Anovel silicon containing carbon precursor was synthesised by reacting a petroleum pitchfraction and polydimethylsilane. The precursor containing about 26wt% Si was meltspunintofibresand then oxidativelystabilised in...Anovel silicon containing carbon precursor was synthesised by reacting a petroleum pitchfraction and polydimethylsilane. The precursor containing about 26wt% Si was meltspunintofibresand then oxidativelystabilised in airto renderthefibresinfusiblebefore pyrolysisat1200℃underinertatmospheretoproduceC Sialloy( CSA) fibres. Theextentofstabili sation wasfoundto becriticalto the development of mechanicalstrength of thefibres which varied with heattreatmenttemperature, showing a maximum at 1200 ℃when thestrength was 1 4 1 6 GPa. Thesestrengthsareremarkably goodconsideringthelow modulus whichis duetothe quite high failurestrains. Thefibrescanshow excellentresistanceto oxidation if given an initialshortexposureto oxygen athigh temperature duetotheformation of an im perceptiblelayer of silica. CSAfibreshavethe advantagesof both carbon fibresand SiCfi bres,thusextended application areascan beenvisaged .展开更多
In the last decades,vanadium alloyed coatings have been introduced as potential candidates for self-lubrication due to their perfect tribological properties.In this work,the influence of V incorporation on the wear pe...In the last decades,vanadium alloyed coatings have been introduced as potential candidates for self-lubrication due to their perfect tribological properties.In this work,the influence of V incorporation on the wear performance and oxidation resistance of TiSiN/CrN film coatings deposited by direct current(DC)reactive magnetron sputtering is investigated.The results show that vanadium incorporation significantly decreases the oxidation resistance of the coatings.In general,two layers are formed during the oxidation process:i)Ti(V)O_(2) on top,followed by a protective layer,which is subdivided into two layers,Cr_(2)O_(3) and Si-O.ii)The diffusion of V controls the oxidation of V-containing coatings.The addition of vanadium improves the wear resistance of coatings,and the wear rate decreases with increasing V content in the coatings;however,the friction coefficient is independent of the chemical composition of the coatings.The wear of the V-containing coatings is driven by polishing wear.展开更多
The oxidation tests of different SiC refractories including Si3N4-SiC bricks,Si3N4-Si2N2O-SiC bricks from China(SNO-1),Si3N4-Si2N2O-SiC bricks from overseas(SNO-2),SiAlON-SiC bricks,oxides bonded SiC bricks,self-bonde...The oxidation tests of different SiC refractories including Si3N4-SiC bricks,Si3N4-Si2N2O-SiC bricks from China(SNO-1),Si3N4-Si2N2O-SiC bricks from overseas(SNO-2),SiAlON-SiC bricks,oxides bonded SiC bricks,self-bonded SiC bricks as well as SiC castables were carried out in the steam atmosphere(1 000 ℃,32 kg·m-3·h-1)for different durations(100,200,300,400 and 500 h).The mass,the volume,the bulk density and the apparent porosity before and after the oxidation were tested.The XRD and SEM analyses were conducted.The results indicate that:(1)under the steam atmosphere condition(1 000 ℃,32 kg·m-3·h-1),as the oxidation time increases from 0 to 500 h,the volume and the mass of the silicon carbide refractories increase,while the bulk density decreases;in terms of the apparent porosity,oxides bonded SiC bricks and SiC castables present an increasing trend,Si3N4-SiC bricks,SiAlON-SiC bricks and self-bonded SiC bricks present an increasing trend first and then a decreasing trend,and Si3N4-Si2N2O-SiC bricks present a decreasing trend or a trend of decreasing first and then increasing;(2)as for Si3N4-Si2N2O-SiC bricks,SNO-1 and SNO-2 have basically the same chemical and phase composition,SNO-2 has the lower mass change rate than SNO-1 during oxidation from 200-500 h,which indicates that SNO-2 has the better steam oxidation resistance than SNO-1.展开更多
Scholars aim for the improved impedance matching (Z) of materials while maintaining their excellent wave absorption properties. Based on the hydrolysis characteristics of isopropyl titanate, a simple preparation proce...Scholars aim for the improved impedance matching (Z) of materials while maintaining their excellent wave absorption properties. Based on the hydrolysis characteristics of isopropyl titanate, a simple preparation process for the coating of carbonyl iron powder(CIP) with TiO_(2) was designed. Given the TiO2coating, the Z of the CIP@TiO_(2) composite was adjusted well by decreasing the dielectric constant. Moreover, the interfacial polarization of CIP@TiO_(2) was enhanced. Ultimately, the electromagnetic-wave (EMW) absorption property of the CIP@TiO_(2)composite was improved substantially, the minimum reflection loss reached-46.07 dB, and the effective absorption bandwidth can reach 8 GHz at the composite thickness of 1.5 mm. Moreover, compared with CIP, the oxidation resistance of CIP@TiO_(2)showed remarkable improvement. The results revealed that the oxidation starting temperature of CIP@TiO_(2) as about 400℃,whereas the uncoated CIP had an oxidation starting temperature of approximately 250℃. Moreover, the largest oxidation rate temperature of CIP@TiO_(2) increased to around 550℃. This work opens up a novel strategy for the production of high-performance EMW absorbers via structural design.展开更多
