Dissolved organic matter(DOM) plays important roles in soil biogeochemistry activity and nutrients transportation in soils, but studies regarding the long-term effects of green manures on the content and structure of ...Dissolved organic matter(DOM) plays important roles in soil biogeochemistry activity and nutrients transportation in soils, but studies regarding the long-term effects of green manures on the content and structure of DOM in red paddy soil have not been reported yet. A long-term green manure experiment established in 1982 was utilized to test the DOM contents in different treatments, and the spectral characteristics of DOM were investigated by using ultraviolet-visible(UV-Vis) spectrometry and Fourier transform infrared(FTIR) spectrometry. The experiment included four cropping systems: ricerice-milk vetch(RRV), rice-rice-rape(RRP), rice-rice-ryegrass(RRG) and rice-rice-winter fallow(RRF), among them, milk vetch, rape, and ryegrass are popular winter green manure species in southern China. The results showed that the content of dissolved organic carbon(DOC), which is widely used to estimate the concentration of DOM, was significantly promoted after the incorporation of green manures compared with the other sampling stages. The contents of aromatic groups and the degree of humification of DOM increased in RRV and RRP, suggesting more complex compositions of the soil DOM after long-term application of milk vetch and rape. The contents of phenol, alcohol and carboxylic acid group at the mature stage of early rice were significantly higher than those at the stage of after green manures turned over, especially for the RRV treatment. The absorption ratio of FTIR indicated that winter plantation of rape increased the aromatic-C/aliphatic-C ratio, and ryegrass increased the aromatic-C/carboxyl-C ratio. In conclusion, long-term planting of milk vetch and rape as green manures increased the degree of aromaticity, humification and average molecular weight of DOM, and made the DOM more stable in red paddy soil.展开更多
Effects of free iron oxyhydrates (Fed) and soil organic matter (SOM) on copper (Cu^2+) sorption-desorption behavior by size fractions of aggregates from two typical paddy soils (Ferric-Accumulic Stagnic Anthro...Effects of free iron oxyhydrates (Fed) and soil organic matter (SOM) on copper (Cu^2+) sorption-desorption behavior by size fractions of aggregates from two typical paddy soils (Ferric-Accumulic Stagnic Anthrosol (Soil H) and Gleyic Stagnic Anthrosol (Soil W)) were investigated with and without treatments of dithionite-citrate-bicarbonate and of H2O2. The size fractions of aggregates were obtained from the undisturbed bulk topsoil using a low energy ultrasonic dispersion procedure. Experiments of equilibrium sorption and subsequent desorption were conducted at soil water ratio of 1:20, 25℃. For Soil H, Cu^2+ sorption capacity of the DCB-treated size fractions was decreased by 5.9% for fine sand fraction, by 40.4% for coarse sand fraction, in comparison to 2.9% for the bnlk sample. However, Cu^2+ sorption capacities of the H2O2-treated fractions were decreased by over 80% for the coarse sand fraction and by 15% for the clay-sized fraction in comparison to 88% for bulk soil. For Soil W, Cu^2+ sorption capacity of the DCB-treated size fraction was decreased by 30% for the coarse sand fraction and by over 75% for silt sand fraction in comparison to 44.5% for the bulk sample. Cu^2+ sorption capacities of the H2O2-treated fractions were decreased by only 2.0% for the coarse sand fraction and by 15% for the fine sand fraction in comparison to by 3.4% for bulk soil. However, Cu^2+ desorption rates were increased much in H2O2-treated samples by over 80% except the clay-sized fraction (only 9.5%) for Soil H. While removal of SOM with H2O2 tendend to increase the desorption rate, DCB- and H2O2-treatments caused decrease in Cu^2+ retention capacity of size fractions, Particularly, there hardly remained Cu^2+ retention capacity by size fractions from Soil H after H2O2 treatment except for clay-sized fraction. These findings supported again the dominance of the coarse sand fraction in sorption of metals and the preference of absorbed metals bound to SOM in differently stabilized status among the size fractions. Thus, enrichment and turnover of SOM in paddy soils may have great effects on metal retention and chemical mobility in paddy soils.展开更多
