detection system was 0.90 Thz–1.83 THz.Besides,the effects of pump energy and effective gain length on the detection sensitivity were studied in experiment.The results showed that higher pump energy and longer effective gain length are helpful for improving the detection sensitivity of parametric up-conversion detector. 展开更多
关键词 terahertz wave high-sensitive detection room temperature operation parametric up-conversion
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用于室温全固态锂金属电池的精准丁二腈官能团化聚氧化乙烯固态电解质
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作者 李新阳 张宗楠 +6 位作者 封婕 阴祥凯 崔晓峰 徐巍 张宏俊 曾荣 丁书江 《Science China Materials》 SCIE EI CAS CSCD 2024年第5期1412-1421,共10页
聚环氧乙烷(PEO)聚合物电解质有望应用于全固态锂金属电池.然而,目前还没有提出有效的方法制备全固态PEO电解质,以克服其在室温下无法使用的局限性.在本研究中,我们基于聚合物C-H键功能化策略,通过在聚合物链上直接共价连接具有锂配位... 聚环氧乙烷(PEO)聚合物电解质有望应用于全固态锂金属电池.然而,目前还没有提出有效的方法制备全固态PEO电解质,以克服其在室温下无法使用的局限性.在本研究中,我们基于聚合物C-H键功能化策略,通过在聚合物链上直接共价连接具有锂配位活性的丁二腈官能团,设计出了一种高离子导电性PEO电解质.该官能团有效增强了PEO链的无序性和流动性,同时也作为链间快速离子传导的活性位点,从而实现了离子周围自由体积和迁移行为的双重优化.得益于官能团对离子输运的精准调节,新型电解质表现出更强的离子传导性(离子电导率提升100倍)、更高的转移数(tLi+=0.51)和更宽的电化学窗口(>0.47 V).特别是功能化的PEO300k电解质具有超高室温离子电导率(25℃时为1.01×10^(-4)S cm^(-1))并且能够在室温下稳定工作,该研究为开发具有实际应用价值的聚合物电解质提供了新的途径. 展开更多
关键词 all-solid-state lithium battery PEO electrolyte polymer functionalization room temperature operation fast ionic conduction
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Stable operation of polymer electrolyte-solid-state batteries via lonepair electron fillers 被引量:1
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作者 Hongbin Liu Qing Sun +8 位作者 Jun Cheng Hongqiang Zhang Xiao Xu Yuanyuan Li Zhen Zeng Yue Zhao Deping Li Jingyu Lu Lijie Ci 《Nano Research》 SCIE EI CSCD 2023年第11期12727-12737,共11页
Due to the increasing demand and wide applications of lithium-ion batteries,higher requirements have been placed on the energy density and safety.Polymer solid-state electrolytes have gained significant popularity due... Due to the increasing demand and wide applications of lithium-ion batteries,higher requirements have been placed on the energy density and safety.Polymer solid-state electrolytes have gained significant popularity due to their excellent interface compatibility and safety.However,their applications have been greatly restricted by the high crystallinity at room temperature,which hinders the transport of lithium ions.Herein,we utilize inorganic tubular fillers with abundant lone-pair atoms to reduce the crystallinity of the polyethylene oxide(PEO)solid-state electrolyte membrane and improve its ionic conductivity at room temperature,enabling stable operation of the battery.The tubular lone-pair-rich inorganic fillers play a key role in providing avenues for both internal and external charge transportation.The surface lone-pair electrons facilitate the dissociation and transport of lithium ions,while the internally tubular electron-rich layer attracts ions into the cavities,further enhancing the ion transport.After 100 cycles at room temperature,the lithium battery loaded with this solid-state electrolyte membrane delivers a specific capacity of 141.6 mAh·g−1,which is 51.3%higher compared to the membrane without the fillers. 展开更多
关键词 nanotube filler polymer electrolyte ion transport room temperature(RT)operation
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