Early Devonian Post-collisional Granitic Magmatism in the North Qilian Orogenic Belt,Western China:Insights into Lithospheric Delamination and Orogenic Collapse

Post-collisional magmatism contains important clues for understanding the reworking and growth of continental crust,as well as lithospheric delamination and orogenic collapse.Early Devonian magmatism has been identified in the North Qilian Orogenic Belt(NQOB).This paper reports an integrated study of petrology,whole-rock geochemistry,Sm-Nd isotope and zircon U-Pb dating,as well as Lu-Hf isotopic data,for two Early Devonian intrusive plutons.The Yongchang and Chijin granites yield zircon U-Pb ages of 394-407 Ma and 414 Ma,respectively.Both of them are characterized by weakly peraluminous to metaluminous without typical aluminium-rich minerals,LREE-enriched patterns with negative Eu anomalies and a negative correlation between P_(2)O_(5) and SiO_(2) contents,consistent with geochemical features of I-type granitoids.Zircons from the studied granites display negative to weak positive ε_(Hf)(t)values(−5.7 to 2.1),which agree well with those of negative ε_(Nd)(t)values(−6.4 to−2.9)for the whole-rock samples,indicating that they were derived from the partial melting of Mesoproterozoic crust.Furthermore,low Sr/Y ratios(1.13-21.28)and high zircon saturation temperatures(745℃ to 839℃,with the majority being>800℃)demonstrated a relatively shallow depth level below the garnet stability field and an additional heat source.Taken together,the Early Devonian granitic magmatism could have been produced by the partial melting of ancient crustal materials heated by mantle-derived magmas at high-temperature and low-pressure conditions during postcollisional extensional collapse.The data obtained in this study,when viewed in conjunction with previous studies,provides more information about the tectonic processes that followed the closure of the North Qilian Ocean.The tectonic transition from continental collision to post-collisional delamination could be constrained to~430 Ma,which is provided by the sudden decrease of Sr/Y and La/Yb ratios and an increase in zircon ε_(Hf)(t)values for granitoids.A two-stage tectonic evolution model from continental collision to post-collisional extensional collapse for the NQOB includes(a)continental collision and crustal thickening during ca.455-430 Ma,characterized by granulite-facies metamorphism and widespread low-Mg adakitic magmatism;(b)post-collisional delamination of thickened continental crust and extensional collapse of orogen during ca.430-390 Ma,provided by coeval high-Mg adakitic magmatism,A-type granites and I-type granitoids with low Sr-Y ratios.

Carboniferous Post-collisional Rift Volcanism of the Tianshan Mountains, Northwestern China

The Tianshan Carboniferous post-collisional rift volcanic rocks occur in northwestern China as a large igneous province. Based on petrogeochemical data, the Tianshan Carboniferous post-collisional rift basic lavas can be classified into two major magma types: (1) the low-Ti/Y type situated in the eastern-central Tianshan area, which exhibits low Ti/Y (<500), Ce/Yb (<15) and SiO2 (43-55%), and relatively high Fe2O3T (6.4-11.5%); (2) the high-Ti/Y type situated in the western Tianshan area, which has high Ti/Y (>500), Ce/Yb (>11) and SiO2 (49-55%), and relatively low Fe2O3T (5.8-7.8%). Elemental data suggest that chemical variations of the low-Ti/Y and high-Ti/Y lavas cannot be explained by fractional crystallization from a common parental magma. The Tianshan Carboniferous basic lavas originated most likely from an OIB-like asthenospheric mantle source (87Sr/86Sr(t) ≈ 0.703-0.705, eNd(0 = +4 to +7). The crustal contamination and continental lithospheric mantle have also contributed significantly to the formation of the basic lavas of the Tianshan Carboniferous post-collisional rift. The silicic lavas were probably generated by partial melting of the crust. The data of this study show that spatial petrogeochemical variations exist in the Carboniferous post-collisional rift volcanics province in the Tianshan region. Occurrence of the thickest volcanics dominated by tholeiitic lavas may imply that the center of the mantle-melting anomaly (mantle plume) was in the eastern Tianshan area at that time. The basic volcanic magmas in the eastern Tianshan area were generated by a relatively high degree of partial melting of the mantle source around the spinel-garnet transition zone, whereas the alkaline basaltic lavas are of the dominant magma type in the western Tianshan area, which were generated by a low degree of partial melting of the mantle source within the stable garnet region, thus the basic lavas of the western Tianshan area might have resulted from relatively thick lithosphere and low geothermal gradient.