Al_(4)SiC_(4) was synthesized from Al powder, silicon carbide, and graphite by microwave sintering, and characterized by XRD and SEM. Then the synthesized material was added to the magnesia carbon refractory brick to ...Al_(4)SiC_(4) was synthesized from Al powder, silicon carbide, and graphite by microwave sintering, and characterized by XRD and SEM. Then the synthesized material was added to the magnesia carbon refractory brick to study its effect on the oxidation resistance, apparent porosity, bulk density, elastic modulus, and modulus of rupture. It is found that Al_(4)SiC_(4) can be synthesized by microwave sintering at 1 300 ℃ and the addition of Al_(4)SiC_(4)-containing material as an antioxidant can enhance the oxidation resistance of the magnesia carbon refractory brick.展开更多
Low thermal expansion superalloys have been used for a number of years in a variety of applications, including gas turbine engines. The low thermal expansion characteristics of the most widely used class of materials ...Low thermal expansion superalloys have been used for a number of years in a variety of applications, including gas turbine engines. The low thermal expansion characteristics of the most widely used class of materials are derived from the ferromagnetic characteristics of Ni, Fe, and Co-based austenitic matrices containing little or no Cr.Alloy developments have been aimed at improving the oxidation resistance and stress accelerated grain boundary oxygen (SAGBO) attack.INCONEL alloy 783 is an oxidation resistant, low coefficient of thermal expansion superalloy developed for gas turbine applications. Alloy 783 represents a culmination in the development, of an alloy system with very high alumtnum content that, in addition to forming γ′,causes βaluminide phase precipitation in the austenitic matrix.This type of structure can be processed to resist both SAGBO and general oxidation,while providing low thermal expansion and useful mechanical properties up to 700℃.Key aspects of the alloy's development are presented.展开更多
Nb-16Si-24Ti-6Cr-6A1-2Hf-xCe (x =0, 0.05, 0.1,02.5, 0.5, 1 (%, atom fraction)) in situ composites were prepared by arc melting The microstmcture and the effect of rare earth element cerium on 1250℃ oxidation resi...Nb-16Si-24Ti-6Cr-6A1-2Hf-xCe (x =0, 0.05, 0.1,02.5, 0.5, 1 (%, atom fraction)) in situ composites were prepared by arc melting The microstmcture and the effect of rare earth element cerium on 1250℃ oxidation resistance of the composites were investigated with scanning electron microscopy (SEM) and X-ray energy disperse spectrum (EDS), as well as X-ray diffraction (XRD). The experimental results showed that the high temperature oxidation resistance of the alloy was improved by adding a proper amount of cerium (Ce). The effect of Ce was considered as the concurrent of the following three factors: first, the oxide of Ce formed in the interface reduced the internal oxidation rate; second, the lath shaped oxide containing Ce increased the cracking resistance and reduced the expansion of the oxide scale; and third, the decrease of the sificide volume fraction on account of Ce addition reduces the power of the sample resisting oxygen penetration.展开更多
In order to improve the oxidation resistance properties of 30 at.% Mo5Si3/MoSi2 composite at high temperature in air, a molybdenum disilicide coating was prepared on its surface by a molten salt technology. XRD and SE...In order to improve the oxidation resistance properties of 30 at.% Mo5Si3/MoSi2 composite at high temperature in air, a molybdenum disilicide coating was prepared on its surface by a molten salt technology. XRD and SEM analysis showed that only tetragonal MoSi2 phase existed in the coating after being siliconized for 5 h at 900℃. The oxidation film formed on the uncoated sample was not dense, so that oxygen diffused easily through it. The volatilization of MoO3 resulted in the oxidation film separating from the substrate. The MoSi2 coating was proved to be an effective method to prevent 30 at.% Mo5Si3/MoSi2 composites from being oxidized at 1200℃. A dense glassy SiO2 film was formed on the MoSi2 coating surface, which acted as a barrier layer for the diffusion of oxygen atoms to the substrate. The 30at.% MosSi3/MoSi2 composites with a MoSi2 coating showed much better oxidation resistance at high temperature.展开更多
The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MP...The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MPa is increased by adding proper amounts of yttrium, howevef it decreases bg adding 0.3wt% silicon and 0. 1wt% yttrium at the same time, which may be attributed to the formation of a needle like phase rich in nickel and molybdenum.展开更多
The effect of grain size reduction on the high temperature oxidation of binary two phase alloys was discussed based on the recent research progress. The results show that for those two phase alloys with coarse grain p...The effect of grain size reduction on the high temperature oxidation of binary two phase alloys was discussed based on the recent research progress. The results show that for those two phase alloys with coarse grain prepared by the conventional methods, complex oxide scales are easily formed after oxidation under high oxygen pressure or under oxygen pressure below the stability limit of the less reactive component oxides. On the contrary, for the nano sized alloys, an exclusive external oxidation of the most reactive component usually occurs during oxidation in air or pure oxygen even for much lower content of the most reactive component. So the gain size reduction is not always beneficial to improve the oxidation resistance of the materials, but exhibits different effects depending mainly on the protective feature of the scales. The transition mechanisms between the different oxidation modes are discussed with respect to the thermodynamic and dynamic aspects.展开更多
