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Phonons near Peierls Structural Transition in Quasi-One-Dimensional Organic Crystals of TTF-TCNQ 被引量:2
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作者 Silvia Andronic Anatolie Casian 《Advances in Materials Physics and Chemistry》 2016年第4期98-104,共7页
The Peierls structural transition in quasi-one-dimensional organic crystals of TTF-TCNQ is investigated in the frame of a more complete physical model. The two most important electron-phonon interaction mechanisms are... The Peierls structural transition in quasi-one-dimensional organic crystals of TTF-TCNQ is investigated in the frame of a more complete physical model. The two most important electron-phonon interaction mechanisms are taken into account simultaneously. One is similar of that of deformation potential and the other is of polaron type. For simplicity, the 2D crystal model is considered. The renormalized phonon spectrum and the phonon polarization operator are calculated in the random phase approximation for different temperatures. The effects of interchain interaction on renormalized acoustic phonons and on the Peierls critical temperature are analyzed. 展开更多
关键词 Quasi-One-Dimensional organic crystals TTF-TCNQ Peierls Transition Interchain Interaction Renormalized Phonons
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Structure Prediction Based on Hydrophobic to Hydrophilic Volume Ratios in Small Molecule Amphiphilic Organic Crystals
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作者 Zheng-TaoXu StephenLee 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2002年第6期592-596,共5页
The structure type for the crystal of 4,4'-bis-(2-hydroxy-ethoxyl)-biphenyl 1 has been predicted by using the previously developed interfacial model for small organic molecules. Based on the calculated hydrophobic... The structure type for the crystal of 4,4'-bis-(2-hydroxy-ethoxyl)-biphenyl 1 has been predicted by using the previously developed interfacial model for small organic molecules. Based on the calculated hydrophobic to hydrophilic volume of 1, this model predicts the crystal structure to be of lamellar or bicontinuous type, which has been confirmed by the X-ray single-crystal structure analysis (C20H26O6, monoclinic, P21/C, a = 16.084(1), b = 6.0103(4), c = 9.6410(7) A, β9 = 103.014(2)°, V= 908.1(1) A3, Z = 2, Dc= 1.325 g/cm3, F(000)=388,μ = 0.097 mm-1, MoKα radiation, λ = 0.71073 A, R = 0.0382 and wR = 0.0882 with I > 2σ(I) for 7121 reflections collected, 1852 unique reflections and 170 parameters). As predicted, the hydrophobic and hydrophilic portions of 1 form in the lamellae. The same interfacial model is applied to other amphilphilic small molecule organic systems for structural type prediction. 展开更多
关键词 amphiphilic system minimal surface organic crystal structure prediction
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Peierls Structural Transition in Q1D Organic Crystals of TTT<SUB>2</SUB>I<SUB>3</SUB>for Different Values of Carrier Concentration
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作者 Silvia Andronic Anatolie Casian 《Advances in Materials Physics and Chemistry》 2020年第10期239-251,共13页
The Peierls structural transition in the TTT<sub>2</sub>I<sub>3</sub> (tetrathiotetracene-iodide) crystal, for different values of carrier concentration is studied in 3D approximation. A crysta... The Peierls structural transition in the TTT<sub>2</sub>I<sub>3</sub> (tetrathiotetracene-iodide) crystal, for different values of carrier concentration is studied in 3D approximation. A crystal physical model is applied that considers two of the most important hole-phonon interactions. The first interaction describes the deformation potential and the second one is of polaron type. In the presented physical model, the interaction of carriers with the structural defects is taken into account. This is crucial for the explanation of the transition. The renormalized phonon spectrum is calculated in the random phase approximation for different temperatures applying the method of Green functions. The renormalized phonon frequencies for different temperatures are presented in two cases. In the first case the interaction between TTT chains is neglected. In the second one, this interaction is taken into account. Computer simulations for the 3D physical model of the TTT<sub>2</sub>I<sub>3</sub> crystal are performed for different values of dimensionless Fermi momentum <em>k</em><sub>F</sub>, that is determined by variation of carrier concentration. It is shown that the transition is of Peierls type and strongly depends on iodine concentration. Finally, the Peierls critical temperature was determined. 展开更多
关键词 Quasi-One-Dimensional organic crystals Peierls Structural Transition TTT2I3 Renormalized Phonon Spectrum Interchain Interaction Peierls Critical Temperature
