时差定位(Time Difference of Arrival,TDOA)是一种广泛应用的被动定位技术,具有定位精度高、组网能力强、系统鲁棒性强等特点。针对运动目标定位计算复杂、精度收敛较慢等问题,在给出视距(Line of Sight,LOS)环境下定位模型的基础上,...时差定位(Time Difference of Arrival,TDOA)是一种广泛应用的被动定位技术,具有定位精度高、组网能力强、系统鲁棒性强等特点。针对运动目标定位计算复杂、精度收敛较慢等问题,在给出视距(Line of Sight,LOS)环境下定位模型的基础上,提出了定位适用于多站时差定位系统的定位方法,该方法将组群时差定位关系方程合理地线性化为统计估计问题,利用在线迭代实时求解目标位置。给出了针对目标不同运动特性条件下的多平台协同定位算法及其仿真结果,仿真结果表明所述方法可以实现对目标的精确定位,并且分析了运动形式对于定位精度的影响,仿真结果对于系统的工程设计具有指导作用。展开更多
Modern cars are mostly computerized and equipped with passive keyless entry and start(PKES) system. PKES is based on Radio Frequency Identification(RFID) technology for authentication of the authorized drivers. RFID t...Modern cars are mostly computerized and equipped with passive keyless entry and start(PKES) system. PKES is based on Radio Frequency Identification(RFID) technology for authentication of the authorized drivers. RFID technology has replaced the conventional ways of identification and authorization in order to facilitate users while introducing new security challenges. In this article, we focused on verifying the presence of authorized key in the physical proximity of car by employing multiple antennas. Application of multiple antennas to the currently developed cryptographic algorithms opens a new approach for researchers to improve security of RFID based systems. We propose an advanced security system for PKES using multiple antennas wherein an authorized key passes through multiple vicinities to allow driver to access and start the car. Furthermore, we modified a light-weight cryptographic protocol named as HB(Hopper and Blum) protocol to integrate it with the proposed design based on multiple antennas. Simulation results show improvement in security functionality while keeping in view the efficiency constraints.展开更多
Passive NO_(x) adsorbers(PNAs)were proposed to address the NO_(x) emissions during the cold start phase.Here we show a novel Ce-based BEA zeolite,as a noble-metal-free passive NO_(x)adsorber.The NO_(x) adsorption capa...Passive NO_(x) adsorbers(PNAs)were proposed to address the NO_(x) emissions during the cold start phase.Here we show a novel Ce-based BEA zeolite,as a noble-metal-free passive NO_(x)adsorber.The NO_(x) adsorption capacity of Ce/BEA reaches 36μmol/g in the feed gas close to realistic exhaust conditions,and the NO_(x) desorption temperature,which is around 290℃,is ideal for diesel exhaust after-treatment systems.Ce/BEA also behaves notable stability of high temperature CO exposure conditions.Multiple characterizations were performed to explore the NO_(x) adsorption chemistry of Ce/BEA.The Ce(Ⅳ)species in the BEA zeolite serves as the active center for NO_(x) adsorption.The bidentate nitrate species is responsible for the observed NO_(x) storage capacity,and the active oxygen around Ce(Ⅳ)plays a critical role in its formation.Considering the significantly better cost efficiency of Ce compared to Pd,Ce/BEA presents an enormous potential for the PNA applications and provides a novel formulation for the noblemetal choice of PNA materials.展开更多
Due to the technology limitation and inferior deNO_(x) efficiency of urea selective catalytic reduction (SCR) catalysts at low temperatures, passive NO_(x) adsorber (PNA) for decrease of NO_(x), CO and hydrocarbons (H...Due to the technology limitation and inferior deNO_(x) efficiency of urea selective catalytic reduction (SCR) catalysts at low temperatures, passive NO_(x) adsorber (PNA) for decrease of NO_(x), CO and hydrocarbons (HCs) during “cold start” of vehicles was proposed to meet the further tighten NO_(x) emission regulations in future. Among them, Pd modified zeolite PNA materials have received more attention because of their excellent NO_(x) storage capacity, anti-poisoning and hydrothermal stability and since Pd/zeolite PNA was proposed, a variety of advanced characterization methods have been applied to investigate its adsorption behavior and structure-performance relationship. The comprehension of the active sites and adsorption chemistry of Pd/zeolite PNA was also significantly improved. However, there are few reviews that systematically summarize the recent progress and application challenges in atomic-level understanding of this material. In this review, we summarized the latest research progress of Pd/zeolite PNA, including active adsorption sites, adsorption mechanism, material physicochemical properties, preparation methods, storage and release performance and structure-performance relationships. In addition, the deactivation challenges faced by Pd/zeolite PNA in practical applications, such as chemical poisoning, high temperature hydrothermal aging deactivation, etc., were also discussed at the micro-level, and some possible effective countermeasures are given. Besides, some possible improvements and research hotspots were put forward, which could be helpful for designing and constructing more efficient PNA materials for meeting the ultra-low NO_(x) emission regulation in the future.展开更多
