The manufacturing process of CaCO3 modified Polypropylene (PP) spun-bonded nonwovens was studied. Then the effect of the additive amount of CaCO3 on mechanical properties of the product was analyzed, and a compatible ...The manufacturing process of CaCO3 modified Polypropylene (PP) spun-bonded nonwovens was studied. Then the effect of the additive amount of CaCO3 on mechanical properties of the product was analyzed, and a compatible mechanism between CaCO3 particles and the main component of PP was established. In the end, the mechanical performance of the products was studied when the natural light degradation was changed. The experiment results show that after adding CaCO3 to the PP spun-bonded nonwovens and through the application of complex coupling agent and organic modification, hardcore of rigid particles and polymer composite elastomers can be combined together tightly and disperse rapidly and evenly in the main part of PP. In addition, CaCO3 can catalyze the light degradation of PP spun-bonded nonwovens. The larger the content of CaCO3 is, the faster the light degradation will be.展开更多
The monomer methacrylamido propyl trimethy ammonium chloride( MAPTAC) was copolymerized onto the fiber surface of polypropylene( PP) nonwoven fabric under ultroviole radiation. The weak acid red GN dye adsorption and ...The monomer methacrylamido propyl trimethy ammonium chloride( MAPTAC) was copolymerized onto the fiber surface of polypropylene( PP) nonwoven fabric under ultroviole radiation. The weak acid red GN dye adsorption and adsorptive filtration performance of the resulted PP fabrics were investigated.The results showed that the grafting copolymerization preferred to happen in the inner layer of the fabrics. The water flux of the grafted fabrics decreases with the increase of grafting yield. The collapse of the grafted polymer chains causes the flux increase in acidic condition,or vice versa at alkaline version. The coiling of the polyelectrolyte chains upon the dye adsorption seems to violate the routine assumption of the rigid substrate, and this gets the adsorption energy constant negative. The static adsorption process follows the Lagergren's pseudo-second order kinetic equation. The removals of circa( ca.) 100% of the total permeation volume3 500 mL simulated dye wastewater was reached during permeation.The dye adsorbed fabrics were regenerated by the mixed media of the cationic surfactant / ethanol /water. The grafted fabric assumes stable fabric integrity and stability during permeation,and presents excellent dye adsorption capacity,easy desorption, and repeatable utilization.展开更多
文摘The manufacturing process of CaCO3 modified Polypropylene (PP) spun-bonded nonwovens was studied. Then the effect of the additive amount of CaCO3 on mechanical properties of the product was analyzed, and a compatible mechanism between CaCO3 particles and the main component of PP was established. In the end, the mechanical performance of the products was studied when the natural light degradation was changed. The experiment results show that after adding CaCO3 to the PP spun-bonded nonwovens and through the application of complex coupling agent and organic modification, hardcore of rigid particles and polymer composite elastomers can be combined together tightly and disperse rapidly and evenly in the main part of PP. In addition, CaCO3 can catalyze the light degradation of PP spun-bonded nonwovens. The larger the content of CaCO3 is, the faster the light degradation will be.
基金the Priority Academic Development Program for Textile Science and Textile Engineering of Jiangsu Higher Education Institutions,Chinathe Environmental Protection Department of Jiangsu Province,China(No.2012009)Suzhou Municipal Government,China(No.SYG201202)
文摘The monomer methacrylamido propyl trimethy ammonium chloride( MAPTAC) was copolymerized onto the fiber surface of polypropylene( PP) nonwoven fabric under ultroviole radiation. The weak acid red GN dye adsorption and adsorptive filtration performance of the resulted PP fabrics were investigated.The results showed that the grafting copolymerization preferred to happen in the inner layer of the fabrics. The water flux of the grafted fabrics decreases with the increase of grafting yield. The collapse of the grafted polymer chains causes the flux increase in acidic condition,or vice versa at alkaline version. The coiling of the polyelectrolyte chains upon the dye adsorption seems to violate the routine assumption of the rigid substrate, and this gets the adsorption energy constant negative. The static adsorption process follows the Lagergren's pseudo-second order kinetic equation. The removals of circa( ca.) 100% of the total permeation volume3 500 mL simulated dye wastewater was reached during permeation.The dye adsorbed fabrics were regenerated by the mixed media of the cationic surfactant / ethanol /water. The grafted fabric assumes stable fabric integrity and stability during permeation,and presents excellent dye adsorption capacity,easy desorption, and repeatable utilization.