In this research, at different quantities as fillers, Boric Acid, Calcite (CaCO<sub>3</sub>), SPT (Sodium Perborate Tetrahydrate) and as coupling matters, 3%, MAPE (Maleic Anhydride Grafted Polyethylene), ...In this research, at different quantities as fillers, Boric Acid, Calcite (CaCO<sub>3</sub>), SPT (Sodium Perborate Tetrahydrate) and as coupling matters, 3%, MAPE (Maleic Anhydride Grafted Polyethylene), Titanate and Silanyl (Vinyltriethoxysilane) were added waste paper. Composite boards were pressed and cut in 1 × 30 × 30 cm. In order to identify some properties of the produced boards, experimental works were applied according to the standards. In conclusion, bending stress reduced with filler materials and chemicals was reduced even more than the bending stress except for some experimental groups. In addition, it was observed that the coupling chemicals increased the bending strength and modulus of elasticity compared to the fillers.展开更多
Industrial production and domestic discharge produce a large amount of oily wastewater, which seriously affects the stability of the ecological environment. Membrane separation technology provides another path to trea...Industrial production and domestic discharge produce a large amount of oily wastewater, which seriously affects the stability of the ecological environment. Membrane separation technology provides another path to treating oily wastewater. And appropriate surface modification of the membrane helps to achieve high efficiency of treating oily wastewater. With green, economy and stability been more concerned.The focal research reports a completely biodegradable all cellulose composite filter paper(ACCFP) composed of Ⅰ-cellulose macrofibers and Ⅱ-cellulose matrix. It is a simple one-step impregnation method to adjust the surface microstructure of the pristine filter paper(PFP), and it does not involve with chemical reaction. The pre-wetted ACCFP consist of Ⅱ-cellulose hydrogel and Ⅰ-cellulose reinforcement in the process of oil-water separation. This layer of hydrogel is the fundamental to underwater superoleophobicity, which determines their eligibility for applications of efficient oil-water mixture or oil-in-water(oil/water) emulsion separation. The separation efficiency of oil-water mixture and oil/water emulsion exceed 95% and 99.9%, respectively. In addition, excellent mechanical properties of ACCFP in dry and wet conditions ensure its stability in service and prolong service life in applications. The focal study provides a new method for high-performance oil-water separation and it is more in line with sustainable chemistry.展开更多
With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wi...With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wide applications in flexible LIBs. However, due to the prone-to-restacking feature of graphene layers, a long cycle life at high current densities is rather difficult to be achieved. Herein, a unique threedimensional(3D) hierarchically porous NiO micro-flowers/graphene paper(fNiO/GP) electrode is successfully fabricated. The resulting fNiO/GP electrode shows superior long-term cycling stability at high rates(e.g., storage capacity of 359 mAh/g after 600 cycles at a high current density of 1 A/g). The facile 3D porous structure combines both the advantages of the graphene that is highly conductive and flexible to ensure rapid electrons/ions transfer and buffer the volume expansion of NiO during charge/discharge,and of the micro-sized NiO flowers that induces hierarchical between-layer pores ranging from nanomicro meters to promote the penetration of the electrolyte and prevent the re-stacking of graphene layers. Such structural design will inspire future manufacture of a wide range of active materials/graphene composite electrodes for high performance flexible LIBs.展开更多
Carbon nanotubes(CNTs)incorporated polymeric composites have been extensively investigated for microwave absorption at target frequencies to meet the requirement of radar cross-section reduction.In this work,a strateg...Carbon nanotubes(CNTs)incorporated polymeric composites have been extensively investigated for microwave absorption at target frequencies to meet the requirement of radar cross-section reduction.In this work,a strategy of efficient utilization of CNT in producing CNT incorporated aramid papers is demonstrated.The layer-by-layer self-assembly technique is used to coat the surfaces of meta-aramid fibers and fibrils with CNT,providing novel raw materials available for the large-scale papermaking.The hierarchical construction of CNT networks resolves the dilemma of increasing CNT content and avoiding the agglomeration of CNT,which is a frequent challenge for CNT incorporated polymeric composites.The composite paper,which contains abundant heterogeneous interfaces and long-range conductive networks,is capable of reaching a high permittivity and dielectric loss tangent at a low CNT loading,its complex permittivity is,so far,adjustable in the range of(1.20−j0.05)to(25.17−j18.89)at 10 GHz.Some papers with optimal matching thicknesses achieve a high-efficiency microwave absorption with a reflection loss lower than−10 dB in the entire X-band.展开更多