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Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides
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作者 Jaeyong Ahn Zhenping Li +6 位作者 Zhiwei Wang Ke Gao Huagui Zhuo Wanuk Choi Gang Chang Xiaobo Shang Joon Hak Oh 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第9期193-197,共5页
Compared to organic thin films,organic single crystals offer significant potential in organic phototransistors(OPTs)due to their enhanced charge transport,large surface area,and defect-free nature.However,the developm... Compared to organic thin films,organic single crystals offer significant potential in organic phototransistors(OPTs)due to their enhanced charge transport,large surface area,and defect-free nature.However,the development of n-type semiconductors has lagged behind p-type semiconductors.To enhance semiconductor device performance,a doping process can be employed,which typically involves the introduction of charged impurities into the crystalline semiconducting material.Its aim is to reduce the Ohmic losses,increase carrier density,improve transport capabilities,and facilitate effective carrier injection,ultimately enhancing the electrical properties of the material.Traditional doping processes,however,often pose a risk of damaging the structure of single crystals.In this study,we have synthesized novel cyanosubstituted chiral perylene diimides,which self-assemble into two-dimensional single crystals that can be used for n-type semiconductor devices.We have employed a surface doping strategy using diethylamine vapor without disrupting the crystal structure.The fabricated devices exhibit significantly higher charge transport properties after doping,achieving a maximum electron mobility of 0.14 cm^(2)V^(-1)s^(-1),representing an improvement of over threefold.Furthermore,the optoelectronic performance of the doped devices has significantly improved,with the external quantum efficiency increased by over 9 times and the significantly improved response time.These results suggest that our surface doping technology is a promising way for enhancing the performance of 2D organic single-crystal OPTs. 展开更多
关键词 Doping effect PHOTOTRANSISTORS Perylene diimides organic crystals Cyano substitution
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Schiff base flexible organic crystals toward multifunctional applications
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作者 Xue-Hua Ding Li-Zhi Wang +4 位作者 Yong-Zheng Chang Chuan-Xin Wei Jin-Yi Lin Man-Hua Ding Wei Huang 《Aggregate》 EI CAS 2024年第3期4-25,共22页
The emergence offlexible organic crystals changed the perception of molecu-lar crystals that were regarded as brittle entities over a long period of time,and sparked a great interest in exploring mechanically compliant... The emergence offlexible organic crystals changed the perception of molecu-lar crystals that were regarded as brittle entities over a long period of time,and sparked a great interest in exploring mechanically compliant organic crystalline materials toward next-generation smart materials during the past decade.Schiff base compounds are considered to be one of the most promising candidates forflexible organic crystals owing to their easy synthesis,high yield,stimuli respon-siveness and good mechanical properties.This paper gives an overview of the recent development of Schiff baseflexible organic crystals(including elastic organic crystals,plastic organic crystals,andflexible organic crystals integrating elastic-ity and plasticity)from serendipitous discovery to design strategies and versatile applications such as stimuli responses,optical waveguides,optoelectronic devices,biomimetic soft robots,and organic photonic integrated circuits.Notably,atomic force microscopy-micromanipulation technique has been utilized to bring the mul-tifunctional applications offlexible organic crystals from the macroscopic level to the microscopic world.Since understanding mechanicalflexibility at the molec-ular level through crystal engineering can assist us to trace down the structural origin of mechanical properties,we focus on the packing structures of various Schiff baseflexible organic crystals driven by non-covalent intermolecular inter-actions and their close correlation with mechanical behaviors.We hope that the information given here will help in the design of novelflexible organic crys-tals combined with other unique properties,and promote further research into the area of mechanically compliant organic crystalline materials toward multifunctional applications. 展开更多
关键词 flexible organic crystals intermolecular interactions mechanical properties multifunctional applications Schiff base molecules
