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MANTLE SOURCE NATURE OF ORE FLUIDS FOR THE JINDING Pb-Zn DEPOSIT, LANPING, YUNNAN 被引量:2
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作者 Zhang Lisheng, Yu Qian, Mou Chuanlong 《地学前缘》 EI CAS CSCD 2000年第S1期419-420,共2页
Geological setting\;Jinding superlarge Pb\|Zn deposit lies in the Lanping basin between the Lancangjiang fracture zone and the Jinshajiang\|Ailaoshan fracture zone. The Lanping basin is a Meso\|Cenozoic rifting basin ... Geological setting\;Jinding superlarge Pb\|Zn deposit lies in the Lanping basin between the Lancangjiang fracture zone and the Jinshajiang\|Ailaoshan fracture zone. The Lanping basin is a Meso\|Cenozoic rifting basin whose basement consists of the Paleozoic strata. Mesozoic paralic and continental sediments with a thickness of about 20000m deposited in the basin. In the Paleocene, gypsum\|salt\|bearing strata with a thickness of more than 1000m accumulated. In the Cenozoic, collision of the Indian plate with the Eurasian plate resulted in strong folding and napping and subsequent extensions in the Oligocene and Pliocene. The extensions were responsible for alkaline magmatic intrusion in the centre and alkaline magmatic extrusion in the east.Faulting is well developed. N\|S\|trending Bijiang fault with a length of 120km links with the Jinshajiang fracture zone in the north and with the Lancangjiang fracture zone in the south, controlling on the Cenozoic Lanping rifting basin and acting as passage\|way for ore fluids. 展开更多
关键词 JINDING pb\|zn DEPOSIT MANTLE source ore fluid
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Characteristics of the ore-forming fluid in the Huayuan Pb-Zn ore filed, Northwest of Hunan Province, China
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作者 WEI Hantao SHAO Yongjun +2 位作者 ZHOU Haodi WANG Cheng XIONG Yiqu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第S1期239-240,共2页
1 Geological Setting The Huayuan Pb-Zn ore field in Xiangxi is located in the southeastern margin of the Yangtze block and the mid-segment of the West Hunan-West Hubei metallogenic belt.The exposed stratum are the lower
关键词 Characteristics of the ore-forming fluid in the Huayuan pb-zn ore filed China Northwest of Hunan Province REE pb Cl zn
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The Forming Conditions of and Ore-searching Direction for B, Mg,Pb, Zn and Au Deposits in the Liaoji Proterozoic Rift
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作者 Zhu Yongzheng and Yao Fengliang (College of Earth Sciences,Jilin University, Changchun 130026 P. R. China) 《Global Geology》 2001年第1期20-25,共6页
