THE CONVERSION OF PAN-BASED STABILIZED FIBER TO CARBON FIBER

When the PAN-based stabilized fiber(PAN-SF) was converted to the carbon fiber, the effect of some of the carbonizing parameters on the structure and properties of the resulting carbon fibers, such as the molecular structure development, element contents, morphology and mechanical properties, was discussed. The results show that the carbonizing temperature, the purity of the inert gas and the de-oil pretreatment of the tiber have a great influence on them.

A long-term frequency-stabilized erbium-fiber-laser-based optical frequency comb with an intra-cavity electro-optic modulator

We demonstrate an optical frequency comb based on an erbium-doped-fiber femtosecond laser with the nonlinear polarization evolution scheme. The repetition rate of the laser is about 209 MHz. By controlling an intra-cavity electro- optic modulator and a piezo-transducer, the repetition rate can be stabilized with a high-bandwidth servo in a frequency range of 3 kHz, enabling long-term repetition rate phase-locking. The in-loop frequency stability of repetition rate is about 1.6× 10-13 in an integration time of 1 s, limited by the measurement system; and it is inversely proportional to integration time in the short term. Furthermore, using a common path f-2f interferometer, the carrier envelope offset frequency of the comb is obtained with a signal-to-noise ratio of 40 dB in a 3-MHz resolution bandwidth. Stabilized cartier envelope offset frequency exhibits a deviation of 0.6 mHz in an integration time of 1 s.

Effect of Electrochemical Treatment in Aqueous Ammonium Bicarbonate on Surface Properties of PAN-based Carbon Fibers

The surface properties of PAN-based carbon fibers electrochemically treated in aqueous ammonium bicarbonate before and after treatment were characterized by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and Dynamic Contact Angle Analysis (DCAA). The results of characterization indicated that the oxygen and nitrogen contents in carbon fiber surface were significantly increased by electrochemical treatment, and amide groups was introduced onto it, which was related with the electrolyte. The AFM photographs illustrated that the roughness of the fiber surface was also increased. The wettibality of the fibers was improved after treatment because the surface energy especially the polar part of it was increased.

Deformation Resistance Effect of PAN-based Carbon Fibers

The deformation resistance effect of polyacrylonitrile （PAN）-based carbon fibers was investigated, and the variatipn law of electrical resistivity under tensile stress was analyzed. The results show that the gauge factor （fractional change in resistance per unit strain） of PAN-based carbon fibers is 1.38, which is lower than that of the commonly-used resistance strain gauge. These may due to that the electrical resistivity of carbon fibers decreases under tensile stress. In addition when the carbon fibers are stretched, the change of its resistance is caused by fiber physical dimension and the change of electric resistivity, and mainly caused by the change of physical dimension. The mechanical properties of carbon fiber monofilament were also measured.

Geotechnical Properties of Flax Fiber Stabilized Soil

Engineers are often faced with the challenge of constructing with or on soils with poor strength that could pose challenges during the construction phase and service life of the facility.For better results,the geotechnical properties of the soil have to be improved.This study focused on the effect of flax fiber on the geotechnical properties of the soil.The soil samples were obtained from borrow pits within the University of Ibadan,Ibadan,Nigeria.The geotechnical properties CBR(California Bearing Ratio)and UCS(Unconfined Compressive Strength)of the natural soils among others were determined in accordance with BS 1377.Flax fibers of 0.3%,0.6%,0.9%,1.2%,and 1.5%by weight were added to the subsoil.The mixtures geotechnical properties were measured.The results showed that the addition of flax fiber led to increase in the soil CBR from 3.1%to 15%and also its UCS witnessed tremendous increase.The soil maximum CBR and UCS were attained at optimum flax fiber content of 1.2%.

Microstructure and interface thermal stability of C/Mo double-coated SiC fiber reinforced γ-TiAl matrix composites

C/Mo duplex coating interfacially modified SiC fiber-reinforced γ-TiAl matrix composite （SiCf/C/Mo/γ-TiA1） was prepared by foil-fiber-foil method to investigate its interfacial modification effect. SiCf/C/TiAl composites were also prepared under the same processing condition for comparision. Both kinds of the composites were thermally exposed in vacuum at 800 and 900℃ for different durations in order to study thermal stability of the interfacial zone. With the aids of scanning electron microscope （SEM） and energy dispersive spectrometer （EDS）, the interracial microstructures of the composites were investigated. The results reveal that, although adding the Mo coating, the interfacial reaction product of the SiCf/C/Mo/TiAl composite is the same with that of the SiCf/C/TiA1 composite, which is TiC/Ti2AlC between the coating and the matrix. However, C/Mo duplex coating is more efficient in hindering interfacial reaction than C single coating at 900 ℃ and below. In addition, a new layer of interfacial reaction product was found between Ti2AlC and the matrix after 900 ℃, 200 h thermal exposure, which is rich in V and close to the chemical composition of B2 phase.

