The syntheses of Keggin and Dawson-structural phospho-tungsto heteropoly compounds and their Peroxo-derivatives(PCWP), and the catalytic performance over this series of catalysts for the selective oxidation of hexanol...The syntheses of Keggin and Dawson-structural phospho-tungsto heteropoly compounds and their Peroxo-derivatives(PCWP), and the catalytic performance over this series of catalysts for the selective oxidation of hexanol to hexylaldehyde are reported. By means of IR, NMR and UV-DRS techniques the catalysts were characterized and a comparison of the structural properties of these catalysts before and after the reaction was made. The correlation between the catalytic performance and the structure of this series of catalysts was discussed as well.展开更多
Three Keggin-type heteropolyanions, namely H3PMo12O40-13H2O, （NH4）3PMo12O40·4H2O and H3PW12O40·13H2O were prepared and tested in the ring-opening polymerization reaction of tetrahydrofuran. The effects of ...Three Keggin-type heteropolyanions, namely H3PMo12O40-13H2O, （NH4）3PMo12O40·4H2O and H3PW12O40·13H2O were prepared and tested in the ring-opening polymerization reaction of tetrahydrofuran. The effects of the counter-cation （H＋, NH4＋） and the peripheral atoms （Mo, W） on the polymerization were investigated. It has been found that when the protons of H3PMo12O40·13H2O were replaced by the ammonium cations the polymerization rate decreased dramatically. Whereas, when the peripheral atoms （Mo） were replaced by their homologous （W）, the polymerization rate increased twofold. As for the viscosity average molecular weight （My） of polymer products, it was found that the high molecular weight （7930） was obtained by using H3PW12O40·13H2O. The molecular weight （My） obtained by H3PMo12O40·13H2O and （NH4）H3PMo12O40·13H2O was 6470 and 6810, respectively.展开更多
Several kinds of Tungstophosphates of Heteropoly Compounds （TPHC） with different compositions and the same structure were synthesized using the method of solid-phase reaction to change the tool ratio of Na4P2O7·...Several kinds of Tungstophosphates of Heteropoly Compounds （TPHC） with different compositions and the same structure were synthesized using the method of solid-phase reaction to change the tool ratio of Na4P2O7·10H2O, WO3 and Na2WO4 · 2H2O. TPHC, as a catalyst, was used in oxidative desulfurization of diesel. The results show that TPHC has catalytic activity. With THPC existing, the highest desulfurization rate reaches 51.85%, 32.6% higher than that yield without TPHC. And the desulfiarization rate increases with decreasing WO3. FT-IR spectra of TPHC shows that the catalytic activity is related to the activity of end oxygen（Od）.The more active Od is, the stronger the capability of obtaining or losing electron is. It means that TPHC has a good catalytic activity. FT-IR spectra of TPHC indicates that desulfurization rate is in linear correlation with Iw-Od/Ip-Od/ Iw-Od is intensity of W-Od vibration band, Ip-Od is intensity of P-Od vibration band） and correlation coefficient reaches 0.965.展开更多
he single crystal of a tetra-component heteropoly compound Mo_2Co_3O_(68) (H_2O_2)_2 ] [MoO_6]. 15(H_2O) was obtained in an aqueous solution with Na_2MoO_4 , Na_2WO_4, Co (NO_3)_2 and H_3PO_4 as starting materia...he single crystal of a tetra-component heteropoly compound Mo_2Co_3O_(68) (H_2O_2)_2 ] [MoO_6]. 15(H_2O) was obtained in an aqueous solution with Na_2MoO_4 , Na_2WO_4, Co (NO_3)_2 and H_3PO_4 as starting materials. The erystallo-graphic data determined by means of X-ray diffraction analysis are: triclinic sys -tem,space group Pl ,Z= 2:a =1.9227(9) nm,b=1.9359(7)nm , c=1.2565(3)nm . a = 91. 43 (3), The Differential thermal and thermogravimetric analysis indicated the thermal stbility of the compound and its spectral properties were characterized by IR and XPS measurements .展开更多
Allantoin was synthesized with the yield as high as 68.5% using H3PW12O40. xH(2)O as catalyst. Optimum conditions for the synthesis were determined. It. was found that the heteropoly compound has higher catalytic acti...Allantoin was synthesized with the yield as high as 68.5% using H3PW12O40. xH(2)O as catalyst. Optimum conditions for the synthesis were determined. It. was found that the heteropoly compound has higher catalytic activity than conventional inorganic acid catalysts (such as hydrochloric acid, etc.)展开更多
AntiA3typeinfluenza virus activity and toxicity for chick embryo of some heteropoly compounds containing rare earth elements were investigated. The results demonstrate that these heteropoly compounds directly inactiva...AntiA3typeinfluenza virus activity and toxicity for chick embryo of some heteropoly compounds containing rare earth elements were investigated. The results demonstrate that these heteropoly compounds directly inactivate the A3type influenza virus, and the inhibition rate of K15)2]15H2O for the A3type influenza virus is more than 90% with antivirus index TI 69. The result is obviously superior to that of the positive reference drug ribavirin.展开更多