A new type oxidation resistance in situ Cr7 C3/γ-Fe ceramic composite coating was fabricated on hardened and tempered grade C steel by reactive plasma clad with Fe-Cr-C alloy powders. The oxidation resistance of the...A new type oxidation resistance in situ Cr7 C3/γ-Fe ceramic composite coating was fabricated on hardened and tempered grade C steel by reactive plasma clad with Fe-Cr-C alloy powders. The oxidation resistance of the ceramic composite coating was investigated under the test condition of 900 ℃ and 50 hours. The results indicate that the coating has a rapidly solidified microstructure consisting of blocky primary Cr7 C3 and the inter-blocky Cr7 C3/γ-Fe eutectics and is metallurgically bonded to the hardened and tempered grade C steel substrate. The high temperature oxidation resistance of the coating is up to 1.9 times higher than that of grade C steel. The oxidation kinetics curve of the coating is conforming to the parabolic-rate law equation. The excellent oxidation resistance of the coating is mainly attributed to the continuous oxide films which consist of Cr203 and Fe203. The continuous oxide films can prevent the inner part of the coating from being further oxidized.展开更多
This work addresses the alloying of titanium aluminides used in aircraft engine applications and automobiles. The oxidation resistance behavior of two titanium aluminides of α2 + γ (Ti3Al + TiAl) and orthorhombi...This work addresses the alloying of titanium aluminides used in aircraft engine applications and automobiles. The oxidation resistance behavior of two titanium aluminides of α2 + γ (Ti3Al + TiAl) and orthorhombic Ti2NbAl, recognized as candidates for high-temperature applications, was investigated by exposure of the alloys for 100 h in air. Thus, oxidation resistance was expressed as the mass gain rate, whereas surface aspects were analyzed using scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy, and the type of oxidation products was analyzed by X-ray diffraction and Raman spectroscopy. The orthorhombic Ti2NbAl alloy was embrittled, and pores and microcracks were formed as a result of oxygen diffusion through the external oxide layer formed during thermal oxidation for 100 h.展开更多
Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti...Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti-Al alloy. The structure, constituent phases, formation process and oxidation behavior of the coatings were investigated. The experimental results showed that the coatings prepared respectively with NaF and NH_4Cl as activators were composed of a(Ti, X)_5Si_4,(Ti, X)_5Si_3(X represents Nb and Cr), and TiSi_2 outer layer, a TiAl_2 inner layer and an Al-rich interdiffusion zone. However, the constituent phases changed into TiSi_2 in the outer layer and(Ti, X)_5Si_4 and(Ti, X)_5Si_3 phases were observed in the middle layer of the coating prepared with AlCl_3·6H_2O activator. Among the halide activators studied, the coating prepared with AlCl_3·6H_2O was thicker and denser, which is the only suitable activator for pack Si-Al-Y co-deposition coatings on a Ti-Al alloy. The oxidation results show that the coating can protect the Ti-Al alloy from oxidation at 1000 ℃ in air for at least 80 h. The excellent oxidation resistance of the coating is attributed to the formation of a dense scale mainly consisted of TiO_2, SiO_2 and Al_2O_3.展开更多
The effect of the admixtures of Al and Si metals and B4 C and MgAlON compounds on the oxidation of MgO/ Si3N4 composite refractory has been studied, which is a promising carbon free refractory for steel-making applica...The effect of the admixtures of Al and Si metals and B4 C and MgAlON compounds on the oxidation of MgO/ Si3N4 composite refractory has been studied, which is a promising carbon free refractory for steel-making application . The four kinds of admixtures can be used as anti-oxi-dants for Si3N4, but the mixture of Al and Si achieved the best result. The mixture can not only play the role as anti-oxidant, but also assist the sintering process and help form dense sintering layer, improving the property of the composite.展开更多
In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate t...In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2+Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with finer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals and promoting the stable formation of the Al2O3-riched layer, which is beneficial to improve the oxidation properties.展开更多
The oxidation behavior (isothermal and cyclic oxidation) of cast superalloy K38G and the effect of Ce^+ ion implantation with dose of 1×10^(17) ions/cm^2 upon its oxidation resistance at 900 and 1000 ℃ in air we...The oxidation behavior (isothermal and cyclic oxidation) of cast superalloy K38G and the effect of Ce^+ ion implantation with dose of 1×10^(17) ions/cm^2 upon its oxidation resistance at 900 and 1000 ℃ in air were investigated. Meanwhile, the influence of Ce^+ implantation on oxidation behavior of K38G with pre-oxide scale at 1000 ℃ in air was compared. The pre-oxidation was performed at 1000 ℃ in static air for 0.25 and 1.5 h, respectively. It is shown that the homogeneous external mixture oxide of rutile TiO_2+Cr_2O_3 and non-continuous internal oxide of Al_2O_3 are formed during the oxidation procedure in all the cases. The isothermal oxidation resistance and the cracking or spallation resistance of superalloy K38G implanted with Ce^+ by both of the two different implantation ways are not improved notably. This may be attributed to the mixed oxide composition characteristics and the blocking effect differences of Ce^+ segregation along the oxide grain boundaries on the transport process for different diffusing ions.展开更多