Post-collisional Adakitic Porphyries in Tibet:Geochemical and Sr-Nd-Pb Isotopic Constraints on Partial Melting of Oceanic Lithosphere and Crust-Mantle Interaction

The distribution of Neogene felsic porphyries intruding in earlier granitic batholiths was mainly controlled by north-south-tending rifting zones and normal faults. The main rock types of the felsic porphyries include granodiorite-porphyry, monzonitic granite-porphyry and quartz monzonitic porphyry. The porphyries are characterized by high SiO2 ((?)64.26%) and Al2O3 (>15% at 70% SiO2), low Y and HREE (Yb) contents, strong enrichment of LILE and LERR, especially K and ST. Geochemical features of the porphyries show distinct adakitic magma affinity. Nd, Sr and Pb isotopic compositions of the porphyries form a linear alignment from MORB to EM2, suggesting a mixing of the MORB reservoir with the metasomatized mantle reservoir. Considering also the geochemical characteristics of the porphyries and the sequence of observable structural-thermal-magmatic events at Gangdise, it is thought that the Neogene porphyries were formed by partial melting of dead subducted oceanic crust in a post-collision setting. K-enrichment in the porphyries is attributed to the interaction of slab-derived melts, i.e., adakites, with the metasomatized mantle during the ascent. There might be a delamination of residual eclogites or amphibole eclogites before the eruption of potassic lava on the Tibetan plateau since 13 Ma.

Metallogenic Series Related to Permian Mafic Complex in North Xinjiang:Post-collisional Stage or Mantle Plume Result?

There are four deposit types related to a Permian mafic complex in northern Xinjiang, i.e., copper-nickel sulfide deposit, vanadic titanomagnetite deposit, magnetite （-cobalt） deposit and Cu-Ni- VTiFe composite deposit. The deposits are distributed spanning tectonic units with close and consecutive metallogenic ages. A transitional deposit type can occur among the end-member deposits. Trace elements of host rocks show that they can derive from similar source area. Hence, they constitute a particular metallogenic series related to a mafic-ultramafic complex that is also a symbol series of the post-collisional stage of the Central Asia Metallogenic Province （CAMP）. The metallogenic ages of the series are between 260 Ma and 300 Ma throughout the Permian. Unlike mineralization from a mantle plume, the metallogenic period of this series spans at least 40 Ma. Compared with related deposits of the Emeishan mantle plume, the North Xinjiang series has a similar ore-forming element assemblage but has preferably developed Cu-Ni sulfide deposits rather than vanadic titanomagnetite deposits. In concomitance with this series, North Xinjiang area has developed a set of syntectonic Au-Cu-Mo metallogenic series related to a felsic volcanic-intrusive complex, which might indicate that there is no direct relationship with mantle plume activity. From early to late, i.e., the sequence of copper-nickel sulfide to magnetite （-cobalt） to vanadic titanomagnetite deposit, the host rock series evolves from mafic-ultramafic and tholeiite series to mafic and alkalic series, the ~REE content tends to increase with increasing of REE fractionation, and some of the trace elements （particularly LIL） also show an increasing tendency. The above evolutionary regularity possibly reflects a course where the magma source deepens and thermal interface moves down, energy gradually exhausts, and neo-continental crust forming in the postcollision stage tends to stabilize.

Paleozoic post-collisional magmatism and high-temperature granulite-facies metamorphism coupling with lithospheric delamination of the East Kunlun Orogenic Belt,NW China

