PS-TBD triggered general protocol for the synthesis of 4H-chromene,pyrano[4,3-b]pyran and pyrano[3,2-c]chromene derivatives of 1H-pyrazole and their biological activities

A general protocol has been developed for the facile construction of titled derivatives via three component reaction between 3-substituted phenyl-1H-pyrazole-4-carbaldehyde, malononitrile and various Michael donors in presence of 5 mol% polystyrene supported 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene（PS-TBD）. PS-TBD was reused for at least five runs with nearly constant catalytic activity. All compounds were screened for antimicrobial and antioxidant activities.

基于PS-VF-TBD的地波雷达船只目标航迹起始方法

针对地波雷达低信噪比目标信号“闪烁”导致的航迹起始困难问题,本文提出了一种基于PS-VF-TBD的航迹起始方法。该方法综合利用了地波雷达回波谱中目标信号的展宽特征和运动特性,利用PS-VF-TBD方法对运动目标能量有效积累的特点,提高对疑似目标多帧信号间的关联概率,进而提高对真实目标的搜索概率和航迹起始成功率。通过地波雷达实测数据的航迹起始结果及长时间跟踪结果与同步AIS信息的对比分析,表明本文提出的方法相对于基于DP-TBD的航迹起始方法可以给出更好的航迹起始结果,提高了远端低信噪比下“闪烁”目标的航迹起始概率,可提高目标跟踪性能,并具有区分距离-多普勒谱中邻近目标的能力。