To reveal variation of organic matter content in red paddy soil, Through a 27 years-located fertilization experiment in red paddy soil, the content and composi- tion of organic matter in paddy soil were studied in thi...To reveal variation of organic matter content in red paddy soil, Through a 27 years-located fertilization experiment in red paddy soil, the content and composi- tion of organic matter in paddy soil were studied in this paper. The result showed that: the dynamics of soil organic matter of the different fertilization treatments showed significant differences, in the premise of equal nutrient (nitrogen and phos- phorus and potassium), combining application of organic-inorganic was benefited for the accumulation of organic matter in paddy soil than without fertilizer treatment or chemical fertilizer treatment; the dynamics of soil humic acid, HA and FA of chemi- cal fertilizer only and Combining application of organic-inorganic treatments had basi- cally the same trend, But the contents of humic acid, HA and FA of combining ap- plication of organic-inorganic treatments had been higher than that without fertilizer and chemical fertilizer treatment. Moreover combining application of organic-inorganic treatments was benefited for improving the contents of HA and FA, but decreasing HA/FA ratio as an extension of time. Combining application of organic-inorganic was benefited for improving the contents ol readily oxidizable organic matter. And the contents of soil organic matter in long-term experiment and the contents of readily oxidizable O.M were highly significant positive correlation and the contents of soil total nitrogen, avail nitrogen and potassium were significant positive correlation; the contents of soil readily oxidizable O.M and the contents of soil total nitrogen, avail- able P and rice yield were significant positive correlation. Thereinto, the correlation (r=0.818 1 ) between the rice yield and soil readily oxidizable O.M was higher than the correlation (r=0.802 0) between the rice yield and soil organic matter. It showed the soil readily oxidized organic matter had greater contribution to the rice yield.展开更多
Rational fertilization is an important measure to increase crop yield and soil fertility. Through analysis,this paper aims to master the change characteristics of soil organic matter and rice yield under different fer...Rational fertilization is an important measure to increase crop yield and soil fertility. Through analysis,this paper aims to master the change characteristics of soil organic matter and rice yield under different fertilizer treatments,in order to provide an important reference for the sustainable use of soil and effective fertilization. Long-term( 19 years) rice crop rotation experiments in waterloggogenic paddy soil were conducted to investigate the change trend of crop grain yield and soil organic matter with time,reveal the dynamic characteristics and relationship between main fertility factors and crop yields using comparative analysis at three sites with conventional fertilization and non-fertilization in Guilin. The results showed that compared with previous years,the rice yield increased by 53% under the fertilization treatment and degreased by 66% under the control. Over the years,the average soil organic matter( SOM) content under fertilization treatment was 23% higher than under CK treatment. This indicates that chemical fertilizer and organic manure application can increase the rice yield and soil organic matter,and high rice yield can be attributed to the SOM increase.展开更多
Cadmium(Cd) contamination in paddy soil has caused public concern. The uptake of Cd by rice plants depends on soil Cd mobility, which is in turn substantially influenced by organic matter(OM). In this review, we first...Cadmium(Cd) contamination in paddy soil has caused public concern. The uptake of Cd by rice plants depends on soil Cd mobility, which is in turn substantially influenced by organic matter(OM). In this review, we first summarize the fate of Cd in soil and the role of OM. We then focus on the effects of OM on Cd mobility in paddy soil and the factors influencing the remedial effectiveness of OM amendments. We further discuss the performance of straw incorporation in the remediation of Cd-contaminated paddy soils reported in laboratory and field studies. Considering the huge production of organic materials(such as straw) in agriculture, the use of natural OM for soil remediation has obvious appeal due to the environmental benefits and low cost. Although there have been successful application cases, the properties of OM amendments and soil can significantly affect the remedial performance of the OM amendments. Importantly, straw incorporation alone does not often decrease the mobility of Cd in soil or the Cd content in rice grains. Careful evaluation is required when considering natural OM amendments, and the factors and mechanisms that influence their remedial effectiveness need further investigation in paddy soil with realistic Cd concentrations.展开更多
In the rice-wheat rotation system,biochar(BC)can be applied at the initiation of the rice or wheat season.Here,we compared the effects of BC that were applied at two different crop seasons on wheat production,quality,...In the rice-wheat rotation system,biochar(BC)can be applied at the initiation of the rice or wheat season.Here,we compared the effects of BC that were applied at two different crop seasons on wheat production,quality,and soil profile properties in a rice-wheat rotation system with nitrogen(N)fertilizer applied at 280 kg/ha rate.Results showed that both wheat grain production and N recovery use efficiency were influenced by BC applied at two crop seasons.Biochar application did not affect the total non-essential amino-acid,but when applied during wheat season,BC significantly(p<0.05)increased