Pillar effect induced by ultrahigh phosphorous/nitrogen doping enables graphene/MXene film with excellent cycling stability for alkali metal ion storage

Graphene's large theoretical surface area and high conductivity make it an attractive anode material for potassium-ion batteries(PIBs).However,its practical application is hindered by small interlayer distance and long ion transfer distance.Herein,this paper aims to address the issue by introducing MXene through a simple and scalable method for assembling graphene and realizing ultrahigh P doping content.The findings reveal that MXene and P-C bonds have a "pillar effect" on the structure of graphene,and the P-C bond plays a primary role.In addition,N/P co-doping introduces abundant defects,providing more active sites for K^(+) storage and facilitating K^(+) adsorption.As expected,the developed ultrahigh phosphorous/nitrogen co-doped flexible reduced graphene oxide/MXene(NPrGM) electrode exhibits remarkable reversible discharge capacity(554 mA hg^(-1) at 0.05 A g^(-1)),impressive rate capability(178 mA h g^(-1) at 2 A g^(-1)),and robust cyclic stability(0.0005% decay per cycle after 10,000 cycles at 2 A g^(-1)).Furthermore,the assembled activated carbon‖NPrGM potassium-ion hybrid capacitor(PIHC) can deliver an impressive energy density of 131 W h kg^(-1) and stable cycling performance with 98.1% capacitance retention after5000 cycles at 1 A g^(-1).Such a new strategy will effectively promote the practical application of graphene materials in PIBs/PIHCs and open new avenues for the scalable development of flexible films based on two-dimensional materials for potential applications in energy storage,thermal interface,and electromagnetic shielding.

Estimating shear strength of high-level pillars supported with cemented backfilling using the HoekeBrown strength criterion

Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational.

Stability prediction of hard rock pillar using support vector machine optimized by three metaheuristic algorithms

Hard rock pillar is one of the important structures in engineering design and excavation in underground mines.Accurate and convenient prediction of pillar stability is of great significance for underground space safety.This paper aims to develop hybrid support vector machine(SVM)models improved by three metaheuristic algorithms known as grey wolf optimizer(GWO),whale optimization algorithm(WOA)and sparrow search algorithm(SSA)for predicting the hard rock pillar stability.An integrated dataset containing 306 hard rock pillars was established to generate hybrid SVM models.Five parameters including pillar height,pillar width,ratio of pillar width to height,uniaxial compressive strength and pillar stress were set as input parameters.Two global indices,three local indices and the receiver operating characteristic(ROC)curve with the area under the ROC curve(AUC)were utilized to evaluate all hybrid models’performance.The results confirmed that the SSA-SVM model is the best prediction model with the highest values of all global indices and local indices.Nevertheless,the performance of the SSASVM model for predicting the unstable pillar(AUC:0.899)is not as good as those for stable(AUC:0.975)and failed pillars(AUC:0.990).To verify the effectiveness of the proposed models,5 field cases were investigated in a metal mine and other 5 cases were collected from several published works.The validation results indicated that the SSA-SVM model obtained a considerable accuracy,which means that the combination of SVM and metaheuristic algorithms is a feasible approach to predict the pillar stability.

Lateral abutment pressure distribution and evolution in wide pillars under the first mining effect

The wide pillars are generally popular due to the high productivity and efficiency in Northwest China.The distribution of lateral abutment pressure in coal pillars is important for mining safety.To reveal the effect of the first mining on the lateral abutment pressure distribution and evolution in wide pillars,an in-situ experiment,theoretical analysis and numerical simulation were performed.First,the field monitoring of lateral abutment pressure was conducted from the perspective of time and space in the Chahasu Coal Mine,Huangling No.2 Coal Mine and Lingdong Coal Mine during the first mining.Based on the field monitoring stress,a theoretical model was proposed to reveal the lateral abutment pressure distribution.The methodology was demonstrated through a case study.Aiming at the distribution mechanism,a numerical experiment was conducted through the finite-discrete element method(FDEM).Last,field observations of borehole fractures were performed to further study the damage distribution.In addition,two types of lateral abutment pressure evolution with mining advance were discussed.Suggestions on the stress monitoring layout were proposed as well.The results could provide foundations for strata control and disaster prevention in wide pillars in underground coal mines.

