Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electro...Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electronic configuration in valley bottom exhibits inert activity,which seriously fetters the development of catalytic materials with great potentials.Herein,In d^(10)electronic configuration of In_(2)O_(3)was activated by phosphorus atoms replacing its lattice oxygen to regulate the collocation of the ascended In 5p-band(Inɛ5p)and descended O 2p-band(Oɛ2p)centers as efficient active sites for chemisorption to*OH and*H during forward HOS,respectively,along with a declined In 4d-band center(Inɛ4d)to inhibit its backward reaction.A stable STH efficiency of 2.23%under AM 1.5 G irradiation at 65°C has been obtained over the activated d^(10)electronic configuration with a lowered activation energy for H_(2)evolution,verified by femtosecond transient absorption spectroscopy,in situ diffuse reflectance infrared Fourier transform spectroscopy and theoretical calculations of dynamics.These findings devote to activating d^(10)electronic configuration for resolving the reaction energy barrier and dynamical bottleneck of forward HOS,which expands the exploration of high-efficiency catalytic materials.展开更多
客户-设备的p中心定位问题旨在使每个客户访问与其最近的开放设备的最大距离最小,是典型的NP难题。采用聚类分析来解决离散p-中心问题,主要工作包括:(1)分析了按需求点分布类型来分类p-中心问题;(2)提出了基于聚类的p-中心定位算法p-clu...客户-设备的p中心定位问题旨在使每个客户访问与其最近的开放设备的最大距离最小,是典型的NP难题。采用聚类分析来解决离散p-中心问题,主要工作包括:(1)分析了按需求点分布类型来分类p-中心问题;(2)提出了基于聚类的p-中心定位算法p-cluster;(3)提出了用混沌搜索机制来求解带权值的一中心问题的算法CSOC(Chaos Search One Center)。在合成数据和真实数据上的实验表明,使用p-cluster算法可以有效地解决p-中心问题,从对比实验可以看出p-cluster算法明显优于分支限界法。展开更多
文摘Relationship between the activity for photocatalytic H_(2)O overall splitting(HOS)and the electron occupancy on d orbits of the active component in photocatalysts shows volcanic diagram,and specially the d^(10)electronic configuration in valley bottom exhibits inert activity,which seriously fetters the development of catalytic materials with great potentials.Herein,In d^(10)electronic configuration of In_(2)O_(3)was activated by phosphorus atoms replacing its lattice oxygen to regulate the collocation of the ascended In 5p-band(Inɛ5p)and descended O 2p-band(Oɛ2p)centers as efficient active sites for chemisorption to*OH and*H during forward HOS,respectively,along with a declined In 4d-band center(Inɛ4d)to inhibit its backward reaction.A stable STH efficiency of 2.23%under AM 1.5 G irradiation at 65°C has been obtained over the activated d^(10)electronic configuration with a lowered activation energy for H_(2)evolution,verified by femtosecond transient absorption spectroscopy,in situ diffuse reflectance infrared Fourier transform spectroscopy and theoretical calculations of dynamics.These findings devote to activating d^(10)electronic configuration for resolving the reaction energy barrier and dynamical bottleneck of forward HOS,which expands the exploration of high-efficiency catalytic materials.
文摘客户-设备的p中心定位问题旨在使每个客户访问与其最近的开放设备的最大距离最小,是典型的NP难题。采用聚类分析来解决离散p-中心问题,主要工作包括:(1)分析了按需求点分布类型来分类p-中心问题;(2)提出了基于聚类的p-中心定位算法p-cluster;(3)提出了用混沌搜索机制来求解带权值的一中心问题的算法CSOC(Chaos Search One Center)。在合成数据和真实数据上的实验表明,使用p-cluster算法可以有效地解决p-中心问题,从对比实验可以看出p-cluster算法明显优于分支限界法。
