"Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Pro..."Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Province had reached through several decades studies,but geological environment was very complex in the southeastern Yunnan,and Carlin-type gold deposits produced in the southeastern Yunnan were different from that of America,few studies were taken there.Based on a large number of field work,studies on the geological characteristics combining with geochemistry characteristics were taken,and analysis the genesis of Laozhaiwan gold deposit.The types of alteration in Laozhaiwan gold deposit were mainly silicification and pyritization,and Gold grade was high when silicification and pyritization were both occurred.It could be caculated that fluid density(g/cm3)varied from 0.7 to 4.9,salinity varied from 0.76%to 0.95%and ore-forming pressure(Pa)varied from 1.81×105 to 49.96×105 according to fluid inclusion test results,showed that Laozhaiwan gold deposit was hypabyssal hydrothermal deposit in low temperature and low salinity.According to composition of fluid inclusion analysis,combining with H-O isotope,made theδD-δ18O figure,showed that the fluid of the deposit rooted in formation water and mixed with meteoric waters later.展开更多
[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well a...[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well as Quaternary System(Q).Analysis on the migrating features of soil heavy metal from each stratum to tea leaves showed that the enrichment ability of elements was Cu>Cd>Zn>Ni>Hg>As>Cr>Pb.By comparing the soil background values with the soil base values of Sichuan hilly area and Chengdu economic region,it could be concluded that Cd,Hg,Mo,Pb and Se were enriched,and other metal elements existed at a level close to that of the comparing areas.The pH was a little acidic,and high quality tea cultivation could be developed here at present.With the increase of human activities,the environment of study area tends to deteriorate.Therefore,land planning and use should be reasonable.The government should control the environment nearby and prevent pollution.展开更多
The flooding and drainage of paddy fields has great effects on the transformation of heavy metals, however, the transformation of Cr in basalt-derived paddy soil with high geological background values was less recogni...The flooding and drainage of paddy fields has great effects on the transformation of heavy metals, however, the transformation of Cr in basalt-derived paddy soil with high geological background values was less recognized. The typical basalt-derived paddy soil was incubated under alternating redox conditions. The Cr fractions and the dynamics of Fe/N/S/C were examined. The HCl-extractable Cr increased under anaerobic condition and then decreased during aerobic stage. The UV-vis spectra of the supernatant showed that amounts of colloids were released under anaerobic condition, and then re-aggregated during aerobic phase. The scanning transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS) revealed that Fe oxides were reduced and became dispersed during anaerobic stage, whereas Fe(Ⅱ) was oxidized and recrystallized under aerobic condition. Based on these results, a kinetic model was established to further distinguish the relationship between the transformation of Cr and Fe. During anaerobic phase, the reduction of Fe(Ⅲ) oxides not only directly released the structurally bound Cr, but also enhanced the breakdown of soil aggregation and dissolution of organic matter causing indirect mobilization of Cr. During aerobic phase, the oxidation of Fe (Ⅱ) and further recrystallization of newly formed Fe(Ⅲ) oxides might induce the re-aggregation of soil colloids and further incorporation of Cr. In addition,the kinetic model of Cr and Fe transformation was further verified in the pot experiment.The model-based findings demonstrated that the Cr transformation in the basalt-derived paddy soil with high geological background values was highly driven by redox sensitive iron cycling.展开更多
The Neoproterozoic-Cambrian(N-C) and Permian-Triassic(P-T) transitions have been regarded the two most critical transitions in earth history because of the explosive biological radiation in the early Cambrian(the Camb...The Neoproterozoic-Cambrian(N-C) and Permian-Triassic(P-T) transitions have been regarded the two most critical transitions in earth history because of the explosive biological radiation in the early Cambrian(the Cambrian Explosion) and the largest mass extinction at the end-Permian.Previous studies suggest that these two critical transitions showed certain comparability in major evolutionary events.In other words,a series of biological,geological,and geochemical events that had happened in the N-C transition occurred repeatedly during the P-T transition.Those events included continental re-configuration related to the deep mantle dynamics,global-scale glaciations,large C-,Sr-,and S-isotope perturbations indicating atmospheric and oceanic changes,abnormal precipitation