Mechanical behaviors of deep pillar sandwiched between strong and weak layers

A variety of coal room and pillar mining methods have been efficiently practiced at depths of up to 500 m with least strata mechanics issues.However,for the first time,this method was trialled at depths of 850 e900 m in CSM mine of Czech Republic.The rhomboid-shaped coal pillars with acute corners of 70,surrounded with 5.2 m wide and 3.5e4.5 m high mine roadways,were used.Pillars were developed in a staggered manner with their size variation in the Panel II from 83 m×25 m to 24 m×20 m(corner to corner)and Panel V from 35 m×30 m to 26 m×16 m.Coal seam inclined at 12was affected by the unusual slippery slickenside roof bands and sometimes in the floor levels with high vertical stress below strong and massive sandstone roof.In order to ensure safety,pillars in both the panels were continuously monitored using various geotechnical instruments measuring the induced stresses,side spalling and roof sagging.Both panels suffered high amounts of mining induced stress and pillar failure with side-spalling up to 5 m from all sides.Heavy fracturing of coal pillar sides was controlled by fully encapsulated steel bolts.Mining induced stress kept increasing with the progress of development of pillars and galleries.Instruments installed in the pillar failed to monitor actual induced stress due to fracturing of coal mass around it which created an apprehension of pillar failure up to its core due to high vertical mining induced stress.This risk was reduced by carrying out scientific studies including the three-dimensional numerical models calibrated with data from the instrumented pillar.An attempt has been made to study the behavior of coal pillars and their yielding characteristics at deeper cover based on field and simulation results.

Determination of the load bearing capacity of pre-stressed expandable props for ground support in underground mines

This paper aims to determine the load bearing capacity of pre-stressed expandable props with different geometries and load eccentricities for flexible support in underground mining or excavation.It is deduced that the expandable device could have much higher strength(>89 MPa)by laboratory tests,and the load bearing capacity of the expandable prop may depend on the stability of the supporting steel pipe structure.A good agreement was found between the laboratory test and numerical results in terms of the load bearing capacity and the final macro-bending failure pattern for expandable props with heights of 1.5 and 2.7 m,and the theoretical calculation for the strength of traditional steel structures is not directly suitable for the expandable props.Moreover,additional numerical simulations were performed for the expandable props with different normalized slenderness ratiosλ_(n)and loading eccentric distances e.The variation of stability coefficient of the expandable prop is in line with the Perry-Robertson equation and its correlation coefficients are fitted as a of 0.979 and b of 0.314.For estimating the load bearing capacity of the expandable props,the strength equation for traditional steel structures is improved by introducing a bending magnification factor and by modifying the normalized slenderness ratio to a converted slenderness ratio.Based on the underground field monitoring for the strength of expandable props with different heights,the empirical eccentric distances were back calculated,and a safety factor is introduced to obtain the designed strength of the expandable prop.In addition,a four-step design procedure is proposed for the expandable prop.

Study on the disaster caused by the linkage failure of the residual coal pillar and rock stratum during multiple coal seam mining:mechanism of progressive and dynamic failure

Multi-seam mining often leads to the retention of a significant number of coal pillars for purposes such as protection,safety,or water isolation.However,stress concentration beneath these residual coal pillars can significantly impact their strength and stability when mining below them,potentially leading to hydraulic support failure,surface subsidence,and rock bursting.To address this issue,the linkage between the failure and instability of residual coal pillars and rock strata during multi-seam mining is examined in this study.Key controls include residual pillar spalling,safety factor(f.),local mine stiffness(LMS),and the post-peak stiffness(k)of the residual coal pillar.Limits separating the two forms of failure,progressive versus dynamic,are defined.Progressive failure results at lower stresses when the coal pillar transitions from indefinitely stable(f,>1.5)to failing(f,<1.5)when the coal pillar can no longer remain stable for an extended duration,whereas sud-den(unstable)failure results when the strength of the pillar is further degraded and fails.The transition in mode of failure is defined by the LMS/k ratio.Failure transitions from quiescent to dynamic as LMS/k.<1,which can cause chain pillar instability propagating throughout the mine.This study provides theoretical guidance to define this limit to instability of residual coal pillars for multi-seam mining in similar mines.