Lithosphere extension and upwelling of asthenosphere at post-collisional stage of an orogenic cycle generally induce diverse magmatism and/or associated high-temperature metamorphism. Nevertheless, the intimate coexistence of post-collisional magmatic activity and high-temperature metamorphism is rare.In this contribution, a lithological assemblage composing of diverse magmatic rocks deriving from distinct magma sources and coeval high-temperature metamorphism was identified in eastern Kunlun.Petrography, ages, mineral chemistry and whole-rock geochemistry demonstrated that those intimately coexistent diverse rocks were genetically related to post-collisional extension. The garnet-bearing mafic granulites in Jinshuikou area interior of the East Kunlun Orogenic Belt are mainly composed of garnet,orthopyroxene, and plagioclase, with peak metamorphic P–T conditions of ~ 701–756 ℃and 5.6–7.0 kbar,representing a granulite-facies metamorphism at 409.7 ± 1.7 Ma. The diverse contemporaneous magmatic rocks including hornblendites, gabbros and granites yield zircon U–Pb ages of 408.6 ± 2.5 Ma,413.4 ± 4.6 Ma, and 387–407 Ma, respectively. The hornblendites show N-MORB-like REE patterns with(La/Sm)Nvalues of 0.85–0.94. They have positive zircon εHf(t) values of 0.1–4.9 and whole-rock εNd(t) values of 3.9–4.7 but relatively high(^(87)Sr/^(86)Sr)_(i)values of 0.7081 to 0.7088. These features demonstrate that the hornblendites derived from a depleted asthenospheric mantle source with minor continental crustal materials in source. As for the gabbros, they exhibit arc-like elemental signatures, low zircon εHf(t) values(-4.3 to 2.5) and variable whole-rock εNd(t) values(-4.9 to 1.2) as well as high(^(87)Sr/86 Sr)ivalues(0.7068 to 0.7126), arguing for that they were originated from partial melting of heterogeneous lithospheric mantle anteriorly metasomatized by subducted-sediment released melts. Geochemistry of the granites defines their strongly peraluminous S-type signatures. Zircons from the granites yield a large range of εHf(t) values ranging from -30.8 to -5.1, while the whole-rock samples yield consistent(^(87)Sr/86 Sr)ivalues(0.7301 to 0.7342) and negative εNd(t) values(-10.1 to -12.4). These features indicate that the S-type granites could be generated by reworking of an ancient crust. Taken together, the penecontemporaneous magmatism and metamorphic event, demonstrated the early-middle Devonian transition from crustal thickening to extensional collapse. The post-collisional mantle-derived magmas serve as an essential driving force for the high-temperature granulite-facies metamorphism and anataxis of the crust associated with formation of S-type granite. This study not only constructs a more detail Proto-Tethys evolution process of the eastern Kunlun, but also sheds new light on better understanding the intimate relationship between magmatism and metamorphism during post-collisional extensional collapse.

Geochemical characterization of Granitoids in Katchuan Irruan area: further evidence for peraluminous and shoshonitic compositions and post-collisional setting of granitic rocks in the Precambrian Basement Complex of Nigeria

Petrographic studies on Granitoids from Katchuan Irruan and adjoining areas,southeastern Nigeria,has shown that they are garnetiferous biotite granite,aplitic granite,porphyritic hornblende biotite granite,porphyritic muscovite biotite granite,weakly foliated leucogranodiorite and simple pegmatite.They are closely associated with the Precambrian Basement Complex rocks which they intruded.Modal analysis shows that the rocks consist of quartz(10%-25%),oligoclase(10%-30%),K-feldspar(15%-35%),biotite(3%-25%),with occasional garnet,hornblende,muscovite,and accessory chlorite,haematite and magnetite.Geochemical data indicates that the rocks are generally shoshonitic,alkali-calcic to calcic,ferroan and peraluminous.They are enriched in large ion lithophile elements as well as high field strength elements(Hf,Ta,Yb,Sm,Zr and Y).Their trace elements and REE patterns are similar,indicating that they are co-genetic.They are characterized by high fractionation factor(La/Yb)N(3.04-228.44)and pronounced negative Eu anomalies(Eu/Eu*)(0.23-0.71).Their overall geochemical features indicate that they were most likely derived from partial melting of crustal materials in an orogenic(post-collisional)tectonic setting.They are therefore related to the Pan-African granites,otherwise known as the Older Granites which were emplaced during the Pan African orogenic event.