文摘时差定位(Time Difference of Arrival,TDOA)是一种广泛应用的被动定位技术,具有定位精度高、组网能力强、系统鲁棒性强等特点。针对运动目标定位计算复杂、精度收敛较慢等问题,在给出视距(Line of Sight,LOS)环境下定位模型的基础上,提出了定位适用于多站时差定位系统的定位方法,该方法将组群时差定位关系方程合理地线性化为统计估计问题,利用在线迭代实时求解目标位置。给出了针对目标不同运动特性条件下的多平台协同定位算法及其仿真结果,仿真结果表明所述方法可以实现对目标的精确定位,并且分析了运动形式对于定位精度的影响,仿真结果对于系统的工程设计具有指导作用。
基金supported by the National Key Research and Development Program(No.2016YFB0800602)National Natural Science Foundation of China(NSFC)(No.61502048)Shandong provincial Key Research and Development Program of China(2018CXGC0701,2018GGX106005)
文摘Modern cars are mostly computerized and equipped with passive keyless entry and start(PKES) system. PKES is based on Radio Frequency Identification(RFID) technology for authentication of the authorized drivers. RFID technology has replaced the conventional ways of identification and authorization in order to facilitate users while introducing new security challenges. In this article, we focused on verifying the presence of authorized key in the physical proximity of car by employing multiple antennas. Application of multiple antennas to the currently developed cryptographic algorithms opens a new approach for researchers to improve security of RFID based systems. We propose an advanced security system for PKES using multiple antennas wherein an authorized key passes through multiple vicinities to allow driver to access and start the car. Furthermore, we modified a light-weight cryptographic protocol named as HB(Hopper and Blum) protocol to integrate it with the proposed design based on multiple antennas. Simulation results show improvement in security functionality while keeping in view the efficiency constraints.
基金supported by the National Key R&D Program of China(2021YFB3503200)the Major Science and Technology Programs of Yunnan Province(202002AB080001-1)。
文摘Passive NO_(x) adsorbers(PNAs)were proposed to address the NO_(x) emissions during the cold start phase.Here we show a novel Ce-based BEA zeolite,as a noble-metal-free passive NO_(x)adsorber.The NO_(x) adsorption capacity of Ce/BEA reaches 36μmol/g in the feed gas close to realistic exhaust conditions,and the NO_(x) desorption temperature,which is around 290℃,is ideal for diesel exhaust after-treatment systems.Ce/BEA also behaves notable stability of high temperature CO exposure conditions.Multiple characterizations were performed to explore the NO_(x) adsorption chemistry of Ce/BEA.The Ce(Ⅳ)species in the BEA zeolite serves as the active center for NO_(x) adsorption.The bidentate nitrate species is responsible for the observed NO_(x) storage capacity,and the active oxygen around Ce(Ⅳ)plays a critical role in its formation.Considering the significantly better cost efficiency of Ce compared to Pd,Ce/BEA presents an enormous potential for the PNA applications and provides a novel formulation for the noblemetal choice of PNA materials.
基金financial support from the National Natural Science Foundation of China (No. 52000084)the China Postdoctoral Science Foundation (No. 2019M662630)National Engineering Laboratory for Mobile Source Emission Control Technology (No. NELMS2018A08)。
文摘Due to the technology limitation and inferior deNO_(x) efficiency of urea selective catalytic reduction (SCR) catalysts at low temperatures, passive NO_(x) adsorber (PNA) for decrease of NO_(x), CO and hydrocarbons (HCs) during “cold start” of vehicles was proposed to meet the further tighten NO_(x) emission regulations in future. Among them, Pd modified zeolite PNA materials have received more attention because of their excellent NO_(x) storage capacity, anti-poisoning and hydrothermal stability and since Pd/zeolite PNA was proposed, a variety of advanced characterization methods have been applied to investigate its adsorption behavior and structure-performance relationship. The comprehension of the active sites and adsorption chemistry of Pd/zeolite PNA was also significantly improved. However, there are few reviews that systematically summarize the recent progress and application challenges in atomic-level understanding of this material. In this review, we summarized the latest research progress of Pd/zeolite PNA, including active adsorption sites, adsorption mechanism, material physicochemical properties, preparation methods, storage and release performance and structure-performance relationships. In addition, the deactivation challenges faced by Pd/zeolite PNA in practical applications, such as chemical poisoning, high temperature hydrothermal aging deactivation, etc., were also discussed at the micro-level, and some possible effective countermeasures are given. Besides, some possible improvements and research hotspots were put forward, which could be helpful for designing and constructing more efficient PNA materials for meeting the ultra-low NO_(x) emission regulation in the future.
