In order to select a suitable material for the rolling mill guide application, the dry sliding friction and wear resistance of a tungsten carbide combining cobalt (WC-Co) particle reinforced chromium cast iron composi...In order to select a suitable material for the rolling mill guide application, the dry sliding friction and wear resistance of a tungsten carbide combining cobalt (WC-Co) particle reinforced chromium cast iron composite material were studied. In particular, the wear resistance was discussed in detail. The results showed that the composite material demonstrates 25 times the wear resistance of high Cr cast iron, and 9 times the wear resistance of heat resistant steel. However, the average friction factor in the stable friction stage showed a relationship of μComposites/45#steel>μHigh chromium cast iron/45#steel>μHeat resistant steel/45 # steel. The wear resistance mechanism of the composite material was associated with the reinforcing particles, which protruded from the worn surface to bear the friction load when the matrix material surface was worn, thereby reducing the abrasive and adhesive wear. In addition, the matrix material possessed suitable hardness and toughness, providing a support to the reinforcements.展开更多
The mechanisms of interfacial debonding of particle reinforcedrheological materials are studied. Based on an energy criterion, asimple formula of local critical stress for interfacial debonding isderived and expressed...The mechanisms of interfacial debonding of particle reinforcedrheological materials are studied. Based on an energy criterion, asimple formula of local critical stress for interfacial debonding isderived and expressed in terms of the interfacial energy. Theparticle size effect on interface debond- ing can then be analyzedeasily owing to the fact that critical stress is inverselyproportional to the square root of particle radius. By takingPP/CaCO_3 system as an example, the present energy criterion iscompared with the mechanical debonding criterion, and it is foundthat under the condition that bond strength is equal to matrixstrength and particle radius not over 0.2μm, the mechanicaldebonding cri- terion can be automatically satisfied if the energycirterion is satisfied.展开更多
In this study, a high Cr cast iron surface composite material reinforced with WC-Co particles 2-6 mm in size was prepared using a pressureless sand mold infiltration casting technique. The composition, microstructure ...In this study, a high Cr cast iron surface composite material reinforced with WC-Co particles 2-6 mm in size was prepared using a pressureless sand mold infiltration casting technique. The composition, microstructure and hardness were determined by means of energy dispersive spectrometry(EDS), electron probe microanalysis(EPMA), scanning electron microscope(SEM) and Rockwell hardness measurements. It is determined that the obtained composite layer is about 15 mm thick with a WC-Co particle volumetric fraction of ～38%. During solidification, interface reaction takes place between WC-Co particles and high chromium cast iron. Melting and dissolving of prefabricated particles are also found, suggesting that local Co melting and diffusion play an important role in promoting interface metallurgical bonding. The composite layer is composed of ferrite and a series of carbides, such as(Cr, W, Fe)23C6, WC, W2C, M6C and M12C. The inhomogeneous hardness in the obtained composite material shows a gradient decrease from the particle reinforced metal matrix composite layer to the matrix layer. The maximum hardness of 86.3 HRA(69.5 HRC) is obtained on the particle reinforced surface, strongly indicating that the composite can be used as wear resistant material.展开更多
Micromechanical theory is applied to study the nonlinear elastic and viscoelastic constitutive relations of polymeric matrix filled with high rigidity solid particles. It is shown that Eshelby's method can be exte...Micromechanical theory is applied to study the nonlinear elastic and viscoelastic constitutive relations of polymeric matrix filled with high rigidity solid particles. It is shown that Eshelby's method can be extended to the case of nonlinear matrix and Eshelby's tensor still exists provided that Poisson's ratio of the nonlinear matrix assumes constant value in deforming process and the rigidity of elastic filling particles is much higher than that of the matrix. A new method for averaging process is proposed to overcome the difficulty that occured in applying the ordinary equivalent inclusion method or the seff-consistant method to nonlinear matrices. A rather simple constitutive equation is obtained finally and the strengthening effect of solid particles to composites is investigated.展开更多
基金supported by the Special Important Technology of Guangdong Province,China(2009A080304010,2011A080802003)the Core Technology Research and Strategic Emerging Industries of Guangdong Province,China(2012A090100018)
文摘In order to select a suitable material for the rolling mill guide application, the dry sliding friction and wear resistance of a tungsten carbide combining cobalt (WC-Co) particle reinforced chromium cast iron composite material were studied. In particular, the wear resistance was discussed in detail. The results showed that the composite material demonstrates 25 times the wear resistance of high Cr cast iron, and 9 times the wear resistance of heat resistant steel. However, the average friction factor in the stable friction stage showed a relationship of μComposites/45#steel>μHigh chromium cast iron/45#steel>μHeat resistant steel/45 # steel. The wear resistance mechanism of the composite material was associated with the reinforcing particles, which protruded from the worn surface to bear the friction load when the matrix material surface was worn, thereby reducing the abrasive and adhesive wear. In addition, the matrix material possessed suitable hardness and toughness, providing a support to the reinforcements.