Evaluation of roof cutting by directionally single cracking technique in automatic roadway formation for thick coal seam mining

Automatic roadway formation by roof cutting is a sustainable nonpillar mining method that has the potential to increase coal recovery,reduce roadway excavation and improve mining safety.In this method,roof cutting is the key process for stress relief,which significantly affects the stability of the formed roadway.This paper presents a directionally single cracking(DSC)technique for roof cutting with considerations of rock properties.The mechanism of the DSC technique was investi-gated by explicit finite element analyses.The DSC technique and roof cutting parameters were evaluated by discrete element simulation and field experiment.On this basis,the optimized DSC technique was tested in the field.The results indicate that the DSC technique could effectively control the blast-induced stress distribution and crack propagation in the roof rock,thus,achieve directionally single cracking on the roadway roof.The DsC technique for roof cutting with optimized parameters could effectively reduce the deformation and improve the stability of the formed roadway.Field engineering application verified the feasibility and effectiveness of the evaluated DSC technique for roof cutting.

Numerical modeling of destress blasting for strata separation

Destress blasting(DB)implemented along the perimeter of safety pillars is a special application of destressing in coal longwall mining.The goal is to separate relatively more deformed mined areas from safety pillars,such as shaft pillars or cross-cut pillars,to reduce the transfer of high stresses to the protective pillar.This case study aims to numerically simulate selected destress blasts in the Czech part of the Upper Silesian Coal Basin and examine its impact on stress transfer to the safety pillar area.To separate the area between the protective pillar and the longwall(LW),two fans of five 93-mm blast holes(length of 93e100 m)were drilled from the gate roads into the overburden strata.Each set of blast holes was fired separately in two stages without time delay.The explosive charge(gelatin-type of explosive)of each stage is 3450 kg.The two DB stages were fired when the longwall face was approximately 158 m and 152 m away from the blast.A 3D mine-wide model is built and validated with in situ stress measured with hydrofracturing.Mining and destressing in three 5-m thick coal seams are simulated in the region.Numerical modeling of DB is successfully conducted using a rock fragmentation factor a of 0.05 and a stress reduction/dissipation factor β of 0.95.Buffering of transfer of additional stress from the mining area into the safety pillar is evaluated by comparison of yielding volume before and after DB.It is shown that yielding volume drops after DB by nearly 80%in the area of the destressing panel and near the safety shaft pillar.

Experimental study on the movement law of overlying rock non-pillar coal overhead mining

Pillarless coal mining technology is a new practical technology.Based on the compensating mechanical behavior of the Negative Poisson’s Ratio(NPR)anchor cable on the roof,the roadway was successfully retained by the top cutting and pressure relief technology.This study utilizes the Digital Speckle Monitoring(DIC monitoring),stress-strain monitoring,and infrared thermal imaging systems to conduct physical model experiment of similar materials from the displacement,stress-strain,and temperature fields to investigate in depth the fracture change law of the overlying rock.In addition,it uses FLAC3D numerical simulation to invert the surface displacement settlement.The results show that the non-pillar overhead mining under the 110 mining method has little influence on the rock crack in the middle of the coal seam,and the crack development area is mainly concentrated in the overlying rock mass of the upward coal seam.The compensatory mechanical behavior of NPR anchor cable and the dilatation characteristics of rock mass have a good effect of retaining roadway along goaf,and can also reduce surface settlement.The 110 mining method provides a scientific basis for ecological environment protection and the development of other kilometer deep soft rock high ground stress underground projects.

Safety analysis of Sormeh underground mine to improve sublevel stoping stability

In underground mines,sublevel stoping is used among a variety of different methods for mining an orebody,which creates large underground openings.In this case,the stability of these openings is affected by a number of factors,including the geometrical characteristics of the rock and mining-induced stresses.In this study,a sensitivity analysis was conducted with the numerical,squat pillar,and Mathews stability methods using the Taguchi technique to properly understand the influence of geometric parameters and stress on stope stability according to Sormeh underground mine data.The results show a full factorial analysis is more reliable since stope stability is a complex process.Furthermore,the numerical results indicate that overburden stress has the most impact on stope stability,followed by stope height.However,the results obtained with Mathews and squat pillar methods show that stope height has the greatest impact,followed by overburden stress and span.It appears that these methods overestimate the impact of stope height.Therefore,it is highly recommended that Mathews and squat pillar methods should not be used in high stope that is divided with several sill pillars.Nonetheless,Mathews method cannot accurately predict how the sill pillar impacts the stope stability.In addition,numerical analysis shows that all geometric parameters affect the roof safety factor,whereas the sill pillar has no significant influence on the safety factor of the hanging wall,which is primarily determined by the stope height–span ratio.

