Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechan...Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechanical systems.The multi-field coupling and free vibration of a sandwiched FGPS plate are studied,and the governing equation and natural frequency are derived with the consideration of electron movement.The material properties in the functionally-graded layers are assumed to vary smoothly,and the first-order shear deformation theory is introduced to derive the multi-field coupling in the plate.The total strain energy of the plate is obtained,and the governing equations are presented by using Hamilton’s principle.By introducing the boundary conditions,the coupling physical fields are solved.In numerical examples,the natural frequencies of sandwiched FGPS plates under different geometrical and physical parameters are discussed.It is found that the initial electron density can be used to modulate the natural frequencies and vibrational displacement of sandwiched FGPS plates in the case of nano-size.The effects of the material properties of FGPS layers on the natural frequencies are also examined in detail.展开更多
The effect of substrate on the phase morphologies of PMMA/PS blend films was investigated by means of phase contrast microscope. PMMA/PS blend films were cast onto various substrates(such as glass substrate and PP sub...The effect of substrate on the phase morphologies of PMMA/PS blend films was investigated by means of phase contrast microscope. PMMA/PS blend films were cast onto various substrates(such as glass substrate and PP substrate) by spin-coating with thickness of about 10 μm. It was observed that there was a large difference of the phase inversion region between the blend films cast on glass and on PP substrates. On glass substrate, the phase inversion occurred at about \%Φ\%_m=0 4(PS mass fraction) while at \%Φ\%_m=0 5 on PP substrate. This implies that there is a shift of the phase inversion region with the change of substrate in cast polymer blend films. In other words, phase inversion region depends on the substrate. ATR-FTIR analysis was used to detect the composition of the surface and the bottom of the films(about 100 μm thick) obtained by evaporating solvent from the polymer blend solution. The ATR-FTIR spectra of the surface and the bottom of the PMMA/PS blend thin films cast on glass substrate and PP substrate showed that PMMA component preferentially segregated to glass substrate and PS component was enriched on the PP substrate. This selective segregation was due to the difference of the wetting abilities of PS and PMMA on the two kinds of substrates. The polymer-substrate interfacial tension γ were calculated and the results supported the ATR-FTIR results. It could be inferred that the shift of the phase inversion region with the change of the substrate in PMMA/PS blend film was due to the fact that the composition of the blend in the bulk changed, owing to the selective enrichment of one component of polymer blend to the substrate. In other words, the affinity between polymer and substrate can strongly influence the phase morphologies and the phase inversion region in polymer blend films.展开更多
采用极化曲线测定、扫描电镜和金相显微镜技术,对比国外优质1050 PS版板基,研究了热处理工艺对板基电蚀性能的影响。结果表明,具有大量细及均匀分布的第二相颗粒和均匀晶粒组织的板基电解腐蚀性能好。经过600℃×3 m in的高温快速...采用极化曲线测定、扫描电镜和金相显微镜技术,对比国外优质1050 PS版板基,研究了热处理工艺对板基电蚀性能的影响。结果表明,具有大量细及均匀分布的第二相颗粒和均匀晶粒组织的板基电解腐蚀性能好。经过600℃×3 m in的高温快速退火处理后的板基微观组织得到细化,均匀性提高,细小弥散的第二相颗粒大量析出,板基电解活化性能增强,腐蚀均匀、稳定,电解腐蚀性能显著提高。展开更多
基金supported by the National Natural Science Foundation of China(Nos.12172236 and 12202289)。
文摘Sandwiched functionally-graded piezoelectric semiconductor(FGPS)plates possess high strength and excellent piezoelectric and semiconductor properties,and have significant potential applications in micro-electro-mechanical systems.The multi-field coupling and free vibration of a sandwiched FGPS plate are studied,and the governing equation and natural frequency are derived with the consideration of electron movement.The material properties in the functionally-graded layers are assumed to vary smoothly,and the first-order shear deformation theory is introduced to derive the multi-field coupling in the plate.The total strain energy of the plate is obtained,and the governing equations are presented by using Hamilton’s principle.By introducing the boundary conditions,the coupling physical fields are solved.In numerical examples,the natural frequencies of sandwiched FGPS plates under different geometrical and physical parameters are discussed.It is found that the initial electron density can be used to modulate the natural frequencies and vibrational displacement of sandwiched FGPS plates in the case of nano-size.The effects of the material properties of FGPS layers on the natural frequencies are also examined in detail.
文摘The effect of substrate on the phase morphologies of PMMA/PS blend films was investigated by means of phase contrast microscope. PMMA/PS blend films were cast onto various substrates(such as glass substrate and PP substrate) by spin-coating with thickness of about 10 μm. It was observed that there was a large difference of the phase inversion region between the blend films cast on glass and on PP substrates. On glass substrate, the phase inversion occurred at about \%Φ\%_m=0 4(PS mass fraction) while at \%Φ\%_m=0 5 on PP substrate. This implies that there is a shift of the phase inversion region with the change of substrate in cast polymer blend films. In other words, phase inversion region depends on the substrate. ATR-FTIR analysis was used to detect the composition of the surface and the bottom of the films(about 100 μm thick) obtained by evaporating solvent from the polymer blend solution. The ATR-FTIR spectra of the surface and the bottom of the PMMA/PS blend thin films cast on glass substrate and PP substrate showed that PMMA component preferentially segregated to glass substrate and PS component was enriched on the PP substrate. This selective segregation was due to the difference of the wetting abilities of PS and PMMA on the two kinds of substrates. The polymer-substrate interfacial tension γ were calculated and the results supported the ATR-FTIR results. It could be inferred that the shift of the phase inversion region with the change of the substrate in PMMA/PS blend film was due to the fact that the composition of the blend in the bulk changed, owing to the selective enrichment of one component of polymer blend to the substrate. In other words, the affinity between polymer and substrate can strongly influence the phase morphologies and the phase inversion region in polymer blend films.
文摘采用极化曲线测定、扫描电镜和金相显微镜技术,对比国外优质1050 PS版板基,研究了热处理工艺对板基电蚀性能的影响。结果表明,具有大量细及均匀分布的第二相颗粒和均匀晶粒组织的板基电解腐蚀性能好。经过600℃×3 m in的高温快速退火处理后的板基微观组织得到细化,均匀性提高,细小弥散的第二相颗粒大量析出,板基电解活化性能增强,腐蚀均匀、稳定,电解腐蚀性能显著提高。