Vanadium films were deposited on Si(100)substrates at room temperature by direct current(DC)magnetron sputtering.The microstructure and surface morphology were studied using scanning electron microscopy(SEM)and atomic...Vanadium films were deposited on Si(100)substrates at room temperature by direct current(DC)magnetron sputtering.The microstructure and surface morphology were studied using scanning electron microscopy(SEM)and atomic force microscope(AFM).The oxidation resistance of films in air was studied using X-ray photoelectron spectroscopy(XPS)and transmission electron microscopy(TEM).The results showed that the amorphous vanadium film with a flatter surface had higher oxidation resistance than the crystalline film when exposed to atmosphere.The rapid formation of the thin oxide layer of amorphous vanadium film could protect the film from sustained oxidation,and the relative reasons were discussed.展开更多
Steel H13 was put in non toxic salt bath with addition of CeO 2 for co diffusion of sulfur, nitrogen and carbon and followed by oxidation treatment. The effect of rare earths on the improvement of wear resistance a...Steel H13 was put in non toxic salt bath with addition of CeO 2 for co diffusion of sulfur, nitrogen and carbon and followed by oxidation treatment. The effect of rare earths on the improvement of wear resistance and high temperature oxidation resistance of steel H13 was studied using scanning electron microscope, energy dispersive spectrometry and X ray diffraction. The results show that compared to the surface treatment without rare earth addition, the treatment with addition of rare earths improves the wear resistance and high temperature resistance to oxidation of steel H13. Under the conditions of 30 N and 2 h, the wear weight loss was decreased by 40%, and the friction coefficient was reduced from 0 25 to 0 22; whereas for 150 N and 0 2 h, the wear weight loss was decreased by 24%, and the friction coefficient was reduced from 0 35 to 0 32. For the oxidation at 700 ℃ and 4 h, the rate of weight gain decreased to only about 1/30 of that without rare earths.展开更多
A Si-containing K273 superalloy was made using intermediate frequency induction furnace in the study. In the testing of oxidation resistance,the oxidation process of the alloy specimens during the testing at 900℃ for...A Si-containing K273 superalloy was made using intermediate frequency induction furnace in the study. In the testing of oxidation resistance,the oxidation process of the alloy specimens during the testing at 900℃ for 500 h was examined by oxidation weight gain method.The morphology and composition of the oxide scales were determined using scanning electron microscope(SEM)and X-ray diffraction(XRD),respectively.The effects of the transferring of ions and electrons on the oxidation resistance were further analyzed microscopically by semiconductor oxide models.The results show that the composite oxide scales consist of Cr2O3,SiO2 and spinel- type oxide MCr2O4,with flat and compact structure,and fine grains in uniform distribution.All of these endow the superalloy K273 with strong oxidation resistance.The reason for the powerful oxidation resistance of the composite scale is that the formation process of P+N type semiconductor oxide enables to consume most of the surplus negative and positive ions in the oxide scales,which makes the number of the mobile ions and electrons dropped enormously,and the transfer rate of them falls heavily.So the oxidation rate of the metal phase in the alloy matrix is reduced significantly.展开更多
The oxidation behaviour of high Cr Cast iron was investigated at 950 and 800℃ in terms of Cr content in matrix and the amount of carbide.The morphology and types of oxide films and the microstructure of subsurface we...The oxidation behaviour of high Cr Cast iron was investigated at 950 and 800℃ in terms of Cr content in matrix and the amount of carbide.The morphology and types of oxide films and the microstructure of subsurface were also examined.The main conclusions are:1)The original chromium content in the matrix determines the type of oxide film and it is an important factor for the oxidation resistance of high chromium cast iron;2) The oxidation resistance improves with increasing carbide content at 950℃ because of the decomposition of the carbide,while the decompsition of the carbide do not take place at 800℃ so the oxidation resisteance do not improve with increasing carbide volume.展开更多
文摘Anovel silicon containing carbon precursor was synthesised by reacting a petroleum pitchfraction and polydimethylsilane. The precursor containing about 26wt% Si was meltspunintofibresand then oxidativelystabilised in airto renderthefibresinfusiblebefore pyrolysisat1200℃underinertatmospheretoproduceC Sialloy( CSA) fibres. Theextentofstabili sation wasfoundto becriticalto the development of mechanicalstrength of thefibres which varied with heattreatmenttemperature, showing a maximum at 1200 ℃when thestrength was 1 4 1 6 GPa. Thesestrengthsareremarkably goodconsideringthelow modulus whichis duetothe quite high failurestrains. Thefibrescanshow excellentresistanceto oxidation if given an initialshortexposureto oxygen athigh temperature duetotheformation of an im perceptiblelayer of silica. CSAfibreshavethe advantagesof both carbon fibresand SiCfi bres,thusextended application areascan beenvisaged .
