Pure nano-All3 and aggregates at various concentrations were prepared to examine the particle size effect of coagulation with inorganic polymer flocculant. The property and stability of various species formed were cha...Pure nano-All3 and aggregates at various concentrations were prepared to examine the particle size effect of coagulation with inorganic polymer flocculant. The property and stability of various species formed were characterized using Infrared, 27Al-NMR, photo correlation spectroscopy （PCS）, and Ferron assay. Results showed that concentration and temperature exhibited different roles on the stability of Al13. The quantity of Alb species analyzed by ferron assay in the initial aging period corresponded well with that of Al13, which has been confirmed in a dimension range of 1-2 nm by PCS. Al13 solutions at high concentrations （0.5-2.11 tool/L） were observed to undergo further aggregation with aging. The aggregates with a wide particle size distribution would contribute to the disappeared/decreased Al13 basis on the eTA1-NMR spectrum, whereas a part of Al13 would still remain as Alb. At low concentrations, All3 solution was quite stable at normal temperature, but lost its stability quickly when heating to 90~C.展开更多
基金supported by the National Natural Science Foundation of China (No. 51025830, 50921064)the National Hi-Tech Research and Development Program(863) of China (No. 2008AA06A414)
文摘Pure nano-All3 and aggregates at various concentrations were prepared to examine the particle size effect of coagulation with inorganic polymer flocculant. The property and stability of various species formed were characterized using Infrared, 27Al-NMR, photo correlation spectroscopy （PCS）, and Ferron assay. Results showed that concentration and temperature exhibited different roles on the stability of Al13. The quantity of Alb species analyzed by ferron assay in the initial aging period corresponded well with that of Al13, which has been confirmed in a dimension range of 1-2 nm by PCS. Al13 solutions at high concentrations （0.5-2.11 tool/L） were observed to undergo further aggregation with aging. The aggregates with a wide particle size distribution would contribute to the disappeared/decreased Al13 basis on the eTA1-NMR spectrum, whereas a part of Al13 would still remain as Alb. At low concentrations, All3 solution was quite stable at normal temperature, but lost its stability quickly when heating to 90~C.
