Refined carbon(RC) derived from coal fly ash(CFA) as well as powdered activated carbon(PAC) was investigated as adsorbent to remove residual amine collector HAY from aqueous solution.The RC and PAC were characterized ...Refined carbon(RC) derived from coal fly ash(CFA) as well as powdered activated carbon(PAC) was investigated as adsorbent to remove residual amine collector HAY from aqueous solution.The RC and PAC were characterized by scanning electron microscopy(SEM),surface area measurement,Zeta potential measurement and Fourier transform infrared(FTIR) spectroscopy.The effect factors and mechanisms of HAY adsorption onto RC and PAC were studied in detail.The results show that the experimental kinetic data agree well with the pseudo second-order equation,and the Langmuir isotherm model is found to be more appropriate to explicate the experimental equilibrium isotherm results than the Freundlich model.The adsorption capacities of PAC and RC increase with pH.It is found that alkaline condition is conducive to the adsorption of HAY onto PAC and RC and the adsorption efficiency of RC is close to PAC at pH near 11.Zeta potential variation of adsorbents suggests that HAY generates electrostatic adsorption onto RC and PAC.FTIR analysis shows that the adsorption is dominantly of a physical process.The Box-Behnken design optimization conditions of process are RC 1 g/L,pH 11,temperature 302 K and initial HAY concentration 100 mg/L.Under these conditions,the measured adsorption ratio and adsorption capacity are 87.91%and 87.91 mg/g,respectively.Thus,the RC is considered to be a potential adsorbent for the removal of residual amine from aqueous solution.展开更多
Pore structure characteristics are significant factor in the evaluation of the physical characteristics of low-rank coal.In this study,three low-rank coal samples were collected from the Xishanyao Formation,Santanghu ...Pore structure characteristics are significant factor in the evaluation of the physical characteristics of low-rank coal.In this study,three low-rank coal samples were collected from the Xishanyao Formation,Santanghu Basin,and low-temperature liquid-nitrogen adsorption(LP-N2A)measurements were taken under various pretreatment temperatures.Owing to the continuous loss of water and volatile matter in low-rank coal,the total pore volume assumes a three-step profile with knee temperatures of 150°C and 240°C.However,the ash in the coal can protect the coal skeleton.Pore collapse mainly occurs for mesopores with aperture smaller than 20 nm.Mesopores with apertures smaller than 5 nm exhibit a continuous decrease in pore volume,whereas the pore volume of mesopores with apertures ranging from 5 to 10 nm increases at lower pretreatment temperatures(<150°C)followed by a faint decrease.As for mesopores with apertures larger than 10 nm,the pore volume increases significantly when the pretreatment temperature reaches 300°C.The pore structure of low-rank coal features a significant heating effect,the pretreatment temperature should not exceed 150°C when the LP-N2A is used to evaluate the pore structure of low-rank coal to effectively evaluate the reservoir characteristics of low-rank coal.展开更多
The coal mine roof rating(CMRR) is a measure of roof quality or structure competency for bedded roof types typically of underground coal mines. The CMRR has been used widely in the US, South Africa,Canada and Australi...The coal mine roof rating(CMRR) is a measure of roof quality or structure competency for bedded roof types typically of underground coal mines. The CMRR has been used widely in the US, South Africa,Canada and Australia. In order to investigate the application of the CMRR system in Chinese coal mines,two coal mines in China located in Panjiang Coal Field in Guizhou Province were investigated. Field data were collected which is required to calculate the CMRR value based on underground exposure. The CMRR values of 11 locations in two coal mines were calculated. The investigations demonstrated that the chance of mine roof failure is very low if the CMRR value is more than 50, given adequate support is installed in mine. It was found that the CMRR guideline are useful to preliminarily investigate stability in Panjiang Coal Field mines.展开更多