基金the Nationai Natural Science Foundation of China(19632030 and 19872007)Natural Science Foundation of Jiangsu Province
文摘The mechanisms of interfacial debonding of particle reinforcedrheological materials are studied. Based on an energy criterion, asimple formula of local critical stress for interfacial debonding isderived and expressed in terms of the interfacial energy. Theparticle size effect on interface debond- ing can then be analyzedeasily owing to the fact that critical stress is inverselyproportional to the square root of particle radius. By takingPP/CaCO_3 system as an example, the present energy criterion iscompared with the mechanical debonding criterion, and it is foundthat under the condition that bond strength is equal to matrixstrength and particle radius not over 0.2μm, the mechanicaldebonding cri- terion can be automatically satisfied if the energycirterion is satisfied.
基金financially supported by the Special Important Technology of Guangdong Province,China(2009A080304010,2011A080802003)the Core Technology Research and Strategic Emerging Industries of Guangdong Province,China(2012A090100018)
文摘In this study, a high Cr cast iron surface composite material reinforced with WC-Co particles 2-6 mm in size was prepared using a pressureless sand mold infiltration casting technique. The composition, microstructure and hardness were determined by means of energy dispersive spectrometry(EDS), electron probe microanalysis(EPMA), scanning electron microscope(SEM) and Rockwell hardness measurements. It is determined that the obtained composite layer is about 15 mm thick with a WC-Co particle volumetric fraction of ～38%. During solidification, interface reaction takes place between WC-Co particles and high chromium cast iron. Melting and dissolving of prefabricated particles are also found, suggesting that local Co melting and diffusion play an important role in promoting interface metallurgical bonding. The composite layer is composed of ferrite and a series of carbides, such as(Cr, W, Fe)23C6, WC, W2C, M6C and M12C. The inhomogeneous hardness in the obtained composite material shows a gradient decrease from the particle reinforced metal matrix composite layer to the matrix layer. The maximum hardness of 86.3 HRA(69.5 HRC) is obtained on the particle reinforced surface, strongly indicating that the composite can be used as wear resistant material.
基金The work supported by the LNM, Institute of Mechanics, Chinese Academy of Sciencesthe National Natural Science Foundation of China
文摘Micromechanical theory is applied to study the nonlinear elastic and viscoelastic constitutive relations of polymeric matrix filled with high rigidity solid particles. It is shown that Eshelby's method can be extended to the case of nonlinear matrix and Eshelby's tensor still exists provided that Poisson's ratio of the nonlinear matrix assumes constant value in deforming process and the rigidity of elastic filling particles is much higher than that of the matrix. A new method for averaging process is proposed to overcome the difficulty that occured in applying the ordinary equivalent inclusion method or the seff-consistant method to nonlinear matrices. A rather simple constitutive equation is obtained finally and the strengthening effect of solid particles to composites is investigated.
