An 8-Connected Chiral Lanthanide Metal-organic Framework Constructed from Naturally Camphoric Acid:Crystal Structure,Vibrational Circular Dichroism Spectroscopy and Second-order Nonlinear Optical Effect

A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.

Analysis of atom detection via the magnetic optical effect

We demonstrated a new method of atom detection by means of the magnetic optical effect. The number density of the atom cloud was measured by detecting the rotation angle of the polarization plane of linearly polarized probe light when propagating inside the atomic cloud. Detuning, the magnetic field and light intensity dependencies of the rotation angle were studied theoretically and experimentally to find the best parameter for atom detection. In this way, we managed to achieve a rotation angle of 0.22 rad with a signal to noise ratio （SNR） of 75 and a contrast of 87.5%.

OPTICAL EFFECTS OF ANION ADSORPTION ON SILVER SOL

The optical effects of anion adsorption on silver sol have been studied, It was found that the anion adsorption can make the absorption peak of pure silver sol shifting to longer vevelenngth, which is attributed to the reduction of the free electron density in the surface layer of the silver particle.

Exciton-polaritons in a 2D hybrid organic-inorganic perovskite microcavity with the presence of optical Stark effect

This study investigates the properties of exciton-polaritons in a two-dimensional(2D)hybrid organic-inorganic perovskite microcavity in the presence of optical Stark effect.Through both steady and dynamic state analyses,strong coupling between excitons of perovskite and cavity photons is revealed,indicating the formation of polaritons in the perovskite microcavity.Besides,it is found that an external optical Stark pulse can induce energy shifts of excitons proportional to the pulse intensity,which modifies the dispersion characteristics of the polaritons.

Detailed Routing Algorithm with Optical Proximity Effects Constraint

We present a detailed routing algorithm considering the optical proximity effect. The light intensity is calculated beforehand and stored in look-up tables. These costs are used as a constraint to guide the sequential routing. The routing algorithm is based on constructed force directed Steiner tree routing to enhance routing efficien- cy. Experimental results on industrial benchmark circuits show that the presented routing algorithm can obtain much improvement considering optical effects short runtime.

Bioapplications Manipulated by AIEgens with Nonlinear Optical Effect

The modern medicine requires precise diagnostic techniques while the fluorescent imaging shows great potential in such applications due to its excellent sensitivity and high resolution.However,conducting fluorescent imaging in deep-tissue is not so easy because most luminogens show short-wavelength excitation,which may undergo severe light scattering by the bio-tissue.The marriage of fluorescent imaging with nonlinear optical(NLO)effect can alleviate such adverse effects by utilizing NIR laser to reduce light scattering.On the other hand,scientists are enthusiastic in pursuing luminescent materials,which can match well with NLO application.Aggregation-induced emission(AIE)materials exhibit huge advantages in such aspect not only because of its high luminescent efficiency in aggregate state but also due to its excellent photo-stability(a key factor to meet laser application because of its ultrahigh energy density).Inspired by this,many interesting and meaningful works have sprung up based on AIE luminogens with NLO effect in recent years,and for such reason,it motivates us to summarize them to give a systematic presentation.Here,we first give a brief introduction of the principle of NLO effect.Secondly,the strategies for improving the NLO effect of AIE materials,such as increasing molecular conjugation,introduction of donor-acceptor effect,induction of centrally asymmetric array of AIE molecules in crystals and introduction of intermolecular interactions are clarified.In the final part,we also present the multiple applications of AIEgens with NLO effect in cell imaging,deep-tissue tumor and brain blood vessel imaging and photodynamic therapy.We believe,with this review,the topic will attract more attention from the scientists in multi-science field to accelerate the development of AIE materials in biomedical applications.

Effectively modulating spatial vortex four-wave mixing in a diamond atomic system

Due to the spatial characteristics of orbital angular momentum,vortex fields can be applied in the fields of quantum storage and quantum information.We study the realization of spatially modulated vortex fields based on four-wave mixing in a four-level atomic system with a diamond structure.The intensity and spiral phase of the vortex field are effectively transferred to the generated four-wave mixing field.By changing the detuning of the probe field,the phase and intensity of the generated vertex four-wave mixing field can be changed.When the probe field takes a large detuning value,the spatial distribution of the intensity and phase of the vertex four-wave mixing field can be effectively tuned by adjusting the Rabi frequency or detuning value of the coupled field.At the same time,we also provide a detailed explanation based on the dispersion relationship,and the results agree well with our simulation results.

Fluctuations of optical phase of diffracted light for Raman–Nath diffraction in acousto–optic effect

The Raman–Nath diffraction in acousto–optic effect was studied theoretically and experimentally in the paper. Up to now, each order of diffracted light in Raman–Nath diffraction was still considered simply to be just frequency-shifted and to be a plane wave. However, we find that the phase and frequency shifts occur simultaneously and individually in Raman–Nath diffraction. The findings demonstrate that, in addition to the frequency shift, the optical phase of each order of diffracted light is also shifted by the sound wave and fluctuates with the sound wave and is related to the location in the acoustic field from which the diffracted light originates. As a result, the wavefront of each order of diffracted light is modulated to fluctuate spatially and temporally with the sound wave. Obviously, these findings are significant for applications of Raman–Nath diffraction in acousto–optic effect because the optical phase plays an important role in optical coherence technology.

