Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petrole...Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petroleum ether and ethyl acetate. Results show that each atropisomer could be successfully synthesized by controlling the acylation temperature at 0 ℃. They were characterized by 1H NMR, HRMS, IR, UV-Vis and Langmuir-Blodgett（LB） film analyses. Although the results of HRMS, IR, UV-Vis analyses indicate there is no remarkable difference among the atropisomers, the results of the 1H NMR and the mean molecular areas obtained by LB film technique imply that the atropisomers are significantly discrepant. The former shows that the chemical shifts of the methyl and amide protons of each atropisomer are distinct, while the later presents that the different atropisomer molecules can occupy the different surface areas at the air/water interface.展开更多
The ablative Richtmyer–Meshkov instability(ARMI) is crucial to the successful ignition implosion of the inertial confinement fusion(ICF) because of its action as the seed of the Rayleigh–Taylor instability. In usual...The ablative Richtmyer–Meshkov instability(ARMI) is crucial to the successful ignition implosion of the inertial confinement fusion(ICF) because of its action as the seed of the Rayleigh–Taylor instability. In usual ICF implosions, the first shock driven by various foots of the pulses plays a central role in the ARMI growth. We propose a new scheme for refraining from ARMI with a pulse of successive pickets. With the successive-picket pulse design, a rippled capsule surface is compressed by three successive shocks with sequentially strengthening intensities and ablated stabilization, and the ablative Richtmyer–Meshkov growth is mitigated quite effectively.Our numerical simulations and theoretical analyses identify the validity of this scheme.展开更多
基金Supported by the National Natural Science Foundation of China(No.20806025)
文摘Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petroleum ether and ethyl acetate. Results show that each atropisomer could be successfully synthesized by controlling the acylation temperature at 0 ℃. They were characterized by 1H NMR, HRMS, IR, UV-Vis and Langmuir-Blodgett（LB） film analyses. Although the results of HRMS, IR, UV-Vis analyses indicate there is no remarkable difference among the atropisomers, the results of the 1H NMR and the mean molecular areas obtained by LB film technique imply that the atropisomers are significantly discrepant. The former shows that the chemical shifts of the methyl and amide protons of each atropisomer are distinct, while the later presents that the different atropisomer molecules can occupy the different surface areas at the air/water interface.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11675026,11875091 and 11575034
文摘The ablative Richtmyer–Meshkov instability(ARMI) is crucial to the successful ignition implosion of the inertial confinement fusion(ICF) because of its action as the seed of the Rayleigh–Taylor instability. In usual ICF implosions, the first shock driven by various foots of the pulses plays a central role in the ARMI growth. We propose a new scheme for refraining from ARMI with a pulse of successive pickets. With the successive-picket pulse design, a rippled capsule surface is compressed by three successive shocks with sequentially strengthening intensities and ablated stabilization, and the ablative Richtmyer–Meshkov growth is mitigated quite effectively.Our numerical simulations and theoretical analyses identify the validity of this scheme.
