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New Aspects in the Chemistry of Three-membered Ring Compounds Containing a Highly Coordinate Main Group Element 被引量:1
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作者 TAKAYUKI Kawashima 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2005年第9期1267-1269,共3页
The title compounds were synthesized by taking advantage of the Martin ligand. Their structures were determined by X-ray crystallography. Pentacoordinate thiasiliranides were hydrolyzed to give the corresponding thiol... The title compounds were synthesized by taking advantage of the Martin ligand. Their structures were determined by X-ray crystallography. Pentacoordinate thiasiliranides were hydrolyzed to give the corresponding thiol. Pentacoordinate chalcogenaphosphiranes were found to have polar P-chalcogen bonds, which were confirmed by their reactions with CF3SO3Me to give the corresponding 1-(methylchalcogena)alkylphosphonium triflates and by the solvent-dependent NMR studies. 展开更多
关键词 Martin ligand p-chalcogen bond three-membered ring compound
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