Binuclear Cu(Ⅰ) complex [Cu(dppm)(NO_3)]2 (dppm=Ph_2PCH_2PPh_2) and mononuclear Cu(Ⅰ) complex [Cu(dppe)(NO_3)] (dppe=Ph_2PCH_2CH_2PPh_2) have been synthesized by the ligand-reduction reaction of cupric nitrate with ...Binuclear Cu(Ⅰ) complex [Cu(dppm)(NO_3)]2 (dppm=Ph_2PCH_2PPh_2) and mononuclear Cu(Ⅰ) complex [Cu(dppe)(NO_3)] (dppe=Ph_2PCH_2CH_2PPh_2) have been synthesized by the ligand-reduction reaction of cupric nitrate with dppm and dppe in methanol and characterized by means of ICP, elemental analyses, molecular weight determination, TG, ^(31)P-NMR, IR and Raman spectra; their electronic conductivities and CV waves have also been measured. Results show that dppm coordinates to the Cu(Ⅰ) atoms as a bridging bidentate ligand and dppe as a chelating bidentate ligand, (NO_3)^(-1) behaves as a chelating bidentate ligand in both of the newly prepared complexes.展开更多
在所建立的有源电力滤波器APF(active power filter)端口受控哈密顿系统PCH(port controlledHamiltonian)平均化模型基础上,提出了一种非线性L2增益控制新方法。该方法建立了APF的PCH平均化模型,设计了L2增益控制律,针对误差系统的欠驱...在所建立的有源电力滤波器APF(active power filter)端口受控哈密顿系统PCH(port controlledHamiltonian)平均化模型基础上,提出了一种非线性L2增益控制新方法。该方法建立了APF的PCH平均化模型,设计了L2增益控制律,针对误差系统的欠驱动性质和准确估计直流电容参考电压波动量的困难,从提高系统的鲁棒性和简化控制方法执行的角度着眼,分别采用间接控制以及大电容条件下忽略直流电容参考电压波动量的方法进行解决。此外,该方法还对采用固定反馈增益控制时APF内层控制过调制现象的产生原因进行了分析,通过设计滑动反馈增益限幅控制代替固定反馈增益控制,在满足内层控制约束下确保补偿效果。仿真结果验证了该方法的正确性和有效性。展开更多
基金This work was supported by National Key Lab of Coordination Chemistry at Nanjing University Henan Natural Science Foundation.
文摘Binuclear Cu(Ⅰ) complex [Cu(dppm)(NO_3)]2 (dppm=Ph_2PCH_2PPh_2) and mononuclear Cu(Ⅰ) complex [Cu(dppe)(NO_3)] (dppe=Ph_2PCH_2CH_2PPh_2) have been synthesized by the ligand-reduction reaction of cupric nitrate with dppm and dppe in methanol and characterized by means of ICP, elemental analyses, molecular weight determination, TG, ^(31)P-NMR, IR and Raman spectra; their electronic conductivities and CV waves have also been measured. Results show that dppm coordinates to the Cu(Ⅰ) atoms as a bridging bidentate ligand and dppe as a chelating bidentate ligand, (NO_3)^(-1) behaves as a chelating bidentate ligand in both of the newly prepared complexes.
文摘在所建立的有源电力滤波器APF(active power filter)端口受控哈密顿系统PCH(port controlledHamiltonian)平均化模型基础上,提出了一种非线性L2增益控制新方法。该方法建立了APF的PCH平均化模型,设计了L2增益控制律,针对误差系统的欠驱动性质和准确估计直流电容参考电压波动量的困难,从提高系统的鲁棒性和简化控制方法执行的角度着眼,分别采用间接控制以及大电容条件下忽略直流电容参考电压波动量的方法进行解决。此外,该方法还对采用固定反馈增益控制时APF内层控制过调制现象的产生原因进行了分析,通过设计滑动反馈增益限幅控制代替固定反馈增益控制,在满足内层控制约束下确保补偿效果。仿真结果验证了该方法的正确性和有效性。