The all-lithium salts of heteropoly acid Li_xXM_ 12O_ 40(HPA-Li)(X=P, Si; M=Mo, W) were obtained via ion exchange and characterized by means of IR and UV spectroscopies, TG and elemental analyses. The conductivity o...The all-lithium salts of heteropoly acid Li_xXM_ 12O_ 40(HPA-Li)(X=P, Si; M=Mo, W) were obtained via ion exchange and characterized by means of IR and UV spectroscopies, TG and elemental analyses. The conductivity of the electrolytic solution consisting of Li_3PW_ 12O_ 40 and PC/DME mixing solvent(1/2.5, volume ratio) is up to 7.2×10 -2 S/cm, being higher than that of LiClO_4 as the electrolyte. The all-lithium salts were used as electrolytes in secondary lithium-ion batteries. The discharge capacity of the PAS/Li batteries with Li_3PW_ 12O_ 40 electrolyte solutions reaches to 148 (mA·h)/g and the cyclic life is up to 380 times, much better than those of commercialized products with LiClO_4 and LiAsF_6 as electrolytes.展开更多
A new compound,[Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O, has been hydrothermallly synthesized by using Na2MoO4,CoCl2, H3PO4 and dien, and structurally characterized by elemental analysis, X-ray powder dif...A new compound,[Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O, has been hydrothermallly synthesized by using Na2MoO4,CoCl2, H3PO4 and dien, and structurally characterized by elemental analysis, X-ray powder diffraction analysis, SEM, IR and TG analysis. The results show that the compound is composed of a polyanion [P2Mo5O23]2^12, complex [Co（dien）2]^2＋ cation, protonated [dienH3]^3＋ , and forteen crystallization water molecule.展开更多
The four heteropoly isomers K3H3[α ,β i SiW11Zn(H2O)O39]· XH2O(β i=β 1,β 2,β 3) were prepared and characterized by elementary analysis, IR and UV spectroscopy, polargraphy and cyclic voitammetry, 183W NMR a...The four heteropoly isomers K3H3[α ,β i SiW11Zn(H2O)O39]· XH2O(β i=β 1,β 2,β 3) were prepared and characterized by elementary analysis, IR and UV spectroscopy, polargraphy and cyclic voitammetry, 183W NMR and XPS experiments. And these compounds can catalyze epoxidation reaction of olefine.展开更多
The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to mo...The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to monoclinic, space group C2/m, a=2.0654(4)nm, b=1.3306(3)nm, c=1.3194(3)nm, β=119.59(3)°, V=3.1531(11)nm3, Dc=3.606Mg·m-3, Z=2, R=0.0462, Rw=0.0836. The title compound comprises of a 2+ unit, a polyanion and a free (CH3)2NH molecule. The ESR spectrum of the title compound shows that charge transfer between organic groups and polyanion takes place under irradiation of the sunlight in solid state. The TG study of the title compound shows that it had four stages of the weight loss, and the increase of the decomposition temperature for the polyanion shows that the stability of the polyanion was enhanced due to the influence of Zn2+ ion. CCDC:175866.展开更多
基金Supported by the National Natural Science Foundation of China.
文摘The syntheses of Keggin and Dawson-structural phospho-tungsto heteropoly compounds and their Peroxo-derivatives(PCWP), and the catalytic performance over this series of catalysts for the selective oxidation of hexanol to hexylaldehyde are reported. By means of IR, NMR and UV-DRS techniques the catalysts were characterized and a comparison of the structural properties of these catalysts before and after the reaction was made. The correlation between the catalytic performance and the structure of this series of catalysts was discussed as well.
基金supported by the Deanship of Scientific Research,King Saud University(No.M/202) and SABIC Company
文摘Three Keggin-type heteropolyanions, namely H3PMo12O40-13H2O, （NH4）3PMo12O40·4H2O and H3PW12O40·13H2O were prepared and tested in the ring-opening polymerization reaction of tetrahydrofuran. The effects of the counter-cation （H＋, NH4＋） and the peripheral atoms （Mo, W） on the polymerization were investigated. It has been found that when the protons of H3PMo12O40·13H2O were replaced by the ammonium cations the polymerization rate decreased dramatically. Whereas, when the peripheral atoms （Mo） were replaced by their homologous （W）, the polymerization rate increased twofold. As for the viscosity average molecular weight （My） of polymer products, it was found that the high molecular weight （7930） was obtained by using H3PW12O40·13H2O. The molecular weight （My） obtained by H3PMo12O40·13H2O and （NH4）H3PMo12O40·13H2O was 6470 and 6810, respectively.
