Fabrication and Magnetic Properties of Composite Ni_(0.5)Zn_(0.5)Fe_2O_4/Pb(Zr_(0.52)Ti_(0.48))O_3 Nanofibers by Electrospinning

One-dimensional and quasi-one-dimensional nanostructure materials are promising building blocks for electromagnetic devices and nanosystems.In this work,the composite Ni0.5Zn0.5Fe2O4（NZFO）/ Pb（Zr0.52Ti0.48）O3（PZT） nanofibers with average diameters about 65 nm are prepared by electrospinning from poly（vinyl pyrrolidone） （PVP） and metal salts.The precursor composite NZFO/PZT/PVP nanofibers and the subsequent calcined NZFO/PZT nanofibers are investigated by Fourier transform infrared spectroscopy （FT- IR） ,X-ray diffraction （XRD）,scanning electron microscopy （SEM）.The magnetic properties for nanofibers are measured by vibrating sample magnetometer（VSM）.The NZFO/PZT nanofibers obtained at calcination temperature of 900 °C for 2 h consist of the ferromagnetic spinel NZFO and ferroelectric perovskite PZT phases,which are constructed from about 37 nm NZFO and 17 nm PZT grains.The saturation magnetization of these NZFO/PZT nanofibers increases with increasing calcination temperature and contents of NZFO in the composite.

Lead Isotopic Composition and Lead Source of the Huogeqi Cu-Pb-Zn Deposit,Inner Mongolia,China

The Huogeqi orefield located on the northern side of Mt. Langshan, Inner Mongolia occurs in the Middle Proterozoic Langshan Group metamorphic rocks, and the orebodies arc stratiform. In the past twenty years, many Chinese geologists have conducted researches on the Huogeqi Cu-Pb-Zn deposit, but there has been still a controversy on its origin. Some advocate that the deposit is of sedimentary-metamorphic rcworking origin, some hold that it is of sea-floor SEDEX origin, and others have a preference for magmatic superimposition origin. The crux of the controversy is that there is no common understanding about the source of ore-forming materials. In this paper, the Pb isotopic compositions of regional Achaean-Early Proterozoic basement rocks, various types of sedimentary- metamorphic rocks and volcanic rocks in the mining district, Late Proterozoic and Hercynian magmatic rocks arc introduced and compared with the orc-lead composition, so as to constrain the source of the ore lead. The result indicates that （1） sulfides in the ores have homogeneous Pb isotopic compositions, showing a narrow variation range. Their ^206pb/^204pb ratios arc within a range of 17.027- 17.317; ^207Pb/^204pb ratios, 15.451-15.786 and ^208Pb/^204pb ratios, 36.747-37.669; （2） the Pb isotopic compositions of the regional Achaean-Early Proterozoic basement rocks arc characteristic of the old Pb isotopic composition at the early-stage evolution of the Earth, which varies over a wider range, reflecting significant differences in Pb isotopic compositions of the ores. All this indicates that the source of ore lead has no bearing on the basement rocks; （3） the sedimentary-metamorphic rocks in the mining district arc characterized by highly variable and more radiogenic Pb isotopic compositions and their Pb isotopic ratios arc obviously higher than those of ores, demonstrating that ore lead did not result from metamorphic rcworking of these rocks; （4） Pb isotopic compositions of Late Proterozoic diorite-gabbro and Hercynian granite are higher than those of ores. Meanwhile, the Pb isotopic compositions of sulfides in the small-sized strata-penetrating mineralized veinlets formed at later stages arc completely consistent with that of sulfides in stratiform-banded ores, suggesting that these veiniets arc the product of autochthonous rcworking of the stratiform-banded ores during the period of metamorphism and the late magmatic superimposition-mineralization can be excluded; （5） amphibolite, whose protolith is basic volcanic rocks, has the same Pb isotopic compositions as ores, implying that ore lead was derived probably from basic volcanism. So, the source of ore-forming materials for the Huogeqi deposit is like that of the volcanic massive sulfide （VMS） deposits. However, the orebodies do not occur directly within the volcanic rocks, and instead they overlie the volcanic rocks, showing some differences from those typical VMS-type deposits.

Feldspar Lead Isotopic Composition of Granitoids from the Eastern Qinling Orogenic Belt and Their Tectonic Significance

This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South Qinling are characterized by a strong block-effect anddepletion in U-Pb and Th-Pb, showing that these rocks came from the same lead isotopetectono-geochemical province, while those of North Qinling are characterized by higher U-Pband Th-Pb for Late Proterozoic to Early Paleozoic ones and lower U-Pb and Th-Pb forLate-Palaeozoic and younger ones in their feldspar lead isotopic composition. In the NorthQinling block, lead isotopic signatures reflect that the source of granitic magma had changedsince the Late Palaeozoic. Comparison of feldspar lead isotopic composition between SouthQinling and North Qinling shows that there is marked difference in lead isotopic compositionfor pre-Palaeozoic granitoids, indicating that the South Qinling and the North Qinling blocksbelong to different tectonic units, but the similarities in lead isotopic composition are quiteclear, which indicates that the South Qinling block had been welded with the North Qinlingblock and that the magma sources of both blocks were identical. The analysis provides directevidence for underplating of the continental crust of South Qinling beneath the North Qinlingblock in the continent-continent interaction stage of the Eastern Qinling oregenic belt.

Chemical characteristics and Pb isotopic compositions of PM2.5 in Nanchang, China

In mid-September 2013, PM2.5 samples were collected at six sites in Nanchang, Jiangxi Province, China, to quantify nine water-soluble ions （Ca2＋, Mg2＋, K＋, Na＋, NH4＋, SO42-, Cl-, F , NO3 ）, 29 trace elements （Ba, Zn, Pb, Ni, Mo, Cr, Cu, Sr, Sb, Rb, Cd, Bi, Zr, V, Ga, Li, Y, Nb, W, Cs, Tl, Sc, Co, U, Hf, In, Re, Be, and Ta）, and to characterize Pb isotopic ratios （^207pb/^206pb, ^208pb/^206pb, and ^207pb/^204pb） for identifying the main source（s） of Pb. The results showed that the average daily PM2.5 concentration （53.16 ± 24.17） Dg/m3 was within the secondary level of the Chinese ambient air quality standard. The combined concentrations of SO42-, NH4＋, and NO3- to total measured water-soluble ion concentrations in PM2.5 ranged from 79.40% to 95.18%, indicating that anthropogenic sources were significant. Coal combustion and vehicle emissions were both contributors to PM2.5 based on the NO3-/SO4^2- ratios. Wushu School experienced the lowest concentrations of PM2.s and most trace elements among the six sampling sites. Enrichment factor results showed that TI, Cr, In, Cu, Zn, Pb, Bi, Ni, Sb, and Cd in PM2.5 were affected by anthropogenic activities. Cluster analysis suggested that Cd, Sb, Pb, Re, Zn, Bi, Cs, Tl, Ga, and In were possibly related to coal combustion and vehicle exhaust, while Ni, Nb, Cr, and Mo may have originated from metal smelting. Pb isotopic tracing showed that coal dust, cement dust, road dust and construction dust were the major Pb sources in PM2.5 in Nanchang. Combined, these sources contributed an average of 72.51% of the Pb measured, while vehicle exhaust accounted for 27.49% of Pb based on results from a binary Pb isotope mixed model,