In this study, we thoroughly examined the impact of heat treatments and hole count (p) on the properties of LnSrBaCu<sub>3</sub>O<sub>6+z</sub> (Ln = Eu, Sm, Nd) compounds. We focused on prepar...In this study, we thoroughly examined the impact of heat treatments and hole count (p) on the properties of LnSrBaCu<sub>3</sub>O<sub>6+z</sub> (Ln = Eu, Sm, Nd) compounds. We focused on preparation, X-ray diffraction with Rietveld refinement, AC susceptibility, DC resistivity measurements, and heat treatment effects. Two heat treatment types were applied: oxygen annealing [O] and argon annealing followed by oxygen annealing [AO]. As the rare earth Ln’s ionic radius increased, certain parameters notably changed. Specifically, c parameter, surface area S, and volume V increased, while critical temperature Tc and holes (p) in the CuO<sub>2</sub> plane decreased. The evolution of these parameters with rare earth Ln’s ionic radius in [AO] heat treatment is linear. Regardless of the treatment, the structure is orthorhombic for Ln = Eu, tetragonal for Ln = Nd, orthorhombic for Ln = Sm [AO], and pseudo-tetragonal for Sm [O]. The highest critical temperature is reached with Ln = Eu (Tc [AO] = 87.1 K). Notably, for each sample, Tc [AO] surpasses Tc [O]. Observed data stems from factors including rare earth ionic size, improved cationic and oxygen chain order, holes count p in Cu(2)O<sub>2</sub> planes, and in-phase purity of [AO] samples. Our research strives to clearly demonstrate that the density of holes (p) within the copper plane stands as a determinant impacting the structural, electrical, and superconducting properties of these samples. Meanwhile, the other aforementioned parameters contribute to shaping this density (p).展开更多
Through finite element numerical simulation and based on laminated plate theory, the effect of dimension on the torsion properties of uniform C/SiC composites pipe was studied to provide a theoretical guidance for pre...Through finite element numerical simulation and based on laminated plate theory, the effect of dimension on the torsion properties of uniform C/SiC composites pipe was studied to provide a theoretical guidance for preparing the C/SiC pipe with different dimensions. The results show that, with increasing length of pipe, the anti-torsion section coefficient of pipe increases whereas the torsion angle per unit length decreases. Increasing the length can improve the torsion property. Anti-torsion section coefficient rises with increasing internal radius, while the torsion angle per unit length decreases to a constant. With increasing thickness, the anti-torsion section coefficient increases whereas the amplitude decreases gradually, and the torsion angle per unit length is a constant. Increment of internal radius and thickness improves the torsion property finitely.展开更多
文摘In this study, we thoroughly examined the impact of heat treatments and hole count (p) on the properties of LnSrBaCu<sub>3</sub>O<sub>6+z</sub> (Ln = Eu, Sm, Nd) compounds. We focused on preparation, X-ray diffraction with Rietveld refinement, AC susceptibility, DC resistivity measurements, and heat treatment effects. Two heat treatment types were applied: oxygen annealing [O] and argon annealing followed by oxygen annealing [AO]. As the rare earth Ln’s ionic radius increased, certain parameters notably changed. Specifically, c parameter, surface area S, and volume V increased, while critical temperature Tc and holes (p) in the CuO<sub>2</sub> plane decreased. The evolution of these parameters with rare earth Ln’s ionic radius in [AO] heat treatment is linear. Regardless of the treatment, the structure is orthorhombic for Ln = Eu, tetragonal for Ln = Nd, orthorhombic for Ln = Sm [AO], and pseudo-tetragonal for Sm [O]. The highest critical temperature is reached with Ln = Eu (Tc [AO] = 87.1 K). Notably, for each sample, Tc [AO] surpasses Tc [O]. Observed data stems from factors including rare earth ionic size, improved cationic and oxygen chain order, holes count p in Cu(2)O<sub>2</sub> planes, and in-phase purity of [AO] samples. Our research strives to clearly demonstrate that the density of holes (p) within the copper plane stands as a determinant impacting the structural, electrical, and superconducting properties of these samples. Meanwhile, the other aforementioned parameters contribute to shaping this density (p).
基金Funded by the National Natural Science Foundation of China(Nos.51772246,51272210,50902112,and U1737209)the Program for New Century Excellent Talents in University(NCET-13-0474)+1 种基金the Fundamental Research Funds for the Central Universities(3102017jg02001)the National Program for Support of Topnotch Young Professionals
文摘Through finite element numerical simulation and based on laminated plate theory, the effect of dimension on the torsion properties of uniform C/SiC composites pipe was studied to provide a theoretical guidance for preparing the C/SiC pipe with different dimensions. The results show that, with increasing length of pipe, the anti-torsion section coefficient of pipe increases whereas the torsion angle per unit length decreases. Increasing the length can improve the torsion property. Anti-torsion section coefficient rises with increasing internal radius, while the torsion angle per unit length decreases to a constant. With increasing thickness, the anti-torsion section coefficient increases whereas the amplitude decreases gradually, and the torsion angle per unit length is a constant. Increment of internal radius and thickness improves the torsion property finitely.