of carbonates,and associated multiple biological radiations and mass extinctions.The coupling of those events in both N-C and P-T transitions suggests that deep mantle dynamics could be a primary mechanism driving dramatic changes of environment on the earth's surface,which in turn caused major biological re-organizations.A detailed comparison of those events during the two critical transitions indicates that despite their general comparability,significant differences do exist in magnitude,duration,and frequency.The supercontinent Rodinia began to rift before the Snowball Earth time.By contrast,the supercontinent Pangea entered the dispersal stage after the greatest glaciation from the Late Carboniferous to Cisuralian.Quantitative data and qualitative analyses of different fossil groups show a more profound mass extinction during the N-C transition than at the end-Permian in terms of ecosystem disruption.This is indicated by the disappearance of the whole Ediacaran biota at the N-C boundary.The subsequent appearances of many new complex animals at phylum level in the early Cambrian mark the establishment of a brand new ecosystem.However,the end-Permian mass extinction is manifested mainly by the extinction of many different taxa at class and order levels.Although it caused the extinction of 95% of marine species and 75% of terrestrial species as well as complete cessation of coal and reef deposits after the mass extinction,this high-level biological re-organization still occurred within an established ecosystem,however drastic it may seem.Survived or Lazarus taxa re-occupied the existing ecospace in a relatively short duration after the end-Permian mass extinction.C-isotope excursions display large perturbations during both transitions,yet also in different magnitudes and frequencies,which suggest different atmospheric and oceanic conditions.The recurrent geological and geochemical events as well as the coupled major biological turnovers during the two transitions provide new clues to understanding the interplays among the earth-life system.Thus,it is essential to carry out multidisciplinary studies from the deep internal system to the surface of the Earth as a whole in order to unravel the interactions of different spheres of the earth.展开更多
基金financially supported by the Program of National Natural Science Foundation of China(No.41372093No.40930423+2 种基金No.41171302)the work item of China Geological Survey(No.12120113036200)higher education quality engineering project of chalcography excellent textbook Construction(No.XJC1105)
文摘"Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Province had reached through several decades studies,but geological environment was very complex in the southeastern Yunnan,and Carlin-type gold deposits produced in the southeastern Yunnan were different from that of America,few studies were taken there.Based on a large number of field work,studies on the geological characteristics combining with geochemistry characteristics were taken,and analysis the genesis of Laozhaiwan gold deposit.The types of alteration in Laozhaiwan gold deposit were mainly silicification and pyritization,and Gold grade was high when silicification and pyritization were both occurred.It could be caculated that fluid density(g/cm3)varied from 0.7 to 4.9,salinity varied from 0.76%to 0.95%and ore-forming pressure(Pa)varied from 1.81×105 to 49.96×105 according to fluid inclusion test results,showed that Laozhaiwan gold deposit was hypabyssal hydrothermal deposit in low temperature and low salinity.According to composition of fluid inclusion analysis,combining with H-O isotope,made theδD-δ18O figure,showed that the fluid of the deposit rooted in formation water and mixed with meteoric waters later.
基金Supported by International Special Funds to Finance the Construction of Modern Agricultural Technology SystemYouth Science and Technology Foundation of Sichuan Province(09ZQ026-019)Economic and Trade Commission Project of Technological Innovationin Sichuan Province(High Technology Innovation of Famous GreenTea Flavor)
文摘[Objective] Many strata emerge in the high-quality tea producing area in Qionglai Mountains,which belongs to Mesozoic Cretaceous(K),Mingshan Fm(E1-2mn)and Dayi conglomerate Team(N)of Cenozoic Tertiary System as well as Quaternary System(Q).Analysis on the migrating features of soil heavy metal from each stratum to tea leaves showed that the enrichment ability of elements was Cu>Cd>Zn>Ni>Hg>As>Cr>Pb.By comparing the soil background values with the soil base values of Sichuan hilly area and Chengdu economic region,it could be concluded that Cd,Hg,Mo,Pb and Se were enriched,and other metal elements existed at a level close to that of the comparing areas.The pH was a little acidic,and high quality tea cultivation could be developed here at present.With the increase of human activities,the environment of study area tends to deteriorate.Therefore,land planning and use should be reasonable.The government should control the environment nearby and prevent pollution.