Space charge inside oil paper insulation can severely distort the electric field distribution and lead to degradation of electrical performance of materials.A vast number of articles about the space charge characteris...Space charge inside oil paper insulation can severely distort the electric field distribution and lead to degradation of electrical performance of materials.A vast number of articles about the space charge characteristics of oil paper insulation under different conditions has been published;however,few report the influence of oil paper composition.In this paper,a comparison of the space charge distribution as well as the electrical conductivity of four combinations of transformer oil(Kunlun#25 and Nynas oil)and paper(type I from XD factory,type II imported from France)is carried out.The results show that the combination of type II paper and Kunlun oil performs well with minimal charge accumulation inside the materials.To understand the phenomenon,results of space charge measurements and electrical conductivity are associated.A microscopic inspection of two types of paper is conducted to acquire the surface condition of the paper.The relationship between space charge injection quantity and surface condition of the papers is discussed.It is observed that a relatively higher conductivity of oil as well as a smooth,dense surface of paper can suppress space charge in oil paper insulation.展开更多
Carbon nanotubes(CNTs)have received considerable attention for their excellent thermal and electrical conductivity as well as scalable production.However,CNT dispersions are prone to settling and have a short shelf ti...Carbon nanotubes(CNTs)have received considerable attention for their excellent thermal and electrical conductivity as well as scalable production.However,CNT dispersions are prone to settling and have a short shelf time,especially under high concentration,which significantly hinders their further processing and increases transportation costs.Here,we report a highly concentrated CNT dough enabled by ionic liquid crystal(ILC)as auxiliaries.Benefiting from the temperature-controlled physical transformation of the ILC,the CNTs of the powder state are successfully transferred to highly processable dough with excellent electrical conductivity,flame retardancy,and outstanding redispersibility even after 180 days of storage.In particular,the CNT dough exhibits excellent self-healing properties and good reshapable capability.Various bulk form CNT derived from the ILC armored CNT dough are realized by facile processing technique.Hybrid nanocomposite papers with ANF nanofiber exhibited excellent photothermal conversion and Joule heating properties.The redispersible CNT doughs presented here promise to revolutionize traditional CNT powder and dispersions as the primary raw material for building CNT-based architectures and facilitate the large-scale application of CNTs.展开更多
文摘In this research, at different quantities as fillers, Boric Acid, Calcite (CaCO<sub>3</sub>), SPT (Sodium Perborate Tetrahydrate) and as coupling matters, 3%, MAPE (Maleic Anhydride Grafted Polyethylene), Titanate and Silanyl (Vinyltriethoxysilane) were added waste paper. Composite boards were pressed and cut in 1 × 30 × 30 cm. In order to identify some properties of the produced boards, experimental works were applied according to the standards. In conclusion, bending stress reduced with filler materials and chemicals was reduced even more than the bending stress except for some experimental groups. In addition, it was observed that the coupling chemicals increased the bending strength and modulus of elasticity compared to the fillers.
基金the financial support from the National Key R&D Program of China (no. 2018YFB1501602)Science Foundation of Shanxi Province, China (Grant no. 201901D111006ZD)+1 种基金Fund for Shanxi “1331 project”Shanxi Province Platform Base and Talent Special Fund (no. 201705D211023)。
文摘Industrial production and domestic discharge produce a large amount of oily wastewater, which seriously affects the stability of the ecological environment. Membrane separation technology provides another path to treating oily wastewater. And appropriate surface modification of the membrane helps to achieve high efficiency of treating oily wastewater. With green, economy and stability been more concerned.The focal research reports a completely biodegradable all cellulose composite filter paper(ACCFP) composed of Ⅰ-cellulose macrofibers and Ⅱ-cellulose matrix. It is a simple one-step impregnation method to adjust the surface microstructure of the pristine filter paper(PFP), and it does not involve with chemical reaction. The pre-wetted ACCFP consist of Ⅱ-cellulose hydrogel and Ⅰ-cellulose reinforcement in the process of oil-water separation. This layer of hydrogel is the fundamental to underwater superoleophobicity, which determines their eligibility for applications of efficient oil-water mixture or oil-in-water(oil/water) emulsion separation. The separation efficiency of oil-water mixture and oil/water emulsion exceed 95% and 99.9%, respectively. In addition, excellent mechanical properties of ACCFP in dry and wet conditions ensure its stability in service and prolong service life in applications. The focal study provides a new method for high-performance oil-water separation and it is more in line with sustainable chemistry.