The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These d... The Liaoji Proterozoic rift is an inter-intracontinenatl rift developed from Archean granite-greenstone tectonic regime and contains many important mineral deposits of U, B, magnesite, Pb-Zn, Au, Ag, Co and P. These deposits were formed as the result of late mobilization, transportation and concentfation of the previously enriched ore-forming mate- rials in several ore-bearing formations formed during the rift stage. So the metallogeny of these deposits in the rift shows both inheritance and new generation of the ore-forming materials. In future ore-searching practice, attentions should be paid on the studies of the ore-bearing formations in the rift, on the multiple stages of metallogeny and and on multiple derivations of the ore-forming materials. 展开更多
关键词 Liaoji PROTEROZOIC rift B Mg pb - zn AU deposits ore - forming conditions ore - SEARCHING direction
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0.91Pb(Zn_(1/3)Nb_(2/3)O_3-0.09PbTi0_3的析晶行为及助溶剂法生长 被引量:6
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作者 徐家跃 范世(?) 孙仁英 《硅酸盐学报》 EI CAS CSCD 北大核心 2002年第6期721-724,共4页
研究了0.91Pb(znl/3Nb2/3)O3-0.09PbTiO3(PZNT91/9,摩尔分数)在不同组分和配比熔盐中的析晶行为及其对晶体生长的影响。发现B2O3,PbF2等助溶剂不利于钙钛矿相的析出;而BaTiO3-PbO复合体系虽然能够促进钙钛矿相析出,但晶体析出量很少;只... 研究了0.91Pb(znl/3Nb2/3)O3-0.09PbTiO3(PZNT91/9,摩尔分数)在不同组分和配比熔盐中的析晶行为及其对晶体生长的影响。发现B2O3,PbF2等助溶剂不利于钙钛矿相的析出;而BaTiO3-PbO复合体系虽然能够促进钙钛矿相析出,但晶体析出量很少;只有适当比例的。PbO助溶剂比较适合于生长具有铁电性的钙钛矿相PZNT91/9单晶。助溶剂法生长的工艺参数为:溶质与PbO助溶剂的摩尔比为l:l,泡料温度1 150-1 200℃,泡料时间10 h,晶体生长时降温速度0.8-2℃/h,当温度降到900℃时停止生长,以50℃/h快速冷却至室温。所得晶体为琥珀色,最大尺寸达φ30 mm×15 mm,其压电系数和机电偶合系数分别为2000 pc/N和0.92。 展开更多
关键词 0.91pb(zn1/3Nb2/3)O3-0.09pbTiO3 析晶行为 助溶剂法 铌锌钛酸铅 钙钛矿相 晶体生长
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[001]c极化0.93Pb(Zn_(1/3)Nb_(2/3))O_3-0.07PbTiO_3单晶中声表面波传播特性
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作者 李秀明 吴广涛 +2 位作者 徐权 张锐 李玉春 《人工晶体学报》 EI CAS CSCD 北大核心 2015年第5期1222-1226,1253,共6页
利用室温下弛豫铁电单晶0.93Pb(Zn1/3Nb2/3)O3-0.07PbTiO3的材料参数,计算了[001]c极化PZN-7%PT晶体中的声表面波传播特性。结果表明,[001]c极化0.93Pb(Zn1/3Nb2/3)O3-0.07Pb TiO3单晶具有明显优于传统压电材料的声表面波特性。0.93Pb(Z... 利用室温下弛豫铁电单晶0.93Pb(Zn1/3Nb2/3)O3-0.07PbTiO3的材料参数,计算了[001]c极化PZN-7%PT晶体中的声表面波传播特性。结果表明,[001]c极化0.93Pb(Zn1/3Nb2/3)O3-0.07Pb TiO3单晶具有明显优于传统压电材料的声表面波特性。0.93Pb(Zn1/3Nb2/3)O3-0.07Pb Ti O3单晶的声表面波特性随着传播方向发生明显的变化。综合考虑晶体的三种声表面波特性,发现Y切型晶体的综合声表面波性能最好,声表面波机电耦合系数k2值较大,能流角和声表面波自由表面相速度值较小,有望应用于下一代低频声表面波设备中。 展开更多
关键词 0.93pb(zn1/3Nb2/3)O3-0.07pbTiO3 声表面波 机电耦合系数
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丙烯酸-马来酸酐共聚物络合超滤分离水溶液中Pb^(2+)和Zn^(2+)的实验研究 被引量:1
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作者 曹光亮 李振山 包立超 《北京大学学报(自然科学版)》 EI CAS CSCD 北大核心 2014年第3期542-548,共7页
采用丙烯酸-马来酸酐共聚物(PMA)为络合剂,研究络合超滤技术对水溶液中Pb2+和Zn2+的分离效果、竞争络合效应以及外加盐对分离效果的影响。以两种金属离子截留率之差表示分离率,以单一金属离子溶液中离子截留率与混合溶液中该离子的截留... 采用丙烯酸-马来酸酐共聚物(PMA)为络合剂,研究络合超滤技术对水溶液中Pb2+和Zn2+的分离效果、竞争络合效应以及外加盐对分离效果的影响。以两种金属离子截留率之差表示分离率,以单一金属离子溶液中离子截留率与混合溶液中该离子的截留率之差表示金属离子间的竞争强度。结果表明:随着PMA浓度增加,两种金属离子的分离率先增大后减小,当PMA浓度为200 mg/L时,分离率达到最大值,