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Flexible Organic Crystal with Two-Dimensional Elastic Bending and Recoverable Plastic Twisting for Circularly Polarized Luminescence
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作者 Wenjie Kuang Bo Jing +1 位作者 Songgu Wu Junbo Gong 《CCS Chemistry》 CSCD 2024年第6期1439-1447,共9页
Multidimensional mechanical flexible organic crystals with tunable optoelectronic properties hold significant promise for practical application in complicated environmental conditions.Herein,based on a newly designed... Multidimensional mechanical flexible organic crystals with tunable optoelectronic properties hold significant promise for practical application in complicated environmental conditions.Herein,based on a newly designed“flexible”Schiff base small molecule with chirality,we presented a compatibly bendable and twistable organic single crystal with circularly polarized luminescence for the first time.First,the twodimensional elastic bending of the chiral crystal was realized at both room and liquid nitrogen temperatures,along with recoverable plastic twisting at room temperature.Besides,circular dichroism and circularly polarized luminescence spectroscopy were employed to characterize the chiral enantiomer in solution and the solid state.Our design strategy provides a new perspective for the future construction of chiroptical flexible crystal materials. 展开更多
关键词 organic crystal multidimensional flexibility circularly polarized luminescence low-temperature resistance
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Extremely efficient terahertz second-harmonic generation from organic crystals
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作者 Hang Zhao Yong Tan +4 位作者 Chen Wang Ming Liu Yongzheng Wen Yuejin Zhao Ji Zhou 《Advanced Photonics Nexus》 2024年第4期82-91,共10页
Achieving efficient and intense second-harmonic generation(SHG)in the terahertz(THz)spectrum holds great potential for a wide range of technical applications,including THz nonlinear functional devices,wireless communi... Achieving efficient and intense second-harmonic generation(SHG)in the terahertz(THz)spectrum holds great potential for a wide range of technical applications,including THz nonlinear functional devices,wireless communications,and data processing and storage.However,the current research on THz harmonic emission primarily focuses on inorganic materials,which often offers challenges in achieving both efficient and broadband SHG.Herein,the remarkable efficiency of organic materials in producing THz harmonics is studied and demonstrated,thereby opening up a new avenue for searching candidates for frequency-doubling devices in the THz band.By utilizing DAST,DSTMS,and OH1 crystals,we showcase their superior frequency conversion capabilities when pumped by the narrowband THz pulses centered at 2.4,1.6,and 0.8 THz.The SHG spans a high-frequency THz domain of 4.8 THz,achieving an unprecedented conversion efficiency of∼1.21%while maintaining a perturbative nonlinear response.The highly efficient SHG of these materials is theoretically analyzed by considering the combined effects of dispersion,phonon absorption,polarization,and the nonlinear susceptibility of organic crystals.This work presents a promising platform for efficient THz frequency conversion and generation across a wide range of frequencies,offering new opportunities for novel nonlinear THz applications in next-generation electronics and optics. 展开更多
关键词 terahertz organic crystal second-harmonic generation
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Side-Chain Engineering of Organic Crystals for Lasing Media with Tunable Flexibility 被引量:2
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作者 Baolei Tang Shiyue Tang +3 位作者 Cheng Qu Kaiqi Ye Zuolun Zhang Hongyu Zhang 《CCS Chemistry》 CSCD 2023年第10期2348-2357,共10页
Abundant high-performance organic crystals have been reported in the past decades;however,applications of crystalline materials are seriously restricted by their notorious brittleness.Recently,some organic crystals ha... Abundant high-performance organic crystals have been reported in the past decades;however,applications of crystalline materials are seriously restricted by their notorious brittleness.Recently,some organic crystals have been designed to be deformable in response to stress,light,heat,or humidity;nevertheless,the development of flexible organic crystals currently relies on a molecular framework design.So far there is no effective strategy for constructing organic crystals with tunable flexibility based on the same luminescent skeleton.Herein,we propose a side-chain engineering strategy aimed at facilely modulating the mechanical compliance of organic crystals.Subtly