total essential amino acid in grain by 12.3%,particularly for the valine(+48.2%),methionine(+43.8%),and isoleucine(+10.3%).We found that BC significantly(p<0.05)decreased the pH of soil at 0–6 cm and 20–30 cm by 0.14–0.18 and 0.05–0.08 units,respectively.The NH4+-N content of the whole observed soil profile were reduced by BC application,however,the effect of BC on NO3–-N content varied with the application season and profile depth.Interestingly,BC applied at wheat and rice season significantly(p<0.05)improved topsoil N contents by 48.4%and 19.7%,respectively.In addition,data suggested that BC applied during wheat season performed better in enhancing soil available phosphorus,potassium,and organic matter contents.In conclusion,we suggest that the optimum application time of BC for enhancing crop production and quality(take amino-acid content for example)and improving soil fertility is at the initiation of the wheat season.展开更多
基金supported by the earmarked fund for China Agriculture Research System (2013–2017)the Chinese Outstanding Talents Program in Agricultural Sciences
文摘Dissolved organic matter(DOM) plays important roles in soil biogeochemistry activity and nutrients transportation in soils, but studies regarding the long-term effects of green manures on the content and structure of DOM in red paddy soil have not been reported yet. A long-term green manure experiment established in 1982 was utilized to test the DOM contents in different treatments, and the spectral characteristics of DOM were investigated by using ultraviolet-visible(UV-Vis) spectrometry and Fourier transform infrared(FTIR) spectrometry. The experiment included four cropping systems: ricerice-milk vetch(RRV), rice-rice-rape(RRP), rice-rice-ryegrass(RRG) and rice-rice-winter fallow(RRF), among them, milk vetch, rape, and ryegrass are popular winter green manure species in southern China. The results showed that the content of dissolved organic carbon(DOC), which is widely used to estimate the concentration of DOM, was significantly promoted after the incorporation of green manures compared with the other sampling stages. The contents of aromatic groups and the degree of humification of DOM increased in RRV and RRP, suggesting more complex compositions of the soil DOM after long-term application of milk vetch and rape. The contents of phenol, alcohol and carboxylic acid group at the mature stage of early rice were significantly higher than those at the stage of after green manures turned over, especially for the RRV treatment. The absorption ratio of FTIR indicated that winter plantation of rape increased the aromatic-C/aliphatic-C ratio, and ryegrass increased the aromatic-C/carboxyl-C ratio. In conclusion, long-term planting of milk vetch and rape as green manures increased the degree of aromaticity, humification and average molecular weight of DOM, and made the DOM more stable in red paddy soil.
基金supported by the National Natural Science Foundation of China (No. 40231016).
文摘Effects of free iron oxyhydrates (Fed) and soil organic matter (SOM) on copper (Cu^2+) sorption-desorption behavior by size fractions of aggregates from two typical paddy soils (Ferric-Accumulic Stagnic Anthrosol (Soil H) and Gleyic Stagnic Anthrosol (Soil W)) were investigated with and without treatments of dithionite-citrate-bicarbonate and of H2O2. The size fractions of aggregates were obtained from the undisturbed bulk topsoil using a low energy ultrasonic dispersion procedure. Experiments of equilibrium sorption and subsequent desorption were conducted at soil water ratio of 1:20, 25℃. For Soil H, Cu^2+ sorption capacity of the DCB-treated size fractions was decreased by 5.9% for fine sand fraction, by 40.4% for coarse sand fraction, in comparison to 2.9% for the bnlk sample. However, Cu^2+ sorption capacities of the H2O2-treated fractions were decreased by over 80% for the coarse sand fraction and by 15% for the clay-sized fraction in comparison to 88% for bulk soil. For Soil W, Cu^2+ sorption capacity of the DCB-treated size fraction was decreased by 30% for the coarse sand fraction and by over 75% for silt sand fraction in comparison to 44.5% for the bulk sample. Cu^2+ sorption capacities of the H2O2-treated fractions were decreased by only 2.0% for the coarse sand fraction and by 15% for the fine sand fraction in comparison to by 3.4% for bulk soil. However, Cu^2+ desorption rates were increased much in H2O2-treated samples by over 80% except the clay-sized fraction (only 9.5%) for Soil H. While removal of SOM with H2O2 tendend to increase the desorption rate, DCB- and H2O2-treatments caused decrease in Cu^2+ retention capacity of size fractions, Particularly, there hardly remained Cu^2+ retention capacity by size fractions from Soil H after H2O2 treatment except for clay-sized fraction. These findings supported again the dominance of the coarse sand fraction in sorption of metals and the preference of absorbed metals bound to SOM in differently stabilized status among the size fractions. Thus, enrichment and turnover of SOM in paddy soils may have great effects on metal retention and chemical mobility in paddy soils.