基金Supported by the Natural Science Foundation of Hubei Province (2004ABA090)
文摘Several kinds of Tungstophosphates of Heteropoly Compounds （TPHC） with different compositions and the same structure were synthesized using the method of solid-phase reaction to change the tool ratio of Na4P2O7·10H2O, WO3 and Na2WO4 · 2H2O. TPHC, as a catalyst, was used in oxidative desulfurization of diesel. The results show that TPHC has catalytic activity. With THPC existing, the highest desulfurization rate reaches 51.85%, 32.6% higher than that yield without TPHC. And the desulfiarization rate increases with decreasing WO3. FT-IR spectra of TPHC shows that the catalytic activity is related to the activity of end oxygen（Od）.The more active Od is, the stronger the capability of obtaining or losing electron is. It means that TPHC has a good catalytic activity. FT-IR spectra of TPHC indicates that desulfurization rate is in linear correlation with Iw-Od/Ip-Od/ Iw-Od is intensity of W-Od vibration band, Ip-Od is intensity of P-Od vibration band） and correlation coefficient reaches 0.965.
文摘he single crystal of a tetra-component heteropoly compound Mo_2Co_3O_(68) (H_2O_2)_2 ] [MoO_6]. 15(H_2O) was obtained in an aqueous solution with Na_2MoO_4 , Na_2WO_4, Co (NO_3)_2 and H_3PO_4 as starting materials. The erystallo-graphic data determined by means of X-ray diffraction analysis are: triclinic sys -tem,space group Pl ,Z= 2:a =1.9227(9) nm,b=1.9359(7)nm , c=1.2565(3)nm . a = 91. 43 (3), The Differential thermal and thermogravimetric analysis indicated the thermal stbility of the compound and its spectral properties were characterized by IR and XPS measurements .
文摘Allantoin was synthesized with the yield as high as 68.5% using H3PW12O40. xH(2)O as catalyst. Optimum conditions for the synthesis were determined. It. was found that the heteropoly compound has higher catalytic activity than conventional inorganic acid catalysts (such as hydrochloric acid, etc.)
文摘AntiA3typeinfluenza virus activity and toxicity for chick embryo of some heteropoly compounds containing rare earth elements were investigated. The results demonstrate that these heteropoly compounds directly inactivate the A3type influenza virus, and the inhibition rate of K15)2]15H2O for the A3type influenza virus is more than 90% with antivirus index TI 69. The result is obviously superior to that of the positive reference drug ribavirin.
文摘The all-lithium salts of heteropoly acid Li_xXM_ 12O_ 40(HPA-Li)(X=P, Si; M=Mo, W) were obtained via ion exchange and characterized by means of IR and UV spectroscopies, TG and elemental analyses. The conductivity of the electrolytic solution consisting of Li_3PW_ 12O_ 40 and PC/DME mixing solvent(1/2.5, volume ratio) is up to 7.2×10 -2 S/cm, being higher than that of LiClO_4 as the electrolyte. The all-lithium salts were used as electrolytes in secondary lithium-ion batteries. The discharge capacity of the PAS/Li batteries with Li_3PW_ 12O_ 40 electrolyte solutions reaches to 148 (mA·h)/g and the cyclic life is up to 380 times, much better than those of commercialized products with LiClO_4 and LiAsF_6 as electrolytes.
基金Funded by the Natural Science Foundation of Hubei Province (No. 2003ABA085) Key Laboratory for Silicate Materials Science and Engineering (Wuhan University of Technology), Ministry of Education (No.2003-SJSJJ-15)
文摘A new compound,[Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O, has been hydrothermallly synthesized by using Na2MoO4,CoCl2, H3PO4 and dien, and structurally characterized by elemental analysis, X-ray powder diffraction analysis, SEM, IR and TG analysis. The results show that the compound is composed of a polyanion [P2Mo5O23]2^12, complex [Co（dien）2]^2＋ cation, protonated [dienH3]^3＋ , and forteen crystallization water molecule.
文摘The four heteropoly isomers K3H3[α ,β i SiW11Zn(H2O)O39]· XH2O(β i=β 1,β 2,β 3) were prepared and characterized by elementary analysis, IR and UV spectroscopy, polargraphy and cyclic voitammetry, 183W NMR and XPS experiments. And these compounds can catalyze epoxidation reaction of olefine.
文摘The title compound H2SiW12O40·(CH3)2NH was synthesized in mixed solvent of aqueous and acetonitrile, and its crystal structure had been determined using single crystal X ray diffraction. The crystal belongs to monoclinic, space group C2/m, a=2.0654(4)nm, b=1.3306(3)nm, c=1.3194(3)nm, β=119.59(3)°, V=3.1531(11)nm3, Dc=3.606Mg·m-3, Z=2, R=0.0462, Rw=0.0836. The title compound comprises of a 2+ unit, a polyanion and a free (CH3)2NH molecule. The ESR spectrum of the title compound shows that charge transfer between organic groups and polyanion takes place under irradiation of the sunlight in solid state. The TG study of the title compound shows that it had four stages of the weight loss, and the increase of the decomposition temperature for the polyanion shows that the stability of the polyanion was enhanced due to the influence of Zn2+ ion. CCDC:175866.