The Potential of Commercial Pension Insurance to Develop into One of the Pillars of Rural Pension Insurance:A Study from the Demand Perspective

The development of a multi-pillar pension insurance system is an effective solution for an aging society.Commercial pension insurance,as the third pillar of pension insurance,is an integral part of this system in China and can play a critical and complementary role in rural areas where support for the elderly is a more pressing concern and a second pillar of pension insurance remains absent.To this end,we first elaborate on the theoretical logic that commercial pension insurance can develop into one of the pillars of rural pension insurance.We then empirically test rural residents’willingness to participate in a commercial pension insurance plan(CPIP)in a probit model with household research data from rural areas in major labor-exporting provinces,such as Sichuan and Henan so as to explore whether commercial pension insurance has the potential to become one of the pillars of rural pension insurance.Our research findings can be synthesized in three points.First,rural residents out of agricultural production for five consecutive years are more willing to participate in a CPIP than other rural residents,indicating that progress in industrialization and urbanization can significantly boost such willingness.Second,the younger rural residents are more inclined to participate in a CPIP than the older generation.Third,income increases can significantly boost rural residents’willingness to participate in a CPIP.Thus,with progress in industrialization and urbanization and an increase in rural disposable income,commercial pension insurance has a promising potential in rural areas and can hopefully develop into one of the pillars of rural pension insurance.

三维复杂断层网建模方法及应用

针对复杂断层网,提出一种新的路径切割算法,能够处理各种复杂的断层相交情况,如Y型、λ型、X型、半Y型、半λ型等削截关系;避免了Pillar方法和二叉树等传统方法的限制,提高了断层建模的灵活性和精确度。该方法提高了断面之间接触关系的半自动处理程度,方便断层网的快速更新。通过实际模型的验证,解决了复杂断层网的快速构建问题,提高了建模效率。

“地质网格”技术在复杂断块油藏地质建模中的应用

符合客观实际的三维地质模型是油藏地质研究的最终成果,而目前常用的建模软件及其数学算法在构建复杂构造模型和强非均质储集层模型时存在局限性。本文以大港油田C区Z断块为例,利用"地质网格"技术避免了常规PILLAR网格系统在建立构造模型时遇到的网格扭曲现象,确保了构造的完整性和准确性;应用相控多变差函数分析技术弥补了单一变差函数无法准确表征储层空间分布状况及物性变化特征的缺憾,较好地解决了沉积微相变化快、储层非均质性强等问题,为油田勘探开发部署提供了更符合客观实际的精细地质模型。

应用Petrel进行构造建模的研究

采用Petrel软件进行构造建模能更准确直观反映地下构造情况。以某油田工区为例,在地质资料分析的基础上,以地震资料解释及合成地震记录标定结果为约束条件,采用构造特征分析技术研究了分析断层间的接触关系及其延展趋势,建立该研究区的构造模型,并针对建模过程中出现的问题,提出了相应的解决方法。该研究方法提高了构造解释的精度,为后续的油藏地质建模奠定了基础。

