Based on the assumptions of parabolic variation of nucleation rate versus time and transformation kinetics depending mainly on nucleation rate, a different model for bainitic transformation kinetics in hypoeutectoid s...Based on the assumptions of parabolic variation of nucleation rate versus time and transformation kinetics depending mainly on nucleation rate, a different model for bainitic transformation kinetics in hypoeutectoid steels was established. And this model was proved to be effective in the description of bainitic transformation by comparison with the result of conventional Avrami equation.展开更多
Formation and growth of the intermediate phases in the Ni-Al diffusion couples prepared by pouring technique were investigated. Electron probe microanalysis, scanning electron microscopy and X-ray diffraction were use...Formation and growth of the intermediate phases in the Ni-Al diffusion couples prepared by pouring technique were investigated. Electron probe microanalysis, scanning electron microscopy and X-ray diffraction were used to characterize the product phases in the joints. The results show that two intermediate phases form in the sequence of NiAl3 and Ni2Al3 during solidification. After annealed, Ni2Al3 and NiAl3 still exist in the joints of the couples. The reasons for the formation of Ni2Al3 and NiAl3, as well as the absence of NiAl, Ni5Al3 and Ni3Al were discussed, respectively. The growth kinetics of both product phase layers indicates that their growth obeys the parabolic rate law. The activation energies and frequency factors for NiAl3 and Ni2Al3 phases were also calculated according to the Arrhenius equation.展开更多
The influence of an alternative magnetic field on the growth of the diffusionlayer in Al-Zn diffusion couple was studied. The thickness of the diffusion layer was examined. Theresults show that the alternative magneti...The influence of an alternative magnetic field on the growth of the diffusionlayer in Al-Zn diffusion couple was studied. The thickness of the diffusion layer was examined. Theresults show that the alternative magnetic field increases the thickness of the diffusion layer andthe effect increases with the intensity and frequency of the alternative magnetic field increasing. The growth of the diffusion layer obeys the parabolic rate law and the growth rateincreases with the application of the alternative magnetic field. This growth rate change ismanifested through a change in the frequency factor k_0 and not through a change in the activationenergy Q. The frequency factor k_0 for the diffusion layer growth with the alternative magneticfield is 5.03 cm^2/s and the one without the magnetic field is 3.84 cm^2/s.展开更多
文摘Based on the assumptions of parabolic variation of nucleation rate versus time and transformation kinetics depending mainly on nucleation rate, a different model for bainitic transformation kinetics in hypoeutectoid steels was established. And this model was proved to be effective in the description of bainitic transformation by comparison with the result of conventional Avrami equation.
基金Funded by the National Natural Science Foundation of China(No.10477006)the Key Project of Chinese Ministry of Education(No.106055)
文摘Formation and growth of the intermediate phases in the Ni-Al diffusion couples prepared by pouring technique were investigated. Electron probe microanalysis, scanning electron microscopy and X-ray diffraction were used to characterize the product phases in the joints. The results show that two intermediate phases form in the sequence of NiAl3 and Ni2Al3 during solidification. After annealed, Ni2Al3 and NiAl3 still exist in the joints of the couples. The reasons for the formation of Ni2Al3 and NiAl3, as well as the absence of NiAl, Ni5Al3 and Ni3Al were discussed, respectively. The growth kinetics of both product phase layers indicates that their growth obeys the parabolic rate law. The activation energies and frequency factors for NiAl3 and Ni2Al3 phases were also calculated according to the Arrhenius equation.
基金This work was financially supported by the National 863 Foundation of China (No. 2001AA332030)the National Key Basic Research Program (973) (No. G1999064905)
文摘The influence of an alternative magnetic field on the growth of the diffusionlayer in Al-Zn diffusion couple was studied. The thickness of the diffusion layer was examined. Theresults show that the alternative magnetic field increases the thickness of the diffusion layer andthe effect increases with the intensity and frequency of the alternative magnetic field increasing. The growth of the diffusion layer obeys the parabolic rate law and the growth rateincreases with the application of the alternative magnetic field. This growth rate change ismanifested through a change in the frequency factor k_0 and not through a change in the activationenergy Q. The frequency factor k_0 for the diffusion layer growth with the alternative magneticfield is 5.03 cm^2/s and the one without the magnetic field is 3.84 cm^2/s.