基金financially supported by the National Natural Science Foundation of China(Nos.51801081 and 52171071)national funds through FCT of Portugal-Fundacao para a Ciencia e a Tecnologia,under a scientific contract of 2021.04115,CEMMPRE-ref.“UIDB/00285/2020”and LA/P/0112/2020 projects+2 种基金FEDER funds through the COMPETE program-Operational Program on Competitiveness Factorsnational funds through FCT-Foundation for Science and Technology,Outstanding University Young Teachers of“Qing Lan Project”of Jiangsu Province of China,Excellent Talents of“Shenlan Project”of Jiangsu University of Science and Technology of ChinaA part of this study was supported by the Directorate-General of Scientific Research and Technological Development(Algeria)。
文摘In the last decades,vanadium alloyed coatings have been introduced as potential candidates for self-lubrication due to their perfect tribological properties.In this work,the influence of V incorporation on the wear performance and oxidation resistance of TiSiN/CrN film coatings deposited by direct current(DC)reactive magnetron sputtering is investigated.The results show that vanadium incorporation significantly decreases the oxidation resistance of the coatings.In general,two layers are formed during the oxidation process:i)Ti(V)O_(2) on top,followed by a protective layer,which is subdivided into two layers,Cr_(2)O_(3) and Si-O.ii)The diffusion of V controls the oxidation of V-containing coatings.The addition of vanadium improves the wear resistance of coatings,and the wear rate decreases with increasing V content in the coatings;however,the friction coefficient is independent of the chemical composition of the coatings.The wear of the V-containing coatings is driven by polishing wear.
基金supported by Provincial Science&Technology Program(No.201200211500),Henan,China.
文摘The oxidation tests of different SiC refractories including Si3N4-SiC bricks,Si3N4-Si2N2O-SiC bricks from China(SNO-1),Si3N4-Si2N2O-SiC bricks from overseas(SNO-2),SiAlON-SiC bricks,oxides bonded SiC bricks,self-bonded SiC bricks as well as SiC castables were carried out in the steam atmosphere(1 000 ℃,32 kg·m-3·h-1)for different durations(100,200,300,400 and 500 h).The mass,the volume,the bulk density and the apparent porosity before and after the oxidation were tested.The XRD and SEM analyses were conducted.The results indicate that:(1)under the steam atmosphere condition(1 000 ℃,32 kg·m-3·h-1),as the oxidation time increases from 0 to 500 h,the volume and the mass of the silicon carbide refractories increase,while the bulk density decreases;in terms of the apparent porosity,oxides bonded SiC bricks and SiC castables present an increasing trend,Si3N4-SiC bricks,SiAlON-SiC bricks and self-bonded SiC bricks present an increasing trend first and then a decreasing trend,and Si3N4-Si2N2O-SiC bricks present a decreasing trend or a trend of decreasing first and then increasing;(2)as for Si3N4-Si2N2O-SiC bricks,SNO-1 and SNO-2 have basically the same chemical and phase composition,SNO-2 has the lower mass change rate than SNO-1 during oxidation from 200-500 h,which indicates that SNO-2 has the better steam oxidation resistance than SNO-1.