基金Supported by National Key Technology R&D Program(2006BAD02A04)~~
文摘To reveal variation of organic matter content in red paddy soil, Through a 27 years-located fertilization experiment in red paddy soil, the content and composi- tion of organic matter in paddy soil were studied in this paper. The result showed that: the dynamics of soil organic matter of the different fertilization treatments showed significant differences, in the premise of equal nutrient (nitrogen and phos- phorus and potassium), combining application of organic-inorganic was benefited for the accumulation of organic matter in paddy soil than without fertilizer treatment or chemical fertilizer treatment; the dynamics of soil humic acid, HA and FA of chemi- cal fertilizer only and Combining application of organic-inorganic treatments had basi- cally the same trend, But the contents of humic acid, HA and FA of combining ap- plication of organic-inorganic treatments had been higher than that without fertilizer and chemical fertilizer treatment. Moreover combining application of organic-inorganic treatments was benefited for improving the contents of HA and FA, but decreasing HA/FA ratio as an extension of time. Combining application of organic-inorganic was benefited for improving the contents ol readily oxidizable organic matter. And the contents of soil organic matter in long-term experiment and the contents of readily oxidizable O.M were highly significant positive correlation and the contents of soil total nitrogen, avail nitrogen and potassium were significant positive correlation; the contents of soil readily oxidizable O.M and the contents of soil total nitrogen, avail- able P and rice yield were significant positive correlation. Thereinto, the correlation (r=0.818 1 ) between the rice yield and soil readily oxidizable O.M was higher than the correlation (r=0.802 0) between the rice yield and soil organic matter. It showed the soil readily oxidized organic matter had greater contribution to the rice yield.
基金Supported by National Natural Science Foundation of China(41361068)Key Science and Technology Research Funds for Guangxi Universities(2013ZD067)Guangxi Natural Science Foundation(2011GXNSFB-018056)
文摘Rational fertilization is an important measure to increase crop yield and soil fertility. Through analysis,this paper aims to master the change characteristics of soil organic matter and rice yield under different fertilizer treatments,in order to provide an important reference for the sustainable use of soil and effective fertilization. Long-term( 19 years) rice crop rotation experiments in waterloggogenic paddy soil were conducted to investigate the change trend of crop grain yield and soil organic matter with time,reveal the dynamic characteristics and relationship between main fertility factors and crop yields using comparative analysis at three sites with conventional fertilization and non-fertilization in Guilin. The results showed that compared with previous years,the rice yield increased by 53% under the fertilization treatment and degreased by 66% under the control. Over the years,the average soil organic matter( SOM) content under fertilization treatment was 23% higher than under CK treatment. This indicates that chemical fertilizer and organic manure application can increase the rice yield and soil organic matter,and high rice yield can be attributed to the SOM increase.
基金supported by the National Natural Science Foundation of China (No. 41977273 )the National Key Research and Development Program of China (No. 2018YFC1800702 )the Natural Science Foundation of Tianjin City (No. 19JCQNJC07700 )。
文摘Cadmium(Cd) contamination in paddy soil has caused public concern. The uptake of Cd by rice plants depends on soil Cd mobility, which is in turn substantially influenced by organic matter(OM). In this review, we first summarize the fate of Cd in soil and the role of OM. We then focus on the effects of OM on Cd mobility in paddy soil and the factors influencing the remedial effectiveness of OM amendments. We further discuss the performance of straw incorporation in the remediation of Cd-contaminated paddy soils reported in laboratory and field studies. Considering the huge production of organic materials(such as straw) in agriculture, the use of natural OM for soil remediation has obvious appeal due to the environmental benefits and low cost. Although there have been successful application cases, the properties of OM amendments and soil can significantly affect the remedial performance of the OM amendments. Importantly, straw incorporation alone does not often decrease the mobility of Cd in soil or the Cd content in rice grains. Careful evaluation is required when considering natural OM amendments, and the factors and mechanisms that influence their remedial effectiveness need further investigation in paddy soil with realistic Cd concentrations.
基金financially supported by the Higher Education Department of Guangdong Province (No.2020KCXTD025)the National Key Research and Development Program of China (No.2017YFD0800404).
文摘In the rice-wheat rotation system,biochar(BC)can be applied at the initiation of the rice or wheat season.Here,we compared the effects of BC that were applied at two different crop seasons on wheat production,quality,and soil profile properties in a rice-wheat rotation system with nitrogen(N)fertilizer applied at 280 kg/ha rate.Results showed that both wheat grain production and N recovery use efficiency were influenced by BC applied at two crop seasons.Biochar application did not affect the total non-essential amino-acid,but when applied during wheat season,BC significantly(p<0.05)increased total essential amino acid in grain by 12.3%,particularly for the valine(+48.2%),methionine(+43.8%),and isoleucine(+10.3%).We found that BC significantly(p<0.05)decreased the pH of soil at 0–6 cm and 20–30 cm by 0.14–0.18 and 0.05–0.08 units,respectively.The NH4+-N content of the whole observed soil profile were reduced by BC application,however,the effect of BC on NO3–-N content varied with the application season and profile depth.Interestingly,BC applied at wheat and rice season significantly(p<0.05)improved topsoil N contents by 48.4%and 19.7%,respectively.In addition,data suggested that BC applied during wheat season performed better in enhancing soil available phosphorus,potassium,and organic matter contents.In conclusion,we suggest that the optimum application time of BC for enhancing crop production and quality(take amino-acid content for example)and improving soil fertility is at the initiation of the wheat season.