Theoretical analysis of the optical rotational Doppler effect under atmospheric turbulence by mode decomposition

The optical rotational Doppler effect associated with orbital angular momentum provides a new means for rotational velocity detection.In this paper,we investigate the influence of atmospheric turbulence on the rotational Doppler effect.First,we deduce the generalized formula of the rotational Doppler shift in atmospheric turbulence by mode decomposition.It is found that the rotational Doppler signal frequency spectrum will be broadened,and the bandwidth is related to the turbulence intensity.In addition,as the propagation distance increases,the bandwidth also increases.And when C_(n)^(2)≤5×10^(-15)m^(-2/3)and 2z≤2 km,the rotational Doppler signal frequency spectrum width d and the spiral spectrum width d_(0)satisfy the relationship d=2d_(0-1).Finally,we analyze the influence of mode crosstalk on the rotational Doppler effect,and the results show that it destroys the symmetrical distribution of the rotational Doppler spectrum about 2l·Ω/2π.This theoretical model enables us to better understand the generation of the rotational Doppler frequency and may help us better analyze the influence of the complex atmospheric environment on the rotational Doppler frequency.

Optical Absorption Enhancement Effects of Silver Nanodisk Arrays in the Application of Silicon Solar Cell

Surface plasmon resonance of noble metal nanoparticles leads to the optical absorption enhancement effects,which have great potential applications in solar cell.By using the general numerical method of discrete dipole approximation （DDA）,we study the absorption and scattering properties of two-dimensional square silver nanodisks （2D SSN） arrays on the single crystal silicon solar cell.Based on the effective reflective index model of the single crystal silicon solar cell,we investigate the optical enhancement absorption of light energy by varying the light incident direction,particle size,aspect ratio,and interparticle spacing of the silver nanodisks.The peak values and position of the optical extinction spectra of the 2D square arrays of noble metal nanodisks are obtained with the different array structures.

Delay Effect on Coherent Transfer of Optical Frequency Based on a Triple-Pass Scheme

We demonstrate a triple-pass scheme for coherent transfer of optical frequency and the delay effect on the fiber phase noise compensation. It is theoretically proved that the delay effect consists of both fiber delay and servo delay. The delay effect confines the servo bandwidth within 1/8 and induces a residual fiber phase noise after noise compensation. For a 25-km-long fiber, the servo bandwidth is found to be around 1 k Hz, and the fiber phase noise is suppressed approaching to the theoretical limitation. The triple-pass scheme enables the simultaneous transfer of optical frequency to multiple remote users. The performance of noise compensator in the triple-pass scheme can achieve a similar level result compared with that in the double-pass scheme.

Ultrafast Optical Kerr Effect of ConjugatedSilver Phenylacetylide Complex Oligomer

Silver phenylacetylide oligomer was found to exhibit prominent third-order nonlinear optical property, with susceptibility chi((3)) of 2.4x10(-14) esu (10(-4) mol/L in 1:1 dimethyl sulfoxide/CHCl3 mixed solution) and second-order hyperpolarizability gamma of 5.18x10(-32) esu via heterodyned ultrafast optical Kerr effect measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.

QUANTITATIVE CONTROL OF OPTICAL CLEARING EFFECTS STUDIED WITH TISSUE-LIKE PHANTOM

Tissue optical clearing by use of optical clearing agents(OCAs)has been proven to have potential to reduce the highly scattering effect of biological tissues in optical techniques.However,the difference in tissue samples could lead to unreliable results,making it difficult to quantitatively control the dose of OCAs during the course of tissue optical clearing.In this work,in order to study the effects of optical clearing,we customized tissue-like phantoms with optical properties of some biological tissue.Diffuse reflectance and total transmittance of tissue-like phantoms with different OCAs(DMSO or glycerol)and porcine skin tissues were measured.Then optical property parameters were calculated by inverse adding-doubling(IAD)algorithm.Results showed that OCAs could lead to a reduction in scattering of tissue-like phantoms as it did to porcine skin tissue in vitro.Furthermore,a series of relational expressions could be fit to quantitatively describe the relationship between the doses of OCAs and the reduction of scattering effects.Therefore,proper tissue-like phantom could facilitate optical clearing to be used in quantitative control of tissue optical properties,and further promote the application potential of optical clearing to light-based noninvasive diagnostic and therapeutic techniques.

