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EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF PEO-NaSCN
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《Chemical Research in Chinese Universities》 SCIE CAS 1986年第1期97-101,共5页
Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast... Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN. 展开更多
关键词 OC PEO EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF peo-nascn
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FT-IR光谱对共混聚合物电解质中离子缔合行为的研究
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作者 李保林 《安阳工学院学报》 2005年第4期19-21,共3页
虽然PVdF几乎不与NaSCN发生溶剂化作用,但由于PVdF可以在PEO-NaSCN电解质中形成具有半晶相的微孔状结构,因此在电解质中加入PVdF能够降低PEO的结晶度,从而导致NaSCN的各种离子缔合成分的百分数随PVdF的含量的变化而变化,而且这种变化的... 虽然PVdF几乎不与NaSCN发生溶剂化作用,但由于PVdF可以在PEO-NaSCN电解质中形成具有半晶相的微孔状结构,因此在电解质中加入PVdF能够降低PEO的结晶度,从而导致NaSCN的各种离子缔合成分的百分数随PVdF的含量的变化而变化,而且这种变化的程度还与电解质中NaSCN的含量有关。 展开更多
关键词 聚氧化乙烯 聚偏氟乙烯 NASCN 聚合物电解质 离子缔合
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