基金financially supported by the National Key R&D Program of China (No.2017YFE0111500)the National Natural Science Foundation of China (No.51673123 and 51222305)Sichuan Province Science and Technology Project (No.2016JQ0049)。
文摘With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wide applications in flexible LIBs. However, due to the prone-to-restacking feature of graphene layers, a long cycle life at high current densities is rather difficult to be achieved. Herein, a unique threedimensional(3D) hierarchically porous NiO micro-flowers/graphene paper(fNiO/GP) electrode is successfully fabricated. The resulting fNiO/GP electrode shows superior long-term cycling stability at high rates(e.g., storage capacity of 359 mAh/g after 600 cycles at a high current density of 1 A/g). The facile 3D porous structure combines both the advantages of the graphene that is highly conductive and flexible to ensure rapid electrons/ions transfer and buffer the volume expansion of NiO during charge/discharge,and of the micro-sized NiO flowers that induces hierarchical between-layer pores ranging from nanomicro meters to promote the penetration of the electrolyte and prevent the re-stacking of graphene layers. Such structural design will inspire future manufacture of a wide range of active materials/graphene composite electrodes for high performance flexible LIBs.
基金the National Natural Science Foundation of China(No.U21A2093).
文摘Carbon nanotubes(CNTs)incorporated polymeric composites have been extensively investigated for microwave absorption at target frequencies to meet the requirement of radar cross-section reduction.In this work,a strategy of efficient utilization of CNT in producing CNT incorporated aramid papers is demonstrated.The layer-by-layer self-assembly technique is used to coat the surfaces of meta-aramid fibers and fibrils with CNT,providing novel raw materials available for the large-scale papermaking.The hierarchical construction of CNT networks resolves the dilemma of increasing CNT content and avoiding the agglomeration of CNT,which is a frequent challenge for CNT incorporated polymeric composites.The composite paper,which contains abundant heterogeneous interfaces and long-range conductive networks,is capable of reaching a high permittivity and dielectric loss tangent at a low CNT loading,its complex permittivity is,so far,adjustable in the range of(1.20−j0.05)to(25.17−j18.89)at 10 GHz.Some papers with optimal matching thicknesses achieve a high-efficiency microwave absorption with a reflection loss lower than−10 dB in the entire X-band.
基金supported in part by the National Key Basic Research Program of China under Project(No.2011CB209404).
文摘Space charge inside oil paper insulation can severely distort the electric field distribution and lead to degradation of electrical performance of materials.A vast number of articles about the space charge characteristics of oil paper insulation under different conditions has been published;however,few report the influence of oil paper composition.In this paper,a comparison of the space charge distribution as well as the electrical conductivity of four combinations of transformer oil(Kunlun#25 and Nynas oil)and paper(type I from XD factory,type II imported from France)is carried out.The results show that the combination of type II paper and Kunlun oil performs well with minimal charge accumulation inside the materials.To understand the phenomenon,results of space charge measurements and electrical conductivity are associated.A microscopic inspection of two types of paper is conducted to acquire the surface condition of the paper.The relationship between space charge injection quantity and surface condition of the papers is discussed.It is observed that a relatively higher conductivity of oil as well as a smooth,dense surface of paper can suppress space charge in oil paper insulation.
基金This work was supported by the National Natural Science Foun-dation of China(Nos.51875330 and 51975342)the Natural Science Foundation of Shaanxi Province(Nos.2018JZ5003 and 2019JZ-24).
文摘Carbon nanotubes(CNTs)have received considerable attention for their excellent thermal and electrical conductivity as well as scalable production.However,CNT dispersions are prone to settling and have a short shelf time,especially under high concentration,which significantly hinders their further processing and increases transportation costs.Here,we report a highly concentrated CNT dough enabled by ionic liquid crystal(ILC)as auxiliaries.Benefiting from the temperature-controlled physical transformation of the ILC,the CNTs of the powder state are successfully transferred to highly processable dough with excellent electrical conductivity,flame retardancy,and outstanding redispersibility even after 180 days of storage.In particular,the CNT dough exhibits excellent self-healing properties and good reshapable capability.Various bulk form CNT derived from the ILC armored CNT dough are realized by facile processing technique.Hybrid nanocomposite papers with ANF nanofiber exhibited excellent photothermal conversion and Joule heating properties.The redispersible CNT doughs presented here promise to revolutionize traditional CNT powder and dispersions as the primary raw material for building CNT-based architectures and facilitate the large-scale application of CNTs.