Effect of Oxygen Concentration and Annealing Theatment on the Optical Properties of the Transparent Conductive CdIn_2O_4 Thin Films

Transparent conductive cadmium indium oxide films (CdIn2O4) were prepared by r.f. reactive sputtering from Cd-In alloy targets under an Ar-O2 atmosphere. Electrical conductivity of the order of 105Ω-1.m-1 and the optical transmission as high as 94% are easily attained by postdeposition annealing treatment. The effects of oxygen concentration in the reactive gas mixture and post-deposition annealing treatment on the optical transmittance as well as optical parameters, such as refractive index (n), extinction coefficient (k), real part (ε') and imaginary part (ε') of the dielectric constant, were studied in the visible and near-infrared region. The highfrequency dielectric constant ε∞ the plasma frequency ωP, and the conduction band effective mass mc of different samples were also investigated

Effect of Optical Microcavity on Absorption Behavior of Homo-Tandem Organic Solar Cells

The optical microcavity effect of the homo-tandem solar cells is explored utilizing the transfer matrix method. Ultrathin silver can reduce the deadzone effect compared with graphene and PH1000, and leads to a factor of 1.07 enhancement for an electrical field in a metal microcavity. The enhancement is considered to be the fact that strong exciton-photon coupling occurs in the microcavity due to ultrathin Ag. On the basis of the optical enhancement effect, optical behaviors are manipulated by varying the microcavity length. It is confirmed that ultrathin silver can serve as an ideal interconnection layer as the active layer is ～ 150nm thick and the thickness ratio between front and rear active layers lies between 1：1 and 1：2.

Copper Ion Beam Irradiation-Induced Effects on Structural,Morphological and Optical Properties of Tin Dioxide Nanowires

The 0.8 Me V copper （ Cu） ion beam irradiation-induced effects on structural, morphological and optical properties of tin dioxide nanowires （Sn02 NWs） are investigated. The samples are irradiated at three different doses 5 × 10^12 ions/cm2, 1 ×10^13 ions/cm2 and 5 × 10^13 ions/em2 at room temperature. The XRD analysis shows that the tetragonal phase of Sn02 NWs remains stable after Cu ion irradiation, but with increasing irradiation dose level the crystal size increases due to ion beam induced coalescence of NWs. The FTIR spectra of pristine Sn02 NWs exhibit the chemical composition of SnO2 while the Cn-O bond is also observed in the FTIR spectra after Cu ion beam irradiation. The presence of Cu impurity in SnO2 is further confirmed by calculating the stopping range of Cu ions by using TRM/SRIM code. Optical properties of SnO2 NWs are studied before and after Cu ion irradiation. Band gap analysis reveMs that the band gap of irradiated samples is found to decrease compared with the pristine sample. Therefore, ion beam irradiation is a promising technology for nanoengineering and band gap tailoring.

Brightness of Blue/Violet Luminescent Nano-Crystalline AZO and IZO Thin Films with Effect of Layer Number:For High Optical Performance

From different reports, it （AZO） and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide （IZO） thin films with their optical, luminescence and surface properties establish an assessment to carry out further information to summarize AZO and IZO impact of the layer number.

Crystal Structure of (γ-CH_3C_5H_4N)_2Zn(S_2C_2(CN)_2)and the Second Harmonic Effect

The title compound (γ-CH3C5H4N)2Zn(S2C2 (CN )2 ) crystallizes in theorthorhombic system, space group C2221, with a= 10. 069 (2), b= 14. 629 (4), c=11. 923(4) A, V= 1756. 2(3) A3, Dc= 1. 48g/cm3, Z=4, Mr= 391.81. λ(MoKa)= 0. 71069 A, μ= 16. 6 cm--l, F(000) = 800, final R= 0. 055 and Rw= 0. 066 for.1481 observed reflections with I≥3σ(I). In the (γ-CH3C5H4N)2Zn(S2C2(CN)2 ) complex, Zn2+ is coordinated by two nitrogen atoms from two 4--methylpyridine ligands andtwo sulfur atoms from maleonitriledithiol ligand. The powder tests show a frequencydoubling effect 2. 4 times as great as KH2PO4, which is in consistency with theoreticalcalculations

Sensitivity enhancement of micro-optical gyro with photonic crystal

We propose a core rotation-sensing element for improving the sensitivity of the micro-optical gyroscope using the large nonreciprocal effect with a photonic crystal.The sharp transmission peak of electromagnetically induced transparency in photonic crystal generated from a periodic distribution of cold atoms is sensitive to the rotation.Our numerical results show that the sensitivity of relative rotation is about 50 times higher and the sensitivity of absolute rotation is more than two orders higher than that of the traditional resonant optical gyroscope.Also,the sensitivity of the gyroscope can be manipulated by varying the atomic density,modulation frequency,probe pulse width,and photonic crystal length,etc.

Coherent population trapping magnetometer by differential detecting magneto–optic rotation effect

A pocket coherent population trapping（CPT） atomic magnetometer scheme that uses a vertical cavity surface emitting laser as a light source is proposed and experimentally investigated.Using the differential detecting magneto–optic rotation effect,a CPT spectrum with the background canceled and a high signal-to-noise ratio is obtained.The experimental results reveal that the sensitivity of the proposed scheme can be improved by half an order,and the ability to detect weak magnetic fields is extended one-fold.Therefore,the proposed scheme is suited to realize a pocket-size CPT magnetometer.