Late syn-to post-collisional magmatism in Madagascar:The genesis of the Ambalavao and Maevarano Suites

The East African Orogen involves a collage of Proterozoic microcontinents and arc terranes that became wedged between older cratonic blocks during the assembly of Gondwana.The Ediacaran-Cambrian Ambalavao and Maevarano Suites in Madagascar were emplaced during the waning orogenic stages and consist of weakly deformed to undeformed plutonic rocks and dykes of mainly porphyritic granite but also gabbro,diorite and charnockite.U-Pb geochronological data date emplacement of the Ambalavao Suite to between ca.580 Ma and 540 Ma and the Maevarano Suite to between ca.537 Ma and522 Ma.Major and trace element concentrations are consistent with emplacement in a syn-to postcollisional tectonic setting as A-type(anorogenic) suites.Oxygen(δ^(18)O of 5.27‰-7.45‰) and hafnium(ε(Hf)(t) of-27.8 to-12.3) isotopic data from plutons in the Itremo and Antananarivo Domains are consistent with incorporation of an ancient crustal source.More primitive δ^(18)O(5.27‰-5.32‰) andε(Hf)(t)(+0.0 to+0.2) isotopic values recorded in samples collected from the Ikalamavony Domain demonstrate the isotopic variation of basement sources present in the Malagasy crust.The Hf isotopic composition of Malagasy zircon are unlike more juvenile Ediacaran-Cambrian zircon sou rces elsewhere in the East African Orogen and,as such,Madagascar represents a distinct and identifiable detrital zircon source region in Phanerozoic sedimentary provenance studies.Taken together,these data indicate that high-T crustal anatexis,crustal assimilation and interaction of crustal material with mantle-derived melts were the processes operating during magma emplacement.This magmatism was coeval with polyphase deformation throughout Madagascar during the amalgamation of Gondwana and magmatism is interpreted to reflect lithospheric delamination of an extensive orogenic plateau.

Petrogenesis of the Late Triassic shoshonitic Shadegai pluton from the northern North China Craton: Implications for crust-mantle interaction and post-collisional extension

Latest Permian to Triassic plutons are widespread in the northern North China Craton(NCC); most of them show calc-alkaline, high-K calc-alkaline, or alkaline geochemical features. The Shadegai pluton in the Wulashan area has shoshonitic affinity and I-type character, and is composed of syenogranites containing abundant mafic microgranular enclaves(MMEs). LA-MC-ICP-MS U-Pb data yield weighted mean 206 Pb/238 U ages of 222 ± 1 Ma and 221 ± 1 Ma for the syenogranites and MMEs, respectively, suggesting their coeval formation during the Late Triassic. The syenogranites have high SiO_2(70.42-72.30 wt%),K_2O(4.58-5.22 wt.%) and Na_2O(4.19-4.43 wt.%) contents but lower concentrations of P_2O_5(0.073-0.096 wt.%) and TiO_2(0.27-0.37 wt.%), and are categorized as I-type granites, rather than A-type granites, as previously thought. These syenogranites exhibit lower(^(87)Sr/^(86)Sr)i ratios(0.70532-0.70547) and strongly negative whole-rock εNd(t) values(-12.54 to-11.86) and zircon εHf(t) values(-17.81 to-10.77),as well as old Nd(1962-2017 Ma) and Hf(2023-2092 Ma) model ages, indicating that they were derived from the lower crust.Field and petrological observations reveal that the MMEs within the pluton probably represent magmatic globules commingled with their host magmas. Geochemically, these MMEs have low SiO_2(53.46-55.91 wt.%)but high FeOt(7.27-8.79 wt.%) contents. They are enriched in light rare earth elements(LREEs) and large ion lithophile elements(LILEs), and are depleted in heavy rare earth elements(HREEs) and high field strength elements(HFSEs). They have whole-rock(^(87)Sr/^(86)Sr)i ratios varying from 0.70551 to 0.70564, εNd(t) values of -10.63 to -9.82, and zircon εHf(t) values of -9.89 to 0.19. Their geochemical and isotopic features indicate that they were derived from the subcontinental lithospheric mantle mainly metasomatized by slab-derived fluids, with minor involvement of melts generated from the ascending asthenospheric mantle. Petrology integrated with elemental and isotopic geochemistry suggest that the Shadegai pluton was produced by crust-mantle interactions, i.e., partial melting of the lower continental crust induced by underplating of mantle-derived mafic magmas(including the subcontinental lithospheric mantle and asthenospheric mantle), and subsequent mixing of the mantle-and crust-derived magmas. In combination with existing geological data, it is inferred that the Shadegai pluton formed in a post-collisional extensional regime related to lithospheric delamination following the collision between the NCC and Mongolia arc terranes.

