Different mathematical methods, including linearization, differential, integration and nonlinear least squares approximation (Newton-Marquardt method), were used to fit different kinetic equations, such as zero-order,...Different mathematical methods, including linearization, differential, integration and nonlinear least squares approximation (Newton-Marquardt method), were used to fit different kinetic equations, such as zero-order, first-order (i. e, membrane diffusion), second-order, parabolic-diffusion, Elovich, two-constant equations, to the experimental data of Pb2+ and Cu2+ adsorption on variable charge soils and kaolinite. Assuming each M2+ occupied two adsorption sites, two more equations, the so-called surface second-order equation and third-order equation were derived and compared with the above equations according to the fitting results, which showed that the second-order equation and surface second-order equation, being one equation in different expressions under some conditions, were better than the other equations in describing the Pb2+ and Cu2+ adsorption kinetics, and the latter was the best.展开更多
A new SIMS U-Pb zircon age of 654.2 ± 2.7 Ma was reported from the middle Datangpo Formation in Changyang County of Hubei Province, China. The age is identical with that of 654 ± 3.8 Ma from the top Datangpo...A new SIMS U-Pb zircon age of 654.2 ± 2.7 Ma was reported from the middle Datangpo Formation in Changyang County of Hubei Province, China. The age is identical with that of 654 ± 3.8 Ma from the top Datangpo Formation in western Hunan Province, revealing that the volcanic activities （- 654 Ma） may have occurred widely in South China. The occurrence of the tuff beds （-654 Ma） at different intervals of the Datangpo Formation indicates that the erosion process after the Datangpo deposition varied significantly in different areas. It is thus consequently suggested that the rift in South China was active until the Nantuo glaciation. In addition, the new age confirms that the Nantuo glaciation started much later than 654 Ma.展开更多
基金Project supported by the N ational Natural Science Foundation of China.
文摘Different mathematical methods, including linearization, differential, integration and nonlinear least squares approximation (Newton-Marquardt method), were used to fit different kinetic equations, such as zero-order, first-order (i. e, membrane diffusion), second-order, parabolic-diffusion, Elovich, two-constant equations, to the experimental data of Pb2+ and Cu2+ adsorption on variable charge soils and kaolinite. Assuming each M2+ occupied two adsorption sites, two more equations, the so-called surface second-order equation and third-order equation were derived and compared with the above equations according to the fitting results, which showed that the second-order equation and surface second-order equation, being one equation in different expressions under some conditions, were better than the other equations in describing the Pb2+ and Cu2+ adsorption kinetics, and the latter was the best.
基金supported by the MLR Public Benefit Research Foundation(201411044)the National Basic Research Program of China(2013CB835005)+1 种基金the National Natural Science Foundation of China(41172035)China Geological Survey(12120114077901)
文摘A new SIMS U-Pb zircon age of 654.2 ± 2.7 Ma was reported from the middle Datangpo Formation in Changyang County of Hubei Province, China. The age is identical with that of 654 ± 3.8 Ma from the top Datangpo Formation in western Hunan Province, revealing that the volcanic activities （- 654 Ma） may have occurred widely in South China. The occurrence of the tuff beds （-654 Ma） at different intervals of the Datangpo Formation indicates that the erosion process after the Datangpo deposition varied significantly in different areas. It is thus consequently suggested that the rift in South China was active until the Nantuo glaciation. In addition, the new age confirms that the Nantuo glaciation started much later than 654 Ma.
