Reversible addition-fragmentation chain transfer(RAFT) mediated grafting of acrylonitrile onto Polyethylene/Poly(ethylene terephthalate)(PE/PET) composite fibers was performed using γ-irradiation as the initial sourc...Reversible addition-fragmentation chain transfer(RAFT) mediated grafting of acrylonitrile onto Polyethylene/Poly(ethylene terephthalate)(PE/PET) composite fibers was performed using γ-irradiation as the initial source at ambient temperature. Different initial concentrations of 2-cyanoprop-2-yl dithiobenzonate were used as the chain transfer agent. The kinetics of graft polymerization is in accordance with the living RAFT polymerization. The successful grafting of acrylonitrile is proved by Fourier transform infrared spectroscopy analysis.The results of monofilament tensile test show that mechanical properties of the fibers change slightly after grafting. Scanning electronic microscopy images of the fibers show that the surface of RAFT grafted fibers is smoother than that of fibers grafted conventionally.展开更多
the composites of grafting polystyrene polyvinyl acetate (PVA) or polyethylene terephthalate (PET) coated with soybean lecithin, are obtained. Results of grafting experiments show that the grafting ratio on the surfac...the composites of grafting polystyrene polyvinyl acetate (PVA) or polyethylene terephthalate (PET) coated with soybean lecithin, are obtained. Results of grafting experiments show that the grafting ratio on the surface of the fibers is low when the grafting polymer chain is not cross linked. Under scanning electron microscope (SEM), it is discovered that there is no different morphology between the raw fibers and their being coated with soybean lecithin. The composites exhibit a good stability of soybean lecithin layer, and better anti coagulant property than the sulfonated grafting fibers or raw fibers.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.11475246 and 11175234)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA02030205)
文摘Reversible addition-fragmentation chain transfer(RAFT) mediated grafting of acrylonitrile onto Polyethylene/Poly(ethylene terephthalate)(PE/PET) composite fibers was performed using γ-irradiation as the initial source at ambient temperature. Different initial concentrations of 2-cyanoprop-2-yl dithiobenzonate were used as the chain transfer agent. The kinetics of graft polymerization is in accordance with the living RAFT polymerization. The successful grafting of acrylonitrile is proved by Fourier transform infrared spectroscopy analysis.The results of monofilament tensile test show that mechanical properties of the fibers change slightly after grafting. Scanning electronic microscopy images of the fibers show that the surface of RAFT grafted fibers is smoother than that of fibers grafted conventionally.
文摘the composites of grafting polystyrene polyvinyl acetate (PVA) or polyethylene terephthalate (PET) coated with soybean lecithin, are obtained. Results of grafting experiments show that the grafting ratio on the surface of the fibers is low when the grafting polymer chain is not cross linked. Under scanning electron microscope (SEM), it is discovered that there is no different morphology between the raw fibers and their being coated with soybean lecithin. The composites exhibit a good stability of soybean lecithin layer, and better anti coagulant property than the sulfonated grafting fibers or raw fibers.