Distributed Fiber Optic Monitoring and Stability Analysis of a Model Slope under Surcharge Loading

In the discipline of geotechnical engineering, fiber optic sensor based distributed monitoring has played an increasingly important role over the past few decades. Compared with conventional sensors, fiber optic sensors have a variety of exclusive advantages, such as smaller size, higher precision, and better corrosion resistance. These innovative monitoring technologies have been successfully applied for performance monitoring of geo-structures and early warning of potential geo- hazards around the world. In order to investigate their ability to monitor slope stability problems, a medium-sized model of soil nailed slope has been constructed in laboratory. The fully distributed Brillouin optical time-domain analysis （BOTDA） sensing technology was employed to measure the horizontal strain distributions inside the model slope. During model construction, a specially designed strain sensing fiber was buried in the soil mass. Afterward, the surcharge loading was applied on the slope crest in stages using hydraulic jacks and a reaction frame. During testing, an NBX-6o5o BOTDA sensing interrogator was used to collect the fiber optic sensing data. The test results have been analyzed in detail, which shows that the fiber optic sensors can capture the progressive deformation and failure pattern of the model slope. The limit equilibrium analyses were also conducted to obtain the factors ofsafety of the slope under different surface loadings. It is found that the characteristic maximum strains can reflect the stability of the model slope and an empirical relationship was obtained, This study verified the effectiveness of the distributed BOTDA sensing technology in performance monitoring of slope.

Test Stability of Uster Advanced Fiber Information System(AFIS)

To study test stability of Advanced Fiber Information System(AFIS),card sliver produced in two experiments(12 plans in each experiment)were tested by AFIS.By a statistic analysis of the test results,the number of test times that can get a reliable test reliability(hereinafter this number of test times is referred to as Reliable Test Times,RTT)of test parameters and the coefficient of variation(CV%)values of 30 test results of each experiment plan were obtained.It's concluded that some parameters,such as length,seed coat nep(SCN)size,nep size and immature fiber content(IFC),etc.are very reliable by a test of ten or more times,but other parameters,such as SCN content,trash content,and visible foreign matter(VFM)content,etc.are not reliable until they are tested over 100 times.

EFFECTS OF TENSOR CLOSURE MODELS AND 3-D ORIENTATION ON THE STABILITY OF FIBER SUSPENSIONS IN A CHANNEL FLOW

Three different kinds of closure model of fiber orientation tensors were applied to simulate numerically the hydrodynamic stability of fiber suspensions in a channel flow. The effects of closure models and three_dimensional (3_D) orientation distribution of fibers on the results of stability analysis were examined. It is found that the relationship of the behavior in hydrodynamic stability and the parameter of the fiber given by all the three models are the same. However, the attenuation of flow instability is most distinct using 3_D hybrid model because the orientation of the fiber departures from the flow direction, and least apparent using its 2_D counterpart for that the fibers show a tendency towards alignment with the flow direction in this case.

STABILITY ANALYSIS IN SPATIAL MODE FOR CHANNEL FLOW OF FIBER SUSPENSIONS

Different from previous temporal evolution assumption, the spatially growing mode was employed to analyze the linear stability for the channel flow of fiber suspensions. The stability equation applicable to fiber suspensions was established and solutions for a wide range of Reynolds number and angular frequency were given numerically . The results show that, the flow instability is governed by a parameter H which represents a ratio between the axial stretching resistance of fiber and the inertial force of the fluid. An increase of H leads to a raise of the critical Reynolds number, a decrease of corresponding wave number, a slowdown of the decreasing of phase velocity , a growth of the spatial attenuation rate and a diminishment of the peak value of disturbance velocity. Although the unstable region is reduced on the whole, long wave disturbances are susceptible to fibers.