基金supported by the National Natural Science Foundation of China (No. 41807026)China Postdoctoral Science Foundation (No. 2021M700888)+1 种基金GDAS’ Project of Science and Technology Development (No. 2021GDASYL20210302003)the China Agriculture Research System, assigned to Ministry of Finance & Ministry of Agriculture and Rural Affairs。
文摘The flooding and drainage of paddy fields has great effects on the transformation of heavy metals, however, the transformation of Cr in basalt-derived paddy soil with high geological background values was less recognized. The typical basalt-derived paddy soil was incubated under alternating redox conditions. The Cr fractions and the dynamics of Fe/N/S/C were examined. The HCl-extractable Cr increased under anaerobic condition and then decreased during aerobic stage. The UV-vis spectra of the supernatant showed that amounts of colloids were released under anaerobic condition, and then re-aggregated during aerobic phase. The scanning transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS) revealed that Fe oxides were reduced and became dispersed during anaerobic stage, whereas Fe(Ⅱ) was oxidized and recrystallized under aerobic condition. Based on these results, a kinetic model was established to further distinguish the relationship between the transformation of Cr and Fe. During anaerobic phase, the reduction of Fe(Ⅲ) oxides not only directly released the structurally bound Cr, but also enhanced the breakdown of soil aggregation and dissolution of organic matter causing indirect mobilization of Cr. During aerobic phase, the oxidation of Fe (Ⅱ) and further recrystallization of newly formed Fe(Ⅲ) oxides might induce the re-aggregation of soil colloids and further incorporation of Cr. In addition,the kinetic model of Cr and Fe transformation was further verified in the pot experiment.The model-based findings demonstrated that the Cr transformation in the basalt-derived paddy soil with high geological background values was highly driven by redox sensitive iron cycling.
基金supported by National Basic Research Program of China (Grant Nos. 2006CB860400, 2011CB808905)Chinese Academy of Sciences (Grant No. KZCX2-YW-Q08-4)NSFC and the CAS/SAFEA International Partnership Program for Creative Research Teams
文摘The Neoproterozoic-Cambrian(N-C) and Permian-Triassic(P-T) transitions have been regarded the two most critical transitions in earth history because of the explosive biological radiation in the early Cambrian(the Cambrian Explosion) and the largest mass extinction at the end-Permian.Previous studies suggest that these two critical transitions showed certain comparability in major evolutionary events.In other words,a series of biological,geological,and geochemical events that had happened in the N-C transition occurred repeatedly during the P-T transition.Those events included continental re-configuration related to the deep mantle dynamics,global-scale glaciations,large C-,Sr-,and S-isotope perturbations indicating atmospheric and oceanic changes,abnormal precipitation of carbonates,and associated multiple biological radiations and mass extinctions.The coupling of those events in both N-C and P-T transitions suggests that deep mantle dynamics could be a primary mechanism driving dramatic changes of environment on the earth's surface,which in turn caused major biological re-organizations.A detailed comparison of those events during the two critical transitions indicates that despite their general comparability,significant differences do exist in magnitude,duration,and frequency.The supercontinent Rodinia began to rift before the Snowball Earth time.By contrast,the supercontinent Pangea entered the dispersal stage after the greatest glaciation from the Late Carboniferous to Cisuralian.Quantitative data and qualitative analyses of different fossil groups show a more profound mass extinction during the N-C transition than at the end-Permian in terms of ecosystem disruption.This is indicated by the disappearance of the whole Ediacaran biota at the N-C boundary.The subsequent appearances of many new complex animals at phylum level in the early Cambrian mark the establishment of a brand new ecosystem.However,the end-Permian mass extinction is manifested mainly by the extinction of many different taxa at class and order levels.Although it caused the extinction of 95% of marine species and 75% of terrestrial species as well as complete cessation of coal and reef deposits after the mass extinction,this high-level biological re-organization still occurred within an established ecosystem,however drastic it may seem.Survived or Lazarus taxa re-occupied the existing ecospace in a relatively short duration after the end-Permian mass extinction.C-isotope excursions display large perturbations during both transitions,yet also in different magnitudes and frequencies,which suggest different atmospheric and oceanic conditions.The recurrent geological and geochemical events as well as the coupled major biological turnovers during the two transitions provide new clues to understanding the interplays among the earth-life system.Thus,it is essential to carry out multidisciplinary studies from the deep internal system to the surface of the Earth as a whole in order to unravel the interactions of different spheres of the earth.