微创经椎弓根Pillar植入治疗胸腰椎压缩性骨折疗效及相关并发症分析

目的 ：探讨经椎弓根pillar植入治疗胸腰椎压缩性骨折的临床效果及相关并发症。方法 ：回顾分析2010年1月～2013年4月采用微创经椎弓根pillar置入治疗胸腰椎压缩性骨折患者27例的临床疗效。手术前后进行疼痛强度视觉模拟评分（visual analogue scale,VAS）、Oswestry功能障碍指数（Oswestry disability index,ODI）、伤椎前缘高度比值、矢状面指数（伤椎前缘高度/伤椎后缘高度×100%）、伤椎Cobb′s角。结果：27例患者共植入54枚椎体支柱块,均获得6～26个月的随访,平均手术时间为（47.6±8.5）min,平均术中失血量（28.4±12.3）ml。术后CT证实17例患者椎弓根皮质有破裂,其中外侧皮质破裂15例,内侧皮质破裂2例,其中1例患者因内侧壁破裂引起下肢神经症状,经治疗后缓解。术后1周及末次随访时VAS评分、ODI值、椎体前缘高度比值、矢状面指数值及伤椎Cobb′s角与术前比较差异均具有统计学意义（P〈0.05）,而术后1周与末次随访时比较差异无统计学意义（P〉0.05）,椎体支柱块未发生移位或塌陷。结论：微创经椎弓根pillar置入是治疗胸腰椎压缩骨折一种安全、有效、可行的方法,严格掌握手术适应证、术中规范操作可降低并发症的发生。

Pillar植入系统联合鼻部手术治疗OSAHS 38例疗效分析

目的探讨Pillar植入系统联合鼻部手术治疗阻塞性睡眠呼吸暂停低通气综合征(OSAHS)的效果。方法选取2006年7至2008年11月本科OSAHS患者38例,38例均同期行Pillar植入系统治疗和鼻部手术,术前及术后6个月均行多导睡眠呼吸监测(polysomnography,PSG),对术前及术后的PSG结果(包括AHI、LSaO2)进行统计学分析。结果术后6个月进行PSG监测,治愈10例,好转17例,减轻7例,无效4例,总有效率达89.5%;所有患者无手术并发症发生。结论Pillar植入系统联合鼻部手术治疗单纯型鼾症(primary snoring,PS)及轻-中度OSAHS可取得良好效果。

平行束孔爆破模型试验及其机理探讨

本文介绍了垂直密集束状平行炮孔(简称平行束孔)落矿有底柱崩落采矿法的实质和结构,并分析了它的特点和优点。由于平行束孔落矿是核心的关键技术,本文为此做了爆破模型试验,对其爆破机理进行了研究和探讨。该项研究在国内尚属首次。

Pillar植入术治疗阻塞性睡眠呼吸暂停综合征病人的观察和护理

[目的]探讨Pillar植入术治疗阻塞性睡眠呼吸暂停综合征(OSAS)的护理及术后随访。[方法]46例鼾症病人经我导睡眠仪(PSG)监测分为轻至中度OSAS(28例)、重度OSAS(6例)和单纯鼾症(12例)3组,行Pillar植入术,并给予全面的身心护理和健康教育,术前及术后1个月和6个月均进行鼾声视觉类比量表(VAS)评分和PSG监测。[结果]术后随访6个月,Pillar植入系统对于轻至中度OSAS病人和单纯鼾症病人打鼾的改善显著,而对于重度OSAS病人疗效较差。28例轻至中度OSAS病人治愈4例,显效10例,有效5例,无效9例,总有效率达67.9%,呼吸紊乱指数(AHI)由术前的每小时17.03次±10.63次到术后6个月降至每小时11.17次±9.52次;6例重度OSAS病人有效1例(1/6),AHI由术前每小时62.93次±9.21次降至每小时55.42次±13.77次,46例病人术后无并发症。[结论]Pillar植入系统对于治疗鼾症可以有效地改善打鼾,对于睡眠呼吸暂停的改善轻至中度OSAS病人的疗效较好,而重度OSAS病人的疗效较差。而做好Pillar手术的护理,可帮助病人顺利完成手术治疗,减轻他们术前的忧虑和术后的痛苦,获得满意效果,提高生活质量。

油藏体数模综合展示技术研究

为扩展用户业务数据的展示,综合分析油藏体的地质结构以及油水分布情况,研究复杂三维地层油藏数值模拟可视化实现过程中的关键技术,先分析现有数模软件输出文件格式,结合用户特定业务数据,应用Pillar模型构建三维地层模型,再使用Open Inventor三维图像开发平台完成3D展示,在此基础上实现三维模型网格筛选、切片、色谱自定义等人机交互功能,提供油藏体数值模拟综合展示功能。