The present work evaluated the properties of modified concrete using polyethylene terephthalate (PET) bottle waste as a partial replacement for coarse aggregate. Modified concrete samples were designed using a water/c...The present work evaluated the properties of modified concrete using polyethylene terephthalate (PET) bottle waste as a partial replacement for coarse aggregate. Modified concrete samples were designed using a water/cement (W/C) ratio of 0.50 and varying percentages of PET replacement (3%, 7%, 10%, and 15% by volume). Dreux Gorisse’s formulation approach was used to make the final products, and the mechanical properties of the samples were determined using Controlab presses. This modified concrete with PET chips has shown that with a 10% replacement of PET chips, the fresh density decreases by 3.56%, and the hardened state density decreases by 2.01%. The water absorption and thermal conductivity of the formulated concretes decreased. However, the results showed that the slump of these fresh concretes increased as the percentage of plastic aggregate replacement increased. Based on the results, incorporating PET aggregates into concrete contributes to good workability, and lightweight concrete structures, and provides some thermal comfort in concrete structures.展开更多
This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ...This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ethylene glycol as depolymerizing agent and zinc acetate dihydrate as catalyst.The glycolysis product,bis（2-hydroxyethyl） terephthalate（BHET）,was purified through repeated crystallization to get an average yield above 80%.Then,BHET was nitrated,reduced,and azotized to get diazonium salt.Finally,the produced diazonium salt was coupled with 1-（4-sulfophenyl）-3-methyl-5-pyrazolone to get azo dyestuff.The structures of BHET and azo dyestuff were identified by FT1 R and ^1H NMR spectra and elemental analysis.Nylon filaments dyed by the synthesized azo dyestuff with the dye bath pH from 4.14 to 5.88 showed bright yellow color.The performances of the dyestuff were described with dye uptake,color fastness,K/S,L^＊,a^＊,b^＊.and △E^＊ values.展开更多
文摘The present work evaluated the properties of modified concrete using polyethylene terephthalate (PET) bottle waste as a partial replacement for coarse aggregate. Modified concrete samples were designed using a water/cement (W/C) ratio of 0.50 and varying percentages of PET replacement (3%, 7%, 10%, and 15% by volume). Dreux Gorisse’s formulation approach was used to make the final products, and the mechanical properties of the samples were determined using Controlab presses. This modified concrete with PET chips has shown that with a 10% replacement of PET chips, the fresh density decreases by 3.56%, and the hardened state density decreases by 2.01%. The water absorption and thermal conductivity of the formulated concretes decreased. However, the results showed that the slump of these fresh concretes increased as the percentage of plastic aggregate replacement increased. Based on the results, incorporating PET aggregates into concrete contributes to good workability, and lightweight concrete structures, and provides some thermal comfort in concrete structures.
基金financially supported by the National High-tech R&D Program of China(863 Program,No.2012AA030313)the Open Project Program of Key Laboratory of Eco-Textiles(Jiangnan University),Ministry of Education,China(No.KLET1115)+1 种基金the Fundamental Research Funds for the Central Universities(No. JUSRP11201)the Cooperative Innovation Fund-Prospective Project of Jiangsu Province,China(No.BY2012060)
文摘This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ethylene glycol as depolymerizing agent and zinc acetate dihydrate as catalyst.The glycolysis product,bis（2-hydroxyethyl） terephthalate（BHET）,was purified through repeated crystallization to get an average yield above 80%.Then,BHET was nitrated,reduced,and azotized to get diazonium salt.Finally,the produced diazonium salt was coupled with 1-（4-sulfophenyl）-3-methyl-5-pyrazolone to get azo dyestuff.The structures of BHET and azo dyestuff were identified by FT1 R and ^1H NMR spectra and elemental analysis.Nylon filaments dyed by the synthesized azo dyestuff with the dye bath pH from 4.14 to 5.88 showed bright yellow color.The performances of the dyestuff were described with dye uptake,color fastness,K/S,L^＊,a^＊,b^＊.and △E^＊ values.
