Coarse (PM2.5-10) and fine (PM2.5) atmospheric particulate samples were collected in summer and winter during 2005―2007 in the juncture belt between urban and rural areas of Beijing. Elements, ions, organic/elemental...Coarse (PM2.5-10) and fine (PM2.5) atmospheric particulate samples were collected in summer and winter during 2005―2007 in the juncture belt between urban and rural areas of Beijing. Elements, ions, organic/elemental carbon (OC/EC) and polynuclear aromatic hydrocarbons (PAHs) were determined to obtain some latest information about the particulate pollution in the juncture belt of Beijing. Particulate matter levels at this site were high as compared with the levels at other sampling sites in Beijing. Pollution elements, secondary ions and PAHs were enriched in fine particles rather than in coarse particles. An obvious seasonal variation of the chemical composition of PM was observed. Source apportionment results showed that secondary components were the largest mass contributor of PM2.5, accounting for 28%; whereas soil-related sources were the largest contributor of PM2.5-10, explaining about 49% of the total mass. The abnormal levels of soil heavy metals at the electronic waste disassembly site in the upwind villages suggested the potential impact of such activities to the environment.展开更多
PM2.5 and PM2.5 lo concentrations, elemental constituents, and sources in a densely populated coastal industrial area （Trombay, Mumbai） were investigated in 2010 and 2011.The PM2.s and PM2.s lo concentra- tions were...PM2.5 and PM2.5 lo concentrations, elemental constituents, and sources in a densely populated coastal industrial area （Trombay, Mumbai） were investigated in 2010 and 2011.The PM2.s and PM2.s lo concentra- tions were 13.50-71.60 and 22.40-127.78 p^g/m3, respectively. The daily PM25 concentrations exceeded the Indian Central Pollution Control Board limit （60 μg/m3） several days in winter. Of the elements analyzed, Si then Al had the highest concentrations in PM2.5- 10, but black carbon then Si had the highest concentrations in PM2.s. The element concentrations varied widely by season. Al, Ca, Fe, Si, and Ti con- centrations were highest in summer, Cl, Mg, and Na concentrations were highest in the monsoon season, and the other trace metal concentrations in both PM2.5 and PM2.5-10 were highest in winter. The PM2.5 and PM2.5-10 sources were apportioned by positive matrix factorization. PM2.5 and PM2.5-10 had six dominant sources, crustal material （8.7% and 25.3%, respectively）, sea salt spray （6.1% and 15.0%, respectively）, coal/biomass combustion （25.5% and 13.8%, respectively）, fuel oil combustion （19.0% and 11.2%, respectively）, road traffic （ 17.7% and 12.6%, respectively）, and the metal industry （ 10.6% and 7.0%, respectively）. Anthropogenic sources clearly contributed most to PM2.5 but natural sources contributed most to PM2.5-10.展开更多
基金Supported by the Swedish International Development Agency (SIDA), National Science Fund for Distinguished Young Scholars (Grant No. 20725723)State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences (Grant No. KF2008-18)
文摘Coarse (PM2.5-10) and fine (PM2.5) atmospheric particulate samples were collected in summer and winter during 2005―2007 in the juncture belt between urban and rural areas of Beijing. Elements, ions, organic/elemental carbon (OC/EC) and polynuclear aromatic hydrocarbons (PAHs) were determined to obtain some latest information about the particulate pollution in the juncture belt of Beijing. Particulate matter levels at this site were high as compared with the levels at other sampling sites in Beijing. Pollution elements, secondary ions and PAHs were enriched in fine particles rather than in coarse particles. An obvious seasonal variation of the chemical composition of PM was observed. Source apportionment results showed that secondary components were the largest mass contributor of PM2.5, accounting for 28%; whereas soil-related sources were the largest contributor of PM2.5-10, explaining about 49% of the total mass. The abnormal levels of soil heavy metals at the electronic waste disassembly site in the upwind villages suggested the potential impact of such activities to the environment.
文摘PM2.5 and PM2.5 lo concentrations, elemental constituents, and sources in a densely populated coastal industrial area （Trombay, Mumbai） were investigated in 2010 and 2011.The PM2.s and PM2.s lo concentra- tions were 13.50-71.60 and 22.40-127.78 p^g/m3, respectively. The daily PM25 concentrations exceeded the Indian Central Pollution Control Board limit （60 μg/m3） several days in winter. Of the elements analyzed, Si then Al had the highest concentrations in PM2.5- 10, but black carbon then Si had the highest concentrations in PM2.s. The element concentrations varied widely by season. Al, Ca, Fe, Si, and Ti con- centrations were highest in summer, Cl, Mg, and Na concentrations were highest in the monsoon season, and the other trace metal concentrations in both PM2.5 and PM2.5-10 were highest in winter. The PM2.5 and PM2.5-10 sources were apportioned by positive matrix factorization. PM2.5 and PM2.5-10 had six dominant sources, crustal material （8.7% and 25.3%, respectively）, sea salt spray （6.1% and 15.0%, respectively）, coal/biomass combustion （25.5% and 13.8%, respectively）, fuel oil combustion （19.0% and 11.2%, respectively）, road traffic （ 17.7% and 12.6%, respectively）, and the metal industry （ 10.6% and 7.0%, respectively）. Anthropogenic sources clearly contributed most to PM2.5 but natural sources contributed most to PM2.5-10.