Geochemistry and Emplacement of Post-collisional Shoshonitic Dyke Swarms, NW of Iran

About 300 mafic dykes are intruded Eocene volcanic and pyroclastic rocks,north east of Meshkinshahr city in the NW of Iran.Most of dyke swarms display NNE-SSE trend.Their composition varies from basalt to tephrite and

Geodynamic Development of Eurasian Active Margin during Closing of Thetys Ocean, Depending on the Scale of Mantle-Crustal Sources Influence at Pre- and Post-collision Settings, Controlled by Geological and Geochemical Indicators

Phanerozoic geodynamic evolution development of Tethys Ocean,its collision and closing,revealed at the Eurasian active margin in pre-and post-collision stages during convergence of Afro-Arabian and Eurasian continents.Subduction of oceanic slab under continental margin revealed in steady state subduction and steepening of subducting slab provoked the incursion of mantle diapir.The steady state subduction is related with island arc setting whereas steepening provoked incursion of mantle diaper interarc-backarc and minor ocean settings.They are controlled by geological indicators—volcagenic,petrochemical,geochemical,tectonic and metallogenic.Each of them is determined by scale of mantle-crustal influence,controlled by intensity and level of mantle diapir incursion in the crust rising from interarc-backarc to minor oceanic setting.The island arc setting is characterized by blocking,which as others by extension of rifting(interarc-backarc)caused spreading out from zone of volcanic activity and mineralization sialic crusts,whereas minor ocean setting caused by spreading out from zone of volcanic activity and mineralization sialic and basaltic crusts.So mantle crustal influence rising from island arc to minor ocean settings controlled type of volcanism and mineralization in pre-collision development.At the closing of ocean occurred the precollision setting which is transferred in post-collision revealed in orogenesis.It is divided in two stages.The first initial stage occurred in penetration hot fluids from the mantle in sialic crust smelted from in granitoid melt and leached the gold and trace melts Sb,W,Mg and Hg from sialic crust.The latter are geochemical indicators of post-collision setting.The second final stage revealed in shoshonite-basalt volcanism activity occurred with penetrated mantle material into deep volcanic chambers and characterized with increasing of mantle influence than initial stage of post-collision activity.

A perspective on potassic and ultrapotassic rocks:Constraints on the Paleoproterozoic late to post-collisional event in the São Francisco paleocontinent

The late-to post-collisional stage in orogenic systems is characterized by the coeval existence of bimodal potassic to ultrapotassic magmatic activity related to partial melting of an enriched lithospheric mantle together with crustal derived melts.In this paper,we present new whole rock geochemical analyses combined with zircon and titanite U–Pb and zircon Hf isotopic data from potassic to ultrapotassic rocks from six plutons that occur within the Archean Itacambira-Monte Azul block(BIMA),to discuss their petrogenesis and the tectonic implications for the São Francisco paleocontinent.The new U–Pb ages range from ca.2.06 Ga to 1.98 Ga and reveal long-lasting potassic magmatism within the BIMA,which is within the late-to-post-collisional stage of the São Francisco paleocontinent evolution.The ultrapotassic rocks are compatible with a fluid-related metasomatized mantle source enriched by previous subduction events,whereas the potassic rocks are bimodal and have a transitional shoshonitic to A-type affinity.These rocks have a hybrid nature,possible related to the mixing between the mafic potassic/ultrapotassic rocks and high temperature crustal melts of the Archean continental crust.Our results also show an increase of within-plate signature towards the younger potassic magmas.The participation of an important Archean crustal component in the genesis of these rocks is highlighted by the common and occasionally abundant occurrence of Archean inherited zircons.The Hf isotopic record shows that most of the zircon inheritance has dominantly subchondriticεHf(t)values,which fits a crustal reworking derivation from a similar Eo-to Paleoarchean precursor crust.However,the presence of juvenile 2.36 Ga zircon inheritance in an ultrapotassic sample reveal the existence of a hidden reservoir that is somewhat similar to the described for the Mineiro Belt in southern São Francisco paleocontinent.

