Free\|radical solution copolymerization of itaconic acid and acrylonitrile was carried out in DMSO at 58～60℃ using azodiisobutyronitrile as initiator.The resulting polymerization solution was spun to form PAN precur...Free\|radical solution copolymerization of itaconic acid and acrylonitrile was carried out in DMSO at 58～60℃ using azodiisobutyronitrile as initiator.The resulting polymerization solution was spun to form PAN precursors of carbon fibres.The precursors were treated with NiSO 4 aqueous solution at 95℃ on line.The structure and properties of untreated and treated PAN precursors and resultant carbon fibres were characterized by IR,SEM,dynamic viscoelasticity study,stabilization process and so on.It was suggested that carbon fibres developed from modified PAN fibres showed an improvement in tensile strength by about 20%～30% and Young’s modulus by about 5%～10%.展开更多
文摘Free\|radical solution copolymerization of itaconic acid and acrylonitrile was carried out in DMSO at 58～60℃ using azodiisobutyronitrile as initiator.The resulting polymerization solution was spun to form PAN precursors of carbon fibres.The precursors were treated with NiSO 4 aqueous solution at 95℃ on line.The structure and properties of untreated and treated PAN precursors and resultant carbon fibres were characterized by IR,SEM,dynamic viscoelasticity study,stabilization process and so on.It was suggested that carbon fibres developed from modified PAN fibres showed an improvement in tensile strength by about 20%～30% and Young’s modulus by about 5%～10%.
基金supported by grants fromthe National Basic Research Program(973 Program)(2006CB606505)the Shanghai Leading Academic Discipline Project(B603)the Shanghai Fundamental Theory Program(07DJ14002)
