The forming mechanism of the multi-component polymer melt is always the difficult problem in the study on the composite fiber, due to the difference of the material properties. The study simulated the flow of PET/PA6 ...The forming mechanism of the multi-component polymer melt is always the difficult problem in the study on the composite fiber, due to the difference of the material properties. The study simulated the flow of PET/PA6 composite melt on the influence law for the velocity distribution and the micro hole's structure on the influence law for extrusion swelling based on the theory of the rheology and the spinning process and the structure of the spinning components by Polyflow. In addition by comparison with the previous experiments about extrusion swelling, the results show that the value of the swell ratio decreases rapidly at low values of length/ diameter and then levels off as length/diameter is increased further, whereas increases with the die exit angle increasing. The veincity distribution of the composite melt and the micro hole's structure have a significant influence on the extrusion swelling, which has very good guidance function for studying the forming mechanism of the composite melt and preparation of the high performance fiber.展开更多
On the basis of melt-spinning, the dynamics model of polyethylene terephthalate (PET) hollow fiber is established. The effects of spinning conditions on hollow ratio are discussed and verified. Because of the differ...On the basis of melt-spinning, the dynamics model of polyethylene terephthalate (PET) hollow fiber is established. The effects of spinning conditions on hollow ratio are discussed and verified. Because of the different quenching conditions, there exist differences of the hollow ratio and the vitrification distances between different cycles. The important role of the quenching conditions on the meltspinning of PEr hollow fiber is also mentioned.展开更多
基金Innovation Program of Shanghai Municipal Education Commission,China(No.12ZZ066)the Research Fund for the Doctoral Program of Higher Education of China(No.20100075120011)+1 种基金the Fundamental Research Funds for the Central Universities,Chinathe Innovation Team Development Plan of Ministry of Education,China
文摘The forming mechanism of the multi-component polymer melt is always the difficult problem in the study on the composite fiber, due to the difference of the material properties. The study simulated the flow of PET/PA6 composite melt on the influence law for the velocity distribution and the micro hole's structure on the influence law for extrusion swelling based on the theory of the rheology and the spinning process and the structure of the spinning components by Polyflow. In addition by comparison with the previous experiments about extrusion swelling, the results show that the value of the swell ratio decreases rapidly at low values of length/ diameter and then levels off as length/diameter is increased further, whereas increases with the die exit angle increasing. The veincity distribution of the composite melt and the micro hole's structure have a significant influence on the extrusion swelling, which has very good guidance function for studying the forming mechanism of the composite melt and preparation of the high performance fiber.
文摘On the basis of melt-spinning, the dynamics model of polyethylene terephthalate (PET) hollow fiber is established. The effects of spinning conditions on hollow ratio are discussed and verified. Because of the different quenching conditions, there exist differences of the hollow ratio and the vitrification distances between different cycles. The important role of the quenching conditions on the meltspinning of PEr hollow fiber is also mentioned.