基金financially supported by the National Natural Science Foundation of China (No.51872058)the Supporting Program for Innovation Team of Outstanding Youth in Colleges and Universities of Shandong Province(No.2020KJA005)。
文摘Scholars aim for the improved impedance matching (Z) of materials while maintaining their excellent wave absorption properties. Based on the hydrolysis characteristics of isopropyl titanate, a simple preparation process for the coating of carbonyl iron powder(CIP) with TiO_(2) was designed. Given the TiO2coating, the Z of the CIP@TiO_(2) composite was adjusted well by decreasing the dielectric constant. Moreover, the interfacial polarization of CIP@TiO_(2) was enhanced. Ultimately, the electromagnetic-wave (EMW) absorption property of the CIP@TiO_(2)composite was improved substantially, the minimum reflection loss reached-46.07 dB, and the effective absorption bandwidth can reach 8 GHz at the composite thickness of 1.5 mm. Moreover, compared with CIP, the oxidation resistance of CIP@TiO_(2)showed remarkable improvement. The results revealed that the oxidation starting temperature of CIP@TiO_(2) as about 400℃,whereas the uncoated CIP had an oxidation starting temperature of approximately 250℃. Moreover, the largest oxidation rate temperature of CIP@TiO_(2) increased to around 550℃. This work opens up a novel strategy for the production of high-performance EMW absorbers via structural design.
基金This work was funded by Luoyang Major Science and Technology Innovation Project(2301009A)Henan Province Key Research and Development Project(231111230200)。
文摘Al_(4)SiC_(4) was synthesized from Al powder, silicon carbide, and graphite by microwave sintering, and characterized by XRD and SEM. Then the synthesized material was added to the magnesia carbon refractory brick to study its effect on the oxidation resistance, apparent porosity, bulk density, elastic modulus, and modulus of rupture. It is found that Al_(4)SiC_(4) can be synthesized by microwave sintering at 1 300 ℃ and the addition of Al_(4)SiC_(4)-containing material as an antioxidant can enhance the oxidation resistance of the magnesia carbon refractory brick.
文摘Low thermal expansion superalloys have been used for a number of years in a variety of applications, including gas turbine engines. The low thermal expansion characteristics of the most widely used class of materials are derived from the ferromagnetic characteristics of Ni, Fe, and Co-based austenitic matrices containing little or no Cr.Alloy developments have been aimed at improving the oxidation resistance and stress accelerated grain boundary oxygen (SAGBO) attack.INCONEL alloy 783 is an oxidation resistant, low coefficient of thermal expansion superalloy developed for gas turbine applications. Alloy 783 represents a culmination in the development, of an alloy system with very high alumtnum content that, in addition to forming γ′,causes βaluminide phase precipitation in the austenitic matrix.This type of structure can be processed to resist both SAGBO and general oxidation,while providing low thermal expansion and useful mechanical properties up to 700℃.Key aspects of the alloy's development are presented.
基金Project supported by the National"863"Project (2003AA305810)
文摘Nb-16Si-24Ti-6Cr-6A1-2Hf-xCe (x =0, 0.05, 0.1,02.5, 0.5, 1 (%, atom fraction)) in situ composites were prepared by arc melting The microstmcture and the effect of rare earth element cerium on 1250℃ oxidation resistance of the composites were investigated with scanning electron microscopy (SEM) and X-ray energy disperse spectrum (EDS), as well as X-ray diffraction (XRD). The experimental results showed that the high temperature oxidation resistance of the alloy was improved by adding a proper amount of cerium (Ce). The effect of Ce was considered as the concurrent of the following three factors: first, the oxide of Ce formed in the interface reduced the internal oxidation rate; second, the lath shaped oxide containing Ce increased the cracking resistance and reduced the expansion of the oxide scale; and third, the decrease of the sificide volume fraction on account of Ce addition reduces the power of the sample resisting oxygen penetration.
文摘In order to improve the oxidation resistance properties of 30 at.% Mo5Si3/MoSi2 composite at high temperature in air, a molybdenum disilicide coating was prepared on its surface by a molten salt technology. XRD and SEM analysis showed that only tetragonal MoSi2 phase existed in the coating after being siliconized for 5 h at 900℃. The oxidation film formed on the uncoated sample was not dense, so that oxygen diffused easily through it. The volatilization of MoO3 resulted in the oxidation film separating from the substrate. The MoSi2 coating was proved to be an effective method to prevent 30 at.% Mo5Si3/MoSi2 composites from being oxidized at 1200℃. A dense glassy SiO2 film was formed on the MoSi2 coating surface, which acted as a barrier layer for the diffusion of oxygen atoms to the substrate. The 30at.% MosSi3/MoSi2 composites with a MoSi2 coating showed much better oxidation resistance at high temperature.
文摘The oridation resistance at 1100°C of a dirationally solidified Ni3Al base alloy IC6is substantially improved by the addition of yttriurn or yttrium and silicon. The stress rupture property under 1100°C/80MPa is increased by adding proper amounts of yttrium, howevef it decreases bg adding 0.3wt% silicon and 0. 1wt% yttrium at the same time, which may be attributed to the formation of a needle like phase rich in nickel and molybdenum.