Long-term stabilization of the optical fiber phase control using dual PID

We propose an approach of long-term stabilization of optical fiber phase by controlling a piezo-based phase modulator and a Peltier component attached to the fiber via a phase-locked loop( PLL) circuit w ith dual proportional-integral- derivative( PID) adjustment. With this approach,we can suppress the fast disturbance and slow drifting of optical fiber to satisfy the requirements of optical phase long-term locking. In theory,a mathematical model of an optical fiber phase control system is established. The disturbance term induced by environment influence is considered into the PLL model. The monotonous and continuous changing environment disturbance w ill cause a steady-state error in this theory model. The experimental results accords w ell w ith the theory. The steady-state performance,adjusting time,and overshoot can be improved by using the dual PID control. As a result,the long-term,highly stable and low noise fiber phase locking is realized experimentally.

Electrical resistance stability of high content carbon fiber reinforced cement composite

The influences of curing time, the content of free evaporable water in cement paste, environmental temperature, and alternative heating and cooling on the electrical resistance of high content carbon fiber reinforced cement (CFRC) paste are studied by experiments with specimens of Portland cement 42.5 with 10 mm PAN-based carbon fiber and methylcellulose. Experimental results indicate that the electrical resistance of CFRC increases relatively by 24% within a hydration time of 90 d and almost keeps constant after 14 d, changes hardly with the mass loss of free evaporable water in the concrete dried at 50 °C, increases relatively by 4% when ambient temperature decreases from 15 °C to ?20 °C, and decreases relatively by 13% with temperature increasing by 88 °C. It is suggested that the electric resistance of the CFRC is stable, which is testified by the stable power output obtained by electrifying the CFRC slab with a given voltage. This implies that such kind of high content carbon fiber reinforced cement composite is potentially a desirable electrothermal material for airfield runways and road surfaces deicing.

Thermal stability and curing kinetics of polycarbosilane fibers

Thermal stability and curing kinetics of polycarbosilane (PCS) fibers were studied by thermogravimetry (TG), Fourier transform infrared spectroscopy(FT-IR). Curing is an essential step in the preparation of SiC fibers and the properties of SiC fibers are affected greatly by curing conditions. TG measurement performed in air shows that mass gain starts at approximately 200℃ and PCS fibers are sensitive to oxygen. Curing with oxygen, which results in crosslinking on the surface, enabled PCS fibers to retain its shape during high-temperature pyrolysis. The curing of PCS fibers is oxidation of Si─H and Si─CH3, then Si─O─Si and Si─O─C bonds are formed. This is a first order reaction, with activation energy of 79.27 kJ/mol, and the pre-exponential factor is calculated as 3.07×106. The kinetics model was obtained and the experimental data of PCS fibers show good agreement with the kinetics model.

An optical fiber spool for laser stabilization with reduced acceleration sensitivity to 10^(-12)/g

Environmental vibration causes mechanical deformation in optical fibers, which induces excess frequency noise in fiber-stabilized lasers. In order to solve such a problem, we propose an ultralow acceleration sensitivity fiber spool with symmetrically mounted structure. By numerical analysis with the finite element method, we obtain the optimal geometry parameters of the spool with which the horizontal and vertical acceleration sensitivity can be reduced to 3.25 × 10^-12/g and 5.38 × 10^-12/g respectively. Moreover, the structure features the insensitivity to the variation of geometry parameters,which will minimize the influence from numerical simulation error and manufacture tolerance.

Fiber resonator using negative-curvature anti-resonant fiber with temperature stability

The coupling efficiency of hollow-core fiber changes with temperature,which leads to the decrease of the finesse(F)of fiber resonator and limits the performance of the resonant fiber optic gyroscope(R-FOG)system.Negative-curvature antiresonant fiber(ARF)can maintain single-mode characteristics under the condition of large mode field diameter,achieve efficient and stable fiber coupling,and significantly improve the consistency of the F of the spatial coupling resonator in variable temperature environment.A new type of ARF with a mode field diameter(MFD)of 25μm is used to fabricate a fiber resonator with a length of 5.14 m.In the range of 25℃-75℃,the average F is 31.45.The ARF resonator is used to construct an R-FOG system that shows long-term bias stability(3600 s)of3.1°/h at room temperature,4.6°/h at 75℃.To our knowledge,this is the best reported index of hollow-core fiber resonator and R-FOG system within the temperature variation range of 50℃ test.

