The coal partial gasification process produces a large number of chars.They have similar combustion characteristics to anthracite and can be utilized as a material manufacturing clean briquette to replace residential ...The coal partial gasification process produces a large number of chars.They have similar combustion characteristics to anthracite and can be utilized as a material manufacturing clean briquette to replace residential coal to achieve clean combustion.Moreover,the coal partial gasification produced more tar at relatively low temperature,which can be applied as naphtha or diesel after purification and hydrogenation.Herein,experiments of coal partial gasification coproducing char,tar,and gas are carried out on a bench-scale fluidized bed reactor during the temperature range of 625–762℃.The effect of equivalence ratio on the characteristics of coal partial gasification products is studied.The results show that the equivalence ratio increasing from 0.06 to 0.13 leads to a higher partial gasification temperature and lower char yield,and tar yield reaches a maximum value and the lower calorific value of gas reaches as high as 6.14 MJ/m^(3).When the gasification temperature is lower than 643℃,the increase in temperature promotes the generation of oxygen-containing functional groups and aromatic compounds in coal particles,and the microstructures of char become more disordered.The combustion stability of char is getting worse,whereas the pore structures in char become abundant at high temperatures.From the analysis of the tar chromatography column,it is observed that asphaltene and non-hydrocarbon account for 77%–88%of the total amount of tar.展开更多
基金supported by the National Key Research and Development Projects of China(2019YFE0100100-05).
文摘The coal partial gasification process produces a large number of chars.They have similar combustion characteristics to anthracite and can be utilized as a material manufacturing clean briquette to replace residential coal to achieve clean combustion.Moreover,the coal partial gasification produced more tar at relatively low temperature,which can be applied as naphtha or diesel after purification and hydrogenation.Herein,experiments of coal partial gasification coproducing char,tar,and gas are carried out on a bench-scale fluidized bed reactor during the temperature range of 625–762℃.The effect of equivalence ratio on the characteristics of coal partial gasification products is studied.The results show that the equivalence ratio increasing from 0.06 to 0.13 leads to a higher partial gasification temperature and lower char yield,and tar yield reaches a maximum value and the lower calorific value of gas reaches as high as 6.14 MJ/m^(3).When the gasification temperature is lower than 643℃,the increase in temperature promotes the generation of oxygen-containing functional groups and aromatic compounds in coal particles,and the microstructures of char become more disordered.The combustion stability of char is getting worse,whereas the pore structures in char become abundant at high temperatures.From the analysis of the tar chromatography column,it is observed that asphaltene and non-hydrocarbon account for 77%–88%of the total amount of tar.