文摘The effect of grain size reduction on the high temperature oxidation of binary two phase alloys was discussed based on the recent research progress. The results show that for those two phase alloys with coarse grain prepared by the conventional methods, complex oxide scales are easily formed after oxidation under high oxygen pressure or under oxygen pressure below the stability limit of the less reactive component oxides. On the contrary, for the nano sized alloys, an exclusive external oxidation of the most reactive component usually occurs during oxidation in air or pure oxygen even for much lower content of the most reactive component. So the gain size reduction is not always beneficial to improve the oxidation resistance of the materials, but exhibits different effects depending mainly on the protective feature of the scales. The transition mechanisms between the different oxidation modes are discussed with respect to the thermodynamic and dynamic aspects.
文摘A new type oxidation resistance in situ Cr7 C3/γ-Fe ceramic composite coating was fabricated on hardened and tempered grade C steel by reactive plasma clad with Fe-Cr-C alloy powders. The oxidation resistance of the ceramic composite coating was investigated under the test condition of 900 ℃ and 50 hours. The results indicate that the coating has a rapidly solidified microstructure consisting of blocky primary Cr7 C3 and the inter-blocky Cr7 C3/γ-Fe eutectics and is metallurgically bonded to the hardened and tempered grade C steel substrate. The high temperature oxidation resistance of the coating is up to 1.9 times higher than that of grade C steel. The oxidation kinetics curve of the coating is conforming to the parabolic-rate law equation. The excellent oxidation resistance of the coating is mainly attributed to the continuous oxide films which consist of Cr203 and Fe203. The continuous oxide films can prevent the inner part of the coating from being further oxidized.
基金funded by National Project PCCA contract No.65/2012POS-CCE O 2.2.1 project INFRANANOCHEM-No 19/January 3,2009 of the EU(ERDF)and Romanian Government
文摘This work addresses the alloying of titanium aluminides used in aircraft engine applications and automobiles. The oxidation resistance behavior of two titanium aluminides of α2 + γ (Ti3Al + TiAl) and orthorhombic Ti2NbAl, recognized as candidates for high-temperature applications, was investigated by exposure of the alloys for 100 h in air. Thus, oxidation resistance was expressed as the mass gain rate, whereas surface aspects were analyzed using scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy, and the type of oxidation products was analyzed by X-ray diffraction and Raman spectroscopy. The orthorhombic Ti2NbAl alloy was embrittled, and pores and microcracks were formed as a result of oxygen diffusion through the external oxide layer formed during thermal oxidation for 100 h.
基金the Key Scientific Research Projects in 2017 at North Minzu University(2017KJ05)
文摘Si-Al-Y co-deposition coatings were prepared on Ti-Al alloy by pack cementation processes at 1 050 ℃ for 4 h with different halide activators in the packs for enhancing the high temperature oxidation resistance of Ti-Al alloy. The structure, constituent phases, formation process and oxidation behavior of the coatings were investigated. The experimental results showed that the coatings prepared respectively with NaF and NH_4Cl as activators were composed of a(Ti, X)_5Si_4,(Ti, X)_5Si_3(X represents Nb and Cr), and TiSi_2 outer layer, a TiAl_2 inner layer and an Al-rich interdiffusion zone. However, the constituent phases changed into TiSi_2 in the outer layer and(Ti, X)_5Si_4 and(Ti, X)_5Si_3 phases were observed in the middle layer of the coating prepared with AlCl_3·6H_2O activator. Among the halide activators studied, the coating prepared with AlCl_3·6H_2O was thicker and denser, which is the only suitable activator for pack Si-Al-Y co-deposition coatings on a Ti-Al alloy. The oxidation results show that the coating can protect the Ti-Al alloy from oxidation at 1000 ℃ in air for at least 80 h. The excellent oxidation resistance of the coating is attributed to the formation of a dense scale mainly consisted of TiO_2, SiO_2 and Al_2O_3.
文摘The effect of the admixtures of Al and Si metals and B4 C and MgAlON compounds on the oxidation of MgO/ Si3N4 composite refractory has been studied, which is a promising carbon free refractory for steel-making application . The four kinds of admixtures can be used as anti-oxi-dants for Si3N4, but the mixture of Al and Si achieved the best result. The mixture can not only play the role as anti-oxidant, but also assist the sintering process and help form dense sintering layer, improving the property of the composite.
基金supported by the Special Program of the Education Bureau of Shaanxi Province of China (No.08JK240)the Breeding Program for Provincial Level Key Research Base of Shaanxi University of Technology (No.SLGJD0806)
文摘In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2+Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with finer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals and promoting the stable formation of the Al2O3-riched layer, which is beneficial to improve the oxidation properties.