Phase and Structural Transformation of Polyacrylonitrile Fiber during Two-Stage Thermal Stabilization

The influence of two-stage isothermal treatment on the change in the linear dimensions of the fiber, the average sizes of the coherent scattering regions, the texture and phase composition of the polyacrylonitrile fiber in the process of isothermal thermal stabilization is considered by the methods of dilatometry and X-ray diffraction analysis. It is shown that preliminary short-term heat treatment at a lower temperature affects the process of structural transformations of the polyacrylonitrile fiber material and the formation of a new highly dispersed phase of the thermally stabilized fiber.

Structural Evolution of Polyacrylonitrile Fibers in Stabilization and Carbonization

The effect of structural evolution polyacrylonitrile (PAN) on mechanical properties was investigated in stabilization and carbonization. PAN spun fibers were stabilized in a convection oven with a constant tension for various times at 250℃. Fourier Transform Infrared spectroscopy (FTIR) and gel fraction results suggested that intra and intermolecular stabilization reactions occurred simultaneously. X-ray diffractograms revealed a disruption of crystalline structure and an appearance of pre-graphitic structure of PAN fibers due to stabilization. These structural changes by stabilization resulted in the significant decrease of tensile properties of fibers. In Raman spectra with heat treated fibers from 400℃ up to 1200℃, the intensity ratio of the D to G bands (ID/IG) decreased as heat treatment temperature increased, indicating an increase of basal plane of graphitic layer of heat treated fibers. Tensile strength of heat treated fibers at 1200℃ was found to be as high as 2.2 GPa.

DURABILITY PERFORMANCE AND DIMENSIONAL STABILITY OF POLYPROPYLENE FIBER REINFORCED CONCRETE

In this study, the durability performance and dimensional stability of polypropylene fiber reinforced concrete mixture were investigated. For this purpose, two series of concrete mixtures, including a 0.45 water/cement ratio was prepared both in the absence and presence of fiber. A CEMI 42.5 R type portland cement and crushed limestone aggregate with a maximum particle size of 25 mm were used. In addition to the control mixture without fiber, three different concrete mixtures were prepared by adding polypropylene fiber as 0.4%, 0.8% and 1% of total volume into the mixture. The time-dependent fresh state properties, strength, ultrasonic pulse velocity, transport properties, drying shrinkage and freeze-thaw resistance of concrete mixtures, sodium sulfate attack and abrasion were investigated comparatively. Test results demonstrated that utilization of fiber affected the fresh properties of the concrete mixtures negatively. However, the 0.8% fiber-bearing mixture showed the highest performance in terms of durability and dimensional stability. Beyond this utilization ratio, the durability performance of the concrete mixture was negatively affected. The risk of nonhomogeneous dispersion of the fiber in the mixture was relatively high in the excess fiber-bearing mixture. Consequently, with the formation of flocculation in the mixture the void ratio of concrete mixture increased.

Non-uniqueness and stability of two-family fiber-reinforced incompressible hyper-elastic sheet under equibiaxial loading

The problems on the non-uniqueness and stability of a two-family fiber- reinforced anisotropic incompressible hyper-elastic square sheet under equibiaxial tensile dead loading are examined within the framework of finite elasticity. For a two-family fiber-reinforced square sheet, which is in-plane symmetric and subjected to the in-plane symmetric tension in dead loading on the edges, three symmetrically deformed configu- rations and six asymmetrically deformed configurations are possible for any values of the loading. Moreover, another four bifurcated asymmetrically deformed configurations are possible for the loading beyond a certain criticM value. The stability of all the solutions is discussed in comparison with the energy of the sheet. It is shown that only one of the symmetric solutions is stable when the loading is less than the critical value. However, this symmetric solution will become unstable when the loading is larger than the critical value, while one of the four bifurcated asymmetric solutions will be stable.

Experimental study of pavement performance of basalt fiber-modified asphalt mixture

To discuss the pavement performance of basalt fiber-modified asphalt mixtures,the optimum dosages of asphalt and fibers are studied by the Marshall test and the rutting test.The results demonstrate that the optimum dosages of asphalt and fibers are 4.63% and 0.3%,respectively.Then the pavement performances of basalt（polyester,xylogen）fiber-modified asphalt mixtures are investigated through high temperature stability tests,water stability tests and low temperature crack resistance tests.It indicates that the pavement performances of the fiber-modified asphalt mixtures such as rutting dynamic stability,freezing splitting tensile strength,low temperature crack resistance and so on are improved compared with control asphalt mixture.The results show that the pavement performances of asphalt mixtures can be improved by fiber-modifiers.Besides,the improvement effects of basalt fiber are superior to polyester fiber and xylogen fiber.