基金Projects(2013BAB07B03,2013BAC15B01)supported by the National Key Technology Research and Development Program of the Ministry of Science and Technology of ChinaProject(51264005)supported by the National Natural Science Foundation of China+1 种基金Project(Qiankehejz[2014]2009)supported by the Key Foundation of Science and Technology of Guizhou Province,ChinaProject([2013]019)supported by“125”Major Special Project of Guizhou Province,China
文摘Refined carbon(RC) derived from coal fly ash(CFA) as well as powdered activated carbon(PAC) was investigated as adsorbent to remove residual amine collector HAY from aqueous solution.The RC and PAC were characterized by scanning electron microscopy(SEM),surface area measurement,Zeta potential measurement and Fourier transform infrared(FTIR) spectroscopy.The effect factors and mechanisms of HAY adsorption onto RC and PAC were studied in detail.The results show that the experimental kinetic data agree well with the pseudo second-order equation,and the Langmuir isotherm model is found to be more appropriate to explicate the experimental equilibrium isotherm results than the Freundlich model.The adsorption capacities of PAC and RC increase with pH.It is found that alkaline condition is conducive to the adsorption of HAY onto PAC and RC and the adsorption efficiency of RC is close to PAC at pH near 11.Zeta potential variation of adsorbents suggests that HAY generates electrostatic adsorption onto RC and PAC.FTIR analysis shows that the adsorption is dominantly of a physical process.The Box-Behnken design optimization conditions of process are RC 1 g/L,pH 11,temperature 302 K and initial HAY concentration 100 mg/L.Under these conditions,the measured adsorption ratio and adsorption capacity are 87.91%and 87.91 mg/g,respectively.Thus,the RC is considered to be a potential adsorbent for the removal of residual amine from aqueous solution.
基金This work was supported by the Natural Science Basic Research Plan in Shaanxi Province of China(Program No.2019JQ-527)Shandong Key laboratory of Depositional Mineralization and Sedimentary Mineral Open Fund(Program No.DMSM20190014)Scientific Research Program Funded by Shaanxi Provincial Education Department(Program No.20JS116)。
文摘Pore structure characteristics are significant factor in the evaluation of the physical characteristics of low-rank coal.In this study,three low-rank coal samples were collected from the Xishanyao Formation,Santanghu Basin,and low-temperature liquid-nitrogen adsorption(LP-N2A)measurements were taken under various pretreatment temperatures.Owing to the continuous loss of water and volatile matter in low-rank coal,the total pore volume assumes a three-step profile with knee temperatures of 150°C and 240°C.However,the ash in the coal can protect the coal skeleton.Pore collapse mainly occurs for mesopores with aperture smaller than 20 nm.Mesopores with apertures smaller than 5 nm exhibit a continuous decrease in pore volume,whereas the pore volume of mesopores with apertures ranging from 5 to 10 nm increases at lower pretreatment temperatures(<150°C)followed by a faint decrease.As for mesopores with apertures larger than 10 nm,the pore volume increases significantly when the pretreatment temperature reaches 300°C.The pore structure of low-rank coal features a significant heating effect,the pretreatment temperature should not exceed 150°C when the LP-N2A is used to evaluate the pore structure of low-rank coal to effectively evaluate the reservoir characteristics of low-rank coal.
基金supported by the Science Foundation of Guizhou Province of China (No. 20177283)the Special Program for Academic Foster and Innovation research of Guizhou University of China (No. 20175788)
文摘The coal mine roof rating(CMRR) is a measure of roof quality or structure competency for bedded roof types typically of underground coal mines. The CMRR has been used widely in the US, South Africa,Canada and Australia. In order to investigate the application of the CMRR system in Chinese coal mines,two coal mines in China located in Panjiang Coal Field in Guizhou Province were investigated. Field data were collected which is required to calculate the CMRR value based on underground exposure. The CMRR values of 11 locations in two coal mines were calculated. The investigations demonstrated that the chance of mine roof failure is very low if the CMRR value is more than 50, given adequate support is installed in mine. It was found that the CMRR guideline are useful to preliminarily investigate stability in Panjiang Coal Field mines.