基金Project supported by National Outstanding Young Scientist Foundation of China (50371095) the Special Funds for the Major State Basic Research Projects (G19990650) and State Laboratory for Corrosion and Protection of Metals
文摘The oxidation behavior (isothermal and cyclic oxidation) of cast superalloy K38G and the effect of Ce^+ ion implantation with dose of 1×10^(17) ions/cm^2 upon its oxidation resistance at 900 and 1000 ℃ in air were investigated. Meanwhile, the influence of Ce^+ implantation on oxidation behavior of K38G with pre-oxide scale at 1000 ℃ in air was compared. The pre-oxidation was performed at 1000 ℃ in static air for 0.25 and 1.5 h, respectively. It is shown that the homogeneous external mixture oxide of rutile TiO_2+Cr_2O_3 and non-continuous internal oxide of Al_2O_3 are formed during the oxidation procedure in all the cases. The isothermal oxidation resistance and the cracking or spallation resistance of superalloy K38G implanted with Ce^+ by both of the two different implantation ways are not improved notably. This may be attributed to the mixed oxide composition characteristics and the blocking effect differences of Ce^+ segregation along the oxide grain boundaries on the transport process for different diffusing ions.
基金Funded by the Science Challenge Project(No.TZ2016001)the National Natural Science Foundation of China(Nos.11602251,51861145306 and 51872212)+3 种基金the 111 Project(No.B13035)Joint Fund of Ministry of Education for Pre-research of Equipment(No.6141A02022257)supported by the International Science&Technology Cooperation Program of China(Nos.2018YFE0103600,2014DFA53090)the Technological Innovation of Hubei Province,China(No.2019AAA030)。
文摘Vanadium films were deposited on Si(100)substrates at room temperature by direct current(DC)magnetron sputtering.The microstructure and surface morphology were studied using scanning electron microscopy(SEM)and atomic force microscope(AFM).The oxidation resistance of films in air was studied using X-ray photoelectron spectroscopy(XPS)and transmission electron microscopy(TEM).The results showed that the amorphous vanadium film with a flatter surface had higher oxidation resistance than the crystalline film when exposed to atmosphere.The rapid formation of the thin oxide layer of amorphous vanadium film could protect the film from sustained oxidation,and the relative reasons were discussed.
文摘Steel H13 was put in non toxic salt bath with addition of CeO 2 for co diffusion of sulfur, nitrogen and carbon and followed by oxidation treatment. The effect of rare earths on the improvement of wear resistance and high temperature oxidation resistance of steel H13 was studied using scanning electron microscope, energy dispersive spectrometry and X ray diffraction. The results show that compared to the surface treatment without rare earth addition, the treatment with addition of rare earths improves the wear resistance and high temperature resistance to oxidation of steel H13. Under the conditions of 30 N and 2 h, the wear weight loss was decreased by 40%, and the friction coefficient was reduced from 0 25 to 0 22; whereas for 150 N and 0 2 h, the wear weight loss was decreased by 24%, and the friction coefficient was reduced from 0 35 to 0 32. For the oxidation at 700 ℃ and 4 h, the rate of weight gain decreased to only about 1/30 of that without rare earths.
文摘A Si-containing K273 superalloy was made using intermediate frequency induction furnace in the study. In the testing of oxidation resistance,the oxidation process of the alloy specimens during the testing at 900℃ for 500 h was examined by oxidation weight gain method.The morphology and composition of the oxide scales were determined using scanning electron microscope(SEM)and X-ray diffraction(XRD),respectively.The effects of the transferring of ions and electrons on the oxidation resistance were further analyzed microscopically by semiconductor oxide models.The results show that the composite oxide scales consist of Cr2O3,SiO2 and spinel- type oxide MCr2O4,with flat and compact structure,and fine grains in uniform distribution.All of these endow the superalloy K273 with strong oxidation resistance.The reason for the powerful oxidation resistance of the composite scale is that the formation process of P+N type semiconductor oxide enables to consume most of the surplus negative and positive ions in the oxide scales,which makes the number of the mobile ions and electrons dropped enormously,and the transfer rate of them falls heavily.So the oxidation rate of the metal phase in the alloy matrix is reduced significantly.
文摘The oxidation behaviour of high Cr Cast iron was investigated at 950 and 800℃ in terms of Cr content in matrix and the amount of carbide.The morphology and types of oxide films and the microstructure of subsurface were also examined.The main conclusions are:1)The original chromium content in the matrix determines the type of oxide film and it is an important factor for the oxidation resistance of high chromium cast iron;2) The oxidation resistance improves with increasing carbide content at 950℃ because of the decomposition of the carbide,while the decompsition of the carbide do not take place at 800℃ so the oxidation resisteance do not improve with increasing carbide volume.