Geochemistry and Sr,Nd Istopes of Granitoids from the Lac Ifni Area(Sirwa Massif-Anti-Atlas Morocco):A Geodynamic Setting for the Post-collisional Ediacaran Magmatic Chain of the Anti-Atlas

The plutonic rocks of the westernmost part of the Sirwa massif belong to the Ediacaran post-collisional magmatic chain of the Anti-Atlas.The geochemistry of major and trace elements attests that the fractional crystallization cannot account for the variations between the granitoids and the associated MME.They represent two contemporaneous but independent magmatic tendencies.However,Sr and Nd configur data argue for a similar and juvenile material

Geodynamic Development of Eurasian Active Margin at Pre-collision Subduction and at Post-collision Closing of Tethys Ocean

Geodynamic development of Eurasian Active Margin is related to Phanerozoic collision and closure of Tethys Ocean coincided with northvergent movement and stressing of Afro-Arabian continent at the Eurasian margin.The collision coincided with subduction oceanic Slab under margin of continent at pre-collision stage revealed in formation of island arc,inter-arc backarc and minor ocean settings at pre-collision stage.After closure of ocean the subduction is terminated and pre-collision stage transferred in post-collision and orogenesis,caused by stressing Afro-Arabian continent at the Eurasian.Character of subduction determined the settings of pre-collision stage.The island arc setting is related with steady state subduction,interarc-backarc and minor ocean settings are controlled by steepening of subducting slab which caused invasion of mantle diapir extension and spreading the crust revealed in rifting in interarc-backarc and intensive spreading in minor ocean setting,whereas at island arc setting the mantle invasion and spreading did not occur.So,scale of mantle material participation in various settings determined character of volcanism and tectonics.The island arcs are characterized by calc-alkaline rhyo-dacite-andesite-basalt volcanism blocking tectonics,revealed in island uplifting and gold-base metal mineralization.The interarc-backarc settings revealed in tholeiite-olivine basaltic volcanism,rifting and Zn-Cu mineralization the minor ocean setting controlled by ophiolite volcanism ultimatic dunite-peridotite-magmatism and the most intensive spreading of lithosphere and copper-pyrite mineralization confirmed by volcano-petrogenic,metallogenic and tectonic indications and geochemical cryteria.Therefore,type of volcanism,magmatism and mineralization at precollision development are controlled by scale and influence of crustal-mantle participation.The post-collision stage of geodynamic development also is characterized by various scales of crustal mantle influence.Our studied region consists of pre-and post-collision stages,located in Iran,Caucasus,Turkey and Balcan-Carpathian is parth of the Eurasian active margin.At post-collision,as at pre-collision stages the volcanic-magmatic activity,tectonics and mineralization are depended on the crustial-mantle scale of influence and are controlled by volcano-petrogenic,metallogenic,as well as,tectonical and geochemical indicators.

Post-collisional lithosphere delamination of the Dabie-Sulu orogen

The consistence between the first rapid cooling time (226-219 Ma) of the untrahigh pressure metamorphic (UHPM) rocks in the Dabie Mountains and the formation time (205-220 Ma) of the syncollisional granites in the Qinling and Sulu areas suggests that the first rapid cooling and uplift of the UHPM rocks may be related to breakoff of subducted plate. Therefore the second rapid cooling and uplift (180-170 Ma) of the UHPM racks needs a post-colli-sional lithosphere delamination which resulted in the granitic magmatism with an age of about 170 Ma. In addition, the rapid rising of the Dabie dome in the early Cretaceous (130-110 Ma) and the corresponding large-scale magmatism in the Dabie Mountains need another litho-sphere delamination. The geochronology of the post-collis-ional mafic-ultramafic intrusions and geological relationship between the mafic-ultramafic intrusions and granites suggest that partial melting was initiated in the mantle, and then progressively developed in the crust, suggesting a mantle

Post-collisional magmatism in Wuyu basin,central Tibet:evidence for recycling of subducted Tethyan oceanic crust

The trachyte and basaltic trachyte and intruded granite-porphyry of Gazacun formation of Wuyu Group in central Tibet are Neogene shoshonitic rocks. They are rich in LREE, with a weak to significant Eu negative anomalies. The enriched Rb, Th, U, K, negative HFS elements Nb, Ta, Ti and P, and Sr, Nd and Pb isotope geochemistry suggest that the volcanic rocks of Wuyu Group originated from the partial melting of lower crust of the Gangdese belt, with the involvement of the Tethyan oceanic crust. It implies that the north-subducted Tethys ocean crust have arrived to the lower crust of Gangdese belt and recycled in the Neogene magmatism.