changing the side chains of a single-benzeneπ-skeleton greatly alters the mechanical behaviors while maintaining the unique optical functions of the produced crystals.Optical waveguides and amplified spontaneous emissions were measured to evaluate the application potentials of the flexible crystals as soft optical transducing media.We anticipate that the proposed strategy will be expanded to regulate the mechanical compliance of other organic crystals with unique emission properties.In addition,the applications attempted preliminarily here highlight the superiority of“crystal flexibility”in flexible optoelectronics for some special application scenarios that require complex and shape changeable optical circuits. 展开更多
关键词 organic crystal ELASTICITY PLASTICITY emissions optical waveguides LASING
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Structure and ion transport properties of organic ionic compounds revealed by NMR
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作者 Haijin Zhu 《Magnetic Resonance Letters》 2024年第2期2-12,共11页
Organic ionic plastic crystals(OIPCs)are emerging as an important material family for solid-state electrolytes and many other applications.They have significant advantages over conventional electrolyte materials,such ... Organic ionic plastic crystals(OIPCs)are emerging as an important material family for solid-state electrolytes and many other applications.They have significant advantages over conventional electrolyte materials,such as high ionic conductivity,non-flammability,and plasticity.Various nuclear magnetic resonance(NMR)spectroscopy techniques including solid-state NMR,pulsed-field gradient(PFG)NMR,and magnetic resonance imaging(MRI)etc.,provide us a versatile toolkit to understand the fundamental level structures,molecular dynamics,and ionic interactions in these materials.This article reviews the commonly used NMR methods including solid-and solution-state NMR,PFG-NMR,dynamic nuclear polarization(DNP)and the application of these methods in revealing the microscopic level structures and ion-transport mechanisms in OIPC materials. 展开更多
关键词 NMR ELECTROLYTE organic ionic plastic crystals DEFECTS Diffusion Microstructure
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Organic crystal-based flexible smart materials 被引量:1
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作者 Yinjuan Huang Qiuyu Gong Jing Yu 《Science China Materials》 SCIE EI CAS CSCD 2022年第8期1994-2016,共23页
Although the famous brittle characteristics of molecular crystals are unfavorable when they are used as flexible smart materials(FSMs),an increasing number of organic crystal-based FSMs have been reported recently.Thi... Although the famous brittle characteristics of molecular crystals are unfavorable when they are used as flexible smart materials(FSMs),an increasing number of organic crystal-based FSMs have been reported recently.This breaks the perception of their stiff and brittle properties and promises a bright future for basic research and practical applications.Crystalline smart materials present considerable advantages over polymer materials under certain circumstances,rendering them potential candidates for certain applications,such as rapidly responsive actuators,ON/OFF switching,and microrobots.In this review,we summarize the recent developments in the field of organic crystal-based FSMs,including the derivatives of azobenzene,diarylethene,anthracene,and olefin.These organic crystal-based FSMs can bend,curl,twist,deform,or respond otherwise to external stimuli,such as heat or light.The detailed mechanisms of their smart behaviors are discussed with their potential applications in exciting intelligent fields.We believe this review could provide guidelines toward future fabrication and developments for novel organic crystal-based FSMs and their advanced smart applications. 展开更多
关键词 organic crystal SMART stimulus-responsive FLEXIBLE mechanical motion
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Ultralong Room-Temperature Phosphorescence of Silicon-Based Pure Organic Crystal for Oxygen Sensing 被引量:1
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作者 Wu-Jie Guo Yu-Zhe Chen +1 位作者 Chen-Ho Tung Li-Zhu Wu 《CCS Chemistry》 CAS 2022年第3期1007-1015,共9页
Quantitative oxygen detection is of great importance in biological fields,complex environments,and chemical process engineering.Due to the high sensitivity and rapid response of long-lived phosphorescence to oxygen,pu... Quantitative oxygen detection is of great importance in biological fields,complex environments,and chemical process engineering.Due to the high sensitivity and rapid response of long-lived phosphorescence to oxygen,pure organic room-temperature phosphorescence(RTP)for oxygen detection has recently attracted considerable interest.However,to simultaneously achieve ultralong phosphorescence at room temperature and quantitative oxygen detection from pure organic crystals is difficult.Tight packing to restrict nonradiative decay is not apt to allow oxygen diffusion for sensing.Reported herein is an exceptional example,that is,a crystal of simple carbazole molecules that bridges with an ethoxysilane(DCzC2OSi)and is capable of oxygen sensing with remarkable sensitivity.Photophysical studies and single-crystal structure analysis reveal that DCzC2OSi crystals display ultralong RTP and suitable oxygen diffusion channels from its butterfly-like tetrahedron geometry.Further comparisons with the crystals of CzC2OH and DCzSi verify the important roles of silicon and ethoxy groups of DCzC2OSi for both enhanced phosphorescence lifetime and oxygen sensitivity.When the crystals of DCzC2OSi were doped into polymer,the lifetime-based oxygen sensor exhibited high KSV(5.308 kPa^(−1))with full reversibility,which is attractive for the development of practical oxygen sensors from pure organic crystals. 展开更多
关键词 pure organic crystal ultralong roomtemperature phosphorescence oxygen sensor molecular packing
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Distribution of Crystal Organic Fertilizer-N in Soil-plant System 被引量:8
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作者 LIU Yi-xin, HAN Yi-wang, WANG Yan-ting, HONG Li-fang XU Xi-min,TANG Shen, LIN Guan-ya and LIU Wu-ding(Department of Environmental Science , Institute of Earth and Space , University of Science and Technology of China , Hefei 230026 , P. R . China Department of Tobacco Science , University of Science and Technology of China , Hefei 230052 , P. R . China +5 位作者 Department of Science , Technology and Education of Tobacco Monopoly Administration of China , Beijing 100052 , P. R . China Institute of Soil and Fertilizer , Yunnan Academy of Agricultural science , Kunmin 650231 , P. R . China Sanmin Tobacco Branch Company of Fujians , Sanmin 365010 , P. R . China Yongzhou Tobacco Branch Company of Hunan , Yongzhou 425000 , P. R . China Sinan Tobacco Company of Guizhou , Sinan 565100 , P. R . China Department of Resources , Environment and Agrochemistry , Huazhong Agricultural University, Wuhan 430070 , P.R.China) 《Agricultural Sciences in China》 CAS CSCD 2002年第9期1012-1016,共5页
The distribution of crystal organic fertilizer, urea and compound fertilizer-N in soil and plant system was researched with 15N-trace under tobacco pot experiment. The results showed that the leaf yield of tobacco use... The distribution of crystal organic fertilizer, urea and compound fertilizer-N in soil and plant system was researched with 15N-trace under tobacco pot experiment. The results showed that the leaf yield of tobacco used crystal organic fertilizer was 23.1% and 14.6% higher than that of urea and compound fertilizer treatments respectively. Compound fertilizer also resulted in higher yield of 8.5 % comparing with the urea treatment. Nitrogen content of the plant from the crystal organic fertilizer treatment was 138. 6% and 145.7% as high as that of the compound fertilizer and urea treatments respectively. The absorbed N from the organic fertilizer was 25.1% and 27.9% more than that from the compound fertilizer and urea respectively. However, the absorbed N from the soil with the organic fertilizer was 47.4% and 58.3% more than that with compound fertilizer and urea respectively. The N use efficiency of the organic fertilizer was 9.4% and 10.1% higher than that of the compound fertilizer and urea. It indicated that the crystal organic fertilizer not only had high N use efficiency, but also stimulated tobacco taking up more N from soil. 展开更多
关键词 TOBACCO crystal organic fertilizer-N Soil-plant system
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ORGANIC NONLINEAR OPTICAL CRYSTAL:N-(4-NITROPHENYL)-(s)-(+)-2-PYRROLIDINEMETHYLENE TOSYLATE(NPP-OTs)
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作者 Cheng YE Nai Jue ZHU Mei Xiang WAN Yan LI (Institute of Chemistry,Academia Sinica,Beijing,100080) 《Chinese Chemical Letters》 SCIE CAS CSCD 1990年第3期241-244,共4页
Large crystal NPP-OTs has been obtained by growth from solution,its powder SHG efficiency is 1/3 of urea.It shows it is a new convenient approach to obtain organic second-order NLO crystal:the dipole-dipole interactio... Large crystal NPP-OTs has been obtained by growth from solution,its powder SHG efficiency is 1/3 of urea.It shows it is a new convenient approach to obtain organic second-order NLO crystal:the dipole-dipole interaction is oppos- ed by introducing a large side group. 展开更多
关键词 NPP-OTs PYRROLIDINEMETHYLENE TOSYLATE organic NONLINEAR OPTICAL crystal NITROPHENYL
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GROWTH OF o-DICYANOVINYL ANISOLE(DIVA) CRYSTAL IN ORGANIC SOLVENTS
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作者 Bu Guo WANG, Cheng YE, Hui Fang ZHANG, Zhi Ming FENG aResearch Institute of Synthetic Crystals, Beijing 100018, bInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100080 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第11期1013-1016,共4页
Crystal growth habits of O-Dicyanovinyl anisole (DIVA) in organic solvents are described
关键词 DIVA crystal IN organic SOLVENTS GROWTH OF o-DICYANOVINYL ANISOLE
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Organic Melt Crystallization as a Method for Synthesis of Supramolecular Complexes
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作者 Masaaki Yokota Ryota Nakamura Norihito Doki 《Advances in Chemical Engineering and Science》 2016年第2期76-81,共6页
The most simple method for solventless synthesis of supramolecular complex of CMCR·2BPY·BZP, [CMCR = C-methylcalix[4]resorcinarene, BPY = 4,4'-bipyridine, BZP = benzophenone], is proposed. Although CMCR ... The most simple method for solventless synthesis of supramolecular complex of CMCR·2BPY·BZP, [CMCR = C-methylcalix[4]resorcinarene, BPY = 4,4'-bipyridine, BZP = benzophenone], is proposed. Although CMCR by itself is high melting point compound (above 300°C), CMCR was found to be dissolved in melt mixture of BPY and BZPeven below 120°C. In the mixture of the three components, the reaction occurs to form CMCR·2BPY·BZP supramolecular complex. 展开更多
关键词 organic Melt crystallization as a Method for Synthesis of Supramolecular Complexes
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Optical-induced dielectric tunability properties of DAST crystal in THz range
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作者 De-Gang Xu Xian-Li Zhu +5 位作者 Yu-Ye Wang Ji-Ning Li Yi-Xin He Zi-Bo Pang Hong-Juan Cheng Jian-Quan Yao 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第12期320-325,共6页
The optical-induced dielectric tunability properties of DAST crystal in THz range were experimentally demonstrated.The DAST crystal was grown by the spontaneous nucleation method(SNM) and characterized by infrared spe... The optical-induced dielectric tunability properties of DAST crystal in THz range were experimentally demonstrated.The DAST crystal was grown by the spontaneous nucleation method(SNM) and characterized by infrared spectrum. With the optimum wavelength of the exciting optical field, the transmission spectra of the DAST crystal excited by 532 nm laser under different power were measured by terahertz time-domain spectroscopy(THz-TDS) at room temperature. The transmitted THz intensity reduction of 26 % was obtained at 0.68 THz when the optical field was up to 80 m W. Meanwhile,the variation of refractive index showed an approximate quadratic behavior with the exciting optical field, which was related to the internal space charge field of photorefractive phenomenon in the DAST crystal caused by the photogenerated carrier.A significant enhancement of 13.7 % for THz absorption coefficient occurred at 0.68 THz due to the photogenerated carrier absorption effect in the DAST crystal. 展开更多
关键词 THz wave organic DAST crystal photogenerated carrier dielectric property
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Irradiation Effect on Second Harmonic Generation of Dyes Doped KDP Crystals 被引量:1
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作者 P.Kumaresan 《Journal of Electronic Science and Technology of China》 2010年第1期43-45,共3页
Most irradiation studies in the hydrogen bonded ferroelectrics have been concentrated on the transient defects induced by ionising radiation, such as ultraviolet (UV) light, where the defects are closely related to ... Most irradiation studies in the hydrogen bonded ferroelectrics have been concentrated on the transient defects induced by ionising radiation, such as ultraviolet (UV) light, where the defects are closely related to the optical properties. But heavy ion beam irradiation effects have rarely been studied. The structural, optical, and non-linear optical properties of the doped crystals were analyzed with the characterization studies, such as powder XRD, UV-Visible and second harmonic generation (SHG) measurements, respectively. The results for doped KDP crystal were compared with the results of the pure KDP crystals. The experiment results showed that Li^3+ irradiation leads to the development of a well-defined surface H peak in dye doped KDP crystals. The stability of KDP single crystal was improved by doping organic dyes. The nano-islands of dye in KDP were likely to be dissolved and enhance the non-linear optical properties of these materials. 展开更多
关键词 Irradiation effect KDP crystals organic dye second harmonic generation (SHG).
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Synthesis of a Highly Crystalline Amide-Linked Covalent Organic Framework 被引量:1
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作者 Yuyao Li Zhipeng Zhou +7 位作者 Yuexian Hong Xin Dong Yonghang Yang Zihao Liang Junliang Sun Xudong Chen Wei Liu Zhikun Zheng 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2023年第4期405-410,共6页
The dilemma for the synthesis of covalent organic frameworks(COFs)is crystallinity and stability.Herein,we present the synthesis of a single-crystalline amide-linked COF,and demonstrate its excellent chemical as well ... The dilemma for the synthesis of covalent organic frameworks(COFs)is crystallinity and stability.Herein,we present the synthesis of a single-crystalline amide-linked COF,and demonstrate its excellent chemical as well as thermal stabilities.This study will inspire the synthesis of a wide spectrum of highly crystalline and stable COFs,promote their structure-property investigations and boost their applications in selective gas adsorption,storage and separation. 展开更多
关键词 Covalent organic frameworks POLYMERS AMIDES organic crystals Microporous materials
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The Optical Properties of Bile Liquid Crystals in Organisms
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《Chinese Journal of Biomedical Engineering(English Edition)》 1999年第4期67-68,共2页
关键词 The Optical Properties of Bile Liquid crystals in Organisms
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Vapor-Induced Coating Method for Well-Aligned and Uniform Organic Semiconductor Single Crystals
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作者 Lu-Jing Shao Sheng-Nan Chen +7 位作者 Yu-Meng Wang Zheng Li Xiao-Song Shi Hao-Ran Long Lang Jiang Jue-Han Yang Ya-Li Qiao Yan-Lin Song 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2023年第10期1638-1645,共8页
Uniform and well-aligned organic semiconductor single crystals(OSSCs)are critical for high-performance electronic and optoelectronic device applications due to their long-range order and low defect density.However,it ... Uniform and well-aligned organic semiconductor single crystals(OSSCs)are critical for high-performance electronic and optoelectronic device applications due to their long-range order and low defect density.However,it is still challenging to fabricate uniform and well-aligned OSSCs by an efficient and facile method.Here,we report a vapor-induced coating method to prepare uniform organic semiconductor stripe single crystals with well-aligned orientation.The coating velocity and solution concentration are important to control the stripe crystals’morphology,which influence the triple-phase contact line dewetting behavior and then change the mass transport of the meniscus.Insufficient solute supply causes the generation of dendritic crystals.Uniform stripe single crystals of high quality and pure orientation are prepared in the condition of a sufficient and suitable solute supply.Moreover,the electronic and optoelectronic properties are evaluated.Notably,the polarization-sensitive photodetectors based on the uniform stripe crystals exhibit high polarization sensitivity and its dichroic ratio of photocurrent is 1.98.This method is efficient for the preparation of various high-quality and uniform organic semiconductor stripe single crystals,opening an opportunity for high-performance organic functional devices. 展开更多
关键词 Vapor-induced coating Marangoni flow organic single crystals organic field-effect transistors Polarization-sensitive photodetectors
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