Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrous rare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show that the compositions of ...Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrous rare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show that the compositions of the complexes are RE(FPPD)_3·nH_2O(RE=La,Pr～Lu and Y;n=3).The ligand and its complexes have been characterized by infrared spectroscopy,UV-visible absorption spectroscopy,~1H-NMR spectra,thermal analysis and molar conductivity measurement.展开更多
文摘Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrous rare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show that the compositions of the complexes are RE(FPPD)_3·nH_2O(RE=La,Pr～Lu and Y;n=3).The ligand and its complexes have been characterized by infrared spectroscopy,UV-visible absorption spectroscopy,~1H-NMR spectra,thermal analysis and molar conductivity measurement.