Carbonatites and Alkaline Igneous Rocks in Post-Collisional Settings:Storehouses of Rare Earth Elements

The rare earth elements(REE)are critical raw materials for much of modern technology,particularly renewable energy infrastructure and electric vehicles that are vital for the energy transition.Many of the world's largest REE deposits occur in alkaline rocks and carbonatites,which are found in intracontinental,rift-related settings,and also in syn-to post-collisional settings.Post-collisional settings host significant REE deposits,such as those of the Mianning-Dechang belt in China.This paper reviews REE mineralization in syn-to post-collisional alkaline-carbonatite complexes worldwide,in order to demonstrate some of the key physical and chemical features of these deposits.We use three examples,in Scotland,Namibia,and Turkey,to illustrate the structure of these systems.We review published geochemical data and use these to build up a broad model for the REE mineral system in post-collisional alkaline-carbonatite complexes.It is evident that immiscibility of carbonate-rich magmas and fluids plays an important part in generating mineralization in these settings,with REE,Ba and F partitioning into the carbonate-rich phase.The most significant REE mineralization in post-collisional alkaline-carbonatite complexes occurs in shallow-level,carbothermal or carbonatite intrusions,but deeper carbonatite bodies and associated alteration zones may also have REE enrichment.

Post-collisional mafic magmatism:Record of lithospheric mantle evolution in continental orogenic belt

In order to better understand the role of post-collisional mafic magmatism at convergent plate boundaries in revealing the earth’s evolution,this paper has systematically summarized the research history of post-collisional mafic magmatism,different types of collision and their influence on the nature of orogenic mantle,the concept and implication of post-collisional magmatism,and the relationship between post-collisional mafic magmatism and orogenic mantle evolution and mineralization.Post-collisional mafic igneous rocks are not only the direct records for studying the nature and evolution of orogenic mantle,but also the important carriers for regional mineralization.However,the type and quantity of the crustal materials involved in modifying the overlying lithospheric mantle during collisional orogeny,the process and mechanism of such modification,and the major control factors and mechanism of mafic magmatism-related mineralization during the post-collisional period are the main contents and direction of future researches in this field.Therefore,the study of post-collisional mafic magmatism is of significant implications for developing the theory of plate tectonics.

Early Paleoproterozoic Post-Collisional Basaltic Magmatism in Quanji Massif:Implications for Precambrian Plate Tectonic Regime in NW China

Basaltic magmas can provide important information about mantle source nature,tectonic settings and tectonic evolution for a given terrain.This paper reports geology,petrography and geochemistry of whole-rock major and trace elements and Nd-Sr isotopes for a suite of garnet amphibolites from southeastern Wulan(Ulan),Quanji Massif,northwestern China.The garnet amphibolites were likely generated from basaltic lavas,associated with both paragneisses and orthogneisses of the lower Delingha Group.The basaltic protolith of these amphibolites can be broadly constrained to be formed at~2.33 Ga in an extensional setting post-collision.The geochemistry of amphibolites shows subalkaline and highly evolved characteristics.They display high-Fe low-Ti characteristics,with TFeO of 13.1 wt.%-17.9 wt.%and TiO_(2) of 1.42 wt.%-3.09 wt.%(in most samples TiO_(2)≤2.5 wt.%).The chondrite-normalized REE patterns show enrichment of LREE and LILE and the primitive-mantle-normalized incompatible element patterns display negative P,Ti,Nb-Ta and Zr-Hf anomalies.The(^(87)Sr/^(86)Sr)t values of 0.6978-0.7123 andε_(Nd)(t)values of-2.81-5.08 respond to depleted mantle model ages(T_(DM))of 2.33-3.30 Ga.These suggest that the precursor magmas of the protolith of the garnet amphibolites were probably derived from the Early Paleoproterozoic depleted sub-continental lithospheric mantle that had been metasomatized by subduction-induced fluids and melts.The precursor basaltic magmas were contaminated by the older crustal components during magma ascending.This post-collisional basaltic magmatic event at~2.33 Ga in Quanji Massif thus enhanced the subduction shutdown or slowdown tectonic regime both in NW China and coevally with those plate tectonics in some important domains worldwide during the Early Paleoproterozoic.

