Blends of PC and PPSQ (A) with high M-w and good ladderlike regularity or PPSQ(B) with low M-w and more defective Si-atoms in its structure have been prepared by solution casting. The dispersed spheres (PPSQ(A)-rich) ...Blends of PC and PPSQ (A) with high M-w and good ladderlike regularity or PPSQ(B) with low M-w and more defective Si-atoms in its structure have been prepared by solution casting. The dispersed spheres (PPSQ(A)-rich) are unevenly dispersed in the continuous PC-rich phase and there is no phase-inversion as PPSQ(A) content increases when the percentage of PPSQ(A) is not more than 70%. PPSQ(B)-rich spheres are evenly dispersed in the continuous phase (PC-rich) and phase-inversion occurs when PPSQ(B) percentage is up to 70%. T-g of PPSQ(A)/PC or PPSQ(B)/PC at some compositions are lower than that of pure PC due to the enlarged free-volume of PC-rich phase because some spheres of rigid PPSQ chains are included in the PC-rich phase. PC and PPSQ(A) or PPSQ(B) are partially compatible. The compatibility of PC and PPSQ(B) is better than that of PC and PPSQ(A) with high M-w and good ladderlike regularity. Heat history has some influence on the T(g)s and compatibility of PPSQ(A)/PC and PPSQ(B)/PC blends.展开更多
We show theoretically that range of reflection bands and defect modes inside the band gap can be tuned by using a one-dimensional tilted photonic crystal (TPC) structure. A TPC structure is similar to the conventional...We show theoretically that range of reflection bands and defect modes inside the band gap can be tuned by using a one-dimensional tilted photonic crystal (TPC) structure. A TPC structure is similar to the conventional PC structure with the only difference that in this case alternate layers are inclined at certain angle in the direction of periodicity of the structure. In order to obtain the reflectance spectra of the proposed structure transfer matrix method (TMM) has been employed. From the analysis of the reflectance curve, it is found that 100% reflectance range can be varied and enhanced by using TPC structure for both (TE- and TM-) polarizations. The enhancement in reflection bands increases as the tilt angle increases for both the polarizations and hence the enlarged omni-reflectance bands are obtained. Further, we study the properties of the defect modes in TPC structure by introducing the tilted defect at the different tilt angle. The results show that defect modes (tunneling modes) can be tuned at different wavelengths by changing the tilt angle of the structure without changing other parameters. Finally, the effect of variation thickness of defect layers on the tunneling mode has been studied for both TPC and conventional PC structure. The proposed model might be used as a tunable broadband omnidirectional reflector as well as tunable tunneling or transmission mode, which has potential applications in the field of photonics and optoelectronics.展开更多
基金This work was supported by Fund of Head of College of Chemistry,Shandong University.
文摘Blends of PC and PPSQ (A) with high M-w and good ladderlike regularity or PPSQ(B) with low M-w and more defective Si-atoms in its structure have been prepared by solution casting. The dispersed spheres (PPSQ(A)-rich) are unevenly dispersed in the continuous PC-rich phase and there is no phase-inversion as PPSQ(A) content increases when the percentage of PPSQ(A) is not more than 70%. PPSQ(B)-rich spheres are evenly dispersed in the continuous phase (PC-rich) and phase-inversion occurs when PPSQ(B) percentage is up to 70%. T-g of PPSQ(A)/PC or PPSQ(B)/PC at some compositions are lower than that of pure PC due to the enlarged free-volume of PC-rich phase because some spheres of rigid PPSQ chains are included in the PC-rich phase. PC and PPSQ(A) or PPSQ(B) are partially compatible. The compatibility of PC and PPSQ(B) is better than that of PC and PPSQ(A) with high M-w and good ladderlike regularity. Heat history has some influence on the T(g)s and compatibility of PPSQ(A)/PC and PPSQ(B)/PC blends.
文摘We show theoretically that range of reflection bands and defect modes inside the band gap can be tuned by using a one-dimensional tilted photonic crystal (TPC) structure. A TPC structure is similar to the conventional PC structure with the only difference that in this case alternate layers are inclined at certain angle in the direction of periodicity of the structure. In order to obtain the reflectance spectra of the proposed structure transfer matrix method (TMM) has been employed. From the analysis of the reflectance curve, it is found that 100% reflectance range can be varied and enhanced by using TPC structure for both (TE- and TM-) polarizations. The enhancement in reflection bands increases as the tilt angle increases for both the polarizations and hence the enlarged omni-reflectance bands are obtained. Further, we study the properties of the defect modes in TPC structure by introducing the tilted defect at the different tilt angle. The results show that defect modes (tunneling modes) can be tuned at different wavelengths by changing the tilt angle of the structure without changing other parameters. Finally, the effect of variation thickness of defect layers on the tunneling mode has been studied for both TPC and conventional PC structure. The proposed model might be used as a tunable broadband omnidirectional reflector as well as tunable tunneling or transmission mode, which has potential applications in the field of photonics and optoelectronics.
