Nitrogen-doped three-dimensional(3 D) porous carbon materials have numerous applications due to their highly porous structures, abundant structural nitrogen heteroatom decoration and low densities. Herein,nitrogen dop...Nitrogen-doped three-dimensional(3 D) porous carbon materials have numerous applications due to their highly porous structures, abundant structural nitrogen heteroatom decoration and low densities. Herein,nitrogen doped hierarchical 3 D porous carbons(NHPC) were prepared via a novel metal–organic aerogel(MOA), using hexamethylenetetramine(HMT), 1,3,5-benzenetricarboxylic acid and copper(II) as starting materials. The morphology, porous structure of the building blocks in the NHPC can be tuned readily using different amount of HMT, which makes elongation of the pristine octahedron of HKUST-1 to give rise to different aspect ratio rod-like structures. The as-prepared NHPC with rod-like carbons exhibit high performance in lithium sulfur battery due to the rational ion transfer pathways, high N-doped doping and hierarchical porous structures. As a result, the initial specific capacity of 1341 m A h/g at rate of 0.5 C(1 C = 1675 m A h/g) and high-rate capability of 354 m A h/g at 5 C was achieved. The decay over 500 cycles is 0.08% per cycle at 1 C, highlighting the long-cycle Li–S batteries.展开更多
A novel class of powdery carbon aerogels(PCAs) has been developed by the union of microemulsion polymerization and hypercrosslinking, followed by carbonization. The resulting aerogels are in a microscale powdery for...A novel class of powdery carbon aerogels(PCAs) has been developed by the union of microemulsion polymerization and hypercrosslinking, followed by carbonization. The resulting aerogels are in a microscale powdery form, demonstrate a well-defined 3D interconnected nanonetwork with hierarchical pores derived from numerous interstitial nanopores and intraparticle micropores, and exhibit high surface area(up to 1969 m^2/g). Benefiting from these structural features, PCAs show impressive capacitive performances when utilized as electrodes for organic electrolyte supercapacitors,including large capacitances of up to 152 F/g, high energy densities of 37-15 Wh/kg at power densities of 34–6750 W/kg, and robust cycling stability.展开更多
基金supported by the National Natural Science Foundation of China(Grant no.U1610105,51672033,U1610255)the Natural Science Foundation of Liaoning Province(201602170)+1 种基金the Open Fund of Key Laboratory of Interface Science and Engineering in Advanced Materials,Ministry of Education(KLISEAM 201601)the Open Sharing Fund Projects for Large Equipments Testing,Dalian University of Technology(2016-54)
文摘Nitrogen-doped three-dimensional(3 D) porous carbon materials have numerous applications due to their highly porous structures, abundant structural nitrogen heteroatom decoration and low densities. Herein,nitrogen doped hierarchical 3 D porous carbons(NHPC) were prepared via a novel metal–organic aerogel(MOA), using hexamethylenetetramine(HMT), 1,3,5-benzenetricarboxylic acid and copper(II) as starting materials. The morphology, porous structure of the building blocks in the NHPC can be tuned readily using different amount of HMT, which makes elongation of the pristine octahedron of HKUST-1 to give rise to different aspect ratio rod-like structures. The as-prepared NHPC with rod-like carbons exhibit high performance in lithium sulfur battery due to the rational ion transfer pathways, high N-doped doping and hierarchical porous structures. As a result, the initial specific capacity of 1341 m A h/g at rate of 0.5 C(1 C = 1675 m A h/g) and high-rate capability of 354 m A h/g at 5 C was achieved. The decay over 500 cycles is 0.08% per cycle at 1 C, highlighting the long-cycle Li–S batteries.
基金financial support from the National Natural Science Foundation of China (Nos 51372280,51422307, U1601206, 51702262)National Program for Support of Top-notch Young Professionals, Guangdong Natural Science Funds for Distinguished Young Scholar (No S2013050014408)+5 种基金Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program (No 2014TQ01C337)Fundamental Research Funds for the Central Universities (Nos. 15lgjc17, 3102017OQD057)the Key Laboratory of Polymeric Composite & Functional Materials of Ministry of Education (No. PCFM201602)the Project of the Natural Science Foundation of Shaanxi Province (No. 2017JQ5003)the Program of Introducing Talents of Discipline to Universities (No. B08040)National Key Basic Research Program of China (No. 2014CB932400)
文摘A novel class of powdery carbon aerogels(PCAs) has been developed by the union of microemulsion polymerization and hypercrosslinking, followed by carbonization. The resulting aerogels are in a microscale powdery form, demonstrate a well-defined 3D interconnected nanonetwork with hierarchical pores derived from numerous interstitial nanopores and intraparticle micropores, and exhibit high surface area(up to 1969 m^2/g). Benefiting from these structural features, PCAs show impressive capacitive performances when utilized as electrodes for organic electrolyte supercapacitors,including large capacitances of up to 152 F/g, high energy densities of 37-15 Wh/kg at power densities of 34–6750 W/kg, and robust cycling stability.