Genesis of the Gentio Metagranitoid: Post-Collisional High-K Plutonism within the Mineiro Belt, S?o Francisco Craton, Brazil

The Gentio metagranitoid presents equigranular and porphyritic facies, modal composition ranging from tonalite to monzogranite with calculated T_(Zr)<800 ℃ for most samples. Its mineralogy is dominated by quartz and feldspar(77% to 95%), biotite is the only mafic mineral present(2% to 18%) and, titanite, zircon, apatite, allanite are important accessory phases. These rocks range from metaluminous to weakly peraluminous, and have large variation in major and trace elements, and high alkali contents(>6 wt.%). Zircon analyses by LA-ICP-MS and SHRIMP yielded a concordia age of 2 119±10 Ma for the porphyritic facies and an upper intercept age of 2 111±15 Ma for the equigranular facies. The whole-rock Sm-Nd T_(DM) ages vary from 2.4 to 2.8 Ga with ε_(Nd)(2.1) values between -0.7 and-5.3, indicating crustal derivation from distinct and/or heterogeneous protoliths. Field observations indicate that the Gentio metagranitoid was formed through different pulses of magma. Individual batches were subject to little or even no fractionation process after its emplacement. Although the Gentio metagranitoid crosscuts metamafic and metaultramafic rocks akin to an oceanic arc setting, this pluton is likely originated by partial melting of a more evolved quartz-feldspathic crustal igneous rock in a post-collisional environment, after the accretion of the arcs from the Mineiro belt and rocks of the Mantiqueira Complex.

Tracking the Tectonic Evolution of the Junggar-Balkhash Ocean: A Case Study from the Post-Collisional Takergan Pluton in the West Junggar, Xinjiang

The Late Carboniferous and Early Permian igneous rocks are widely developed in the West Junggar, Xinjiang, which are considered to be related to the evolution of the Junggar-Balkhash Ocean. However, their tectonic settings have been controversial for a long time. With the aim of providing new evidence for the Late Paleozoic tectonic evolution of the West Junggar, we present petrology, zircon U-Pb chronology, whole-rock major and trace elemental and Sr-Nd isotopic data, to discuss the petrogenesis and tectonic setting of Takergan pluton from the Barleik Mountains in the West Junggar. The Takergan pluton is mainly composed of quartz diorite porphyry and quartz monzonite. The quartz diorite porphyry has low Si O2(57.76 wt.%–57.81 wt.%), high total alkali contents(Na2 O+K2 O=6.29 wt.%–6.56 wt.%), and high Mg# values(45–46), with a zircon U-Pb age of 304±5 Ma. The quartz monzonite shows relatively high SiO2(58.71 wt.%–64.71 wt.%), total alkali contents(7.73 wt.%–9.70 wt.%), and Mg^(#) values(34–47), with the A/CNK values of 0.91–0.98, which belongs to shoshonitic and metaluminous I-type granite series. The quartz monzonite yields zircon U-Pb ages of 302±2 and 296±3 Ma, and is characterized by low initial Sr ratios of 0.703 97–0.704 09, high εNd(t) values of +6.8– +7.0, and young Nd model ages of 551–587 Ma. Both the quartz diorite porphyry and quartz monzonite are enriched in light rare earth elements and Rb, Th, U, K, and depleted in Nb, Ta, Ti, with different degrees of negative Eu anomalies. These features indicate that the Takergan pluton was most likely formed in a post-collisional setting by partial melting of a depleted mantle source that had been metasomatized by subduction-related fluids, with significant fractional crystallization and slightly contaminated by crustal materials. Combined with the widespread distribution of the coeval stitching plutons, the occurrences of terrestrial Late Carboniferous to Permian volcano-sedimentary formations, and the absence of subduction-related rocks later than Early Carboniferous, it is believed that the Junggar-Balkhash Ocean was closed at about 320 Ma, and the central West Junggar has transformed to a post-collisional environment during the Late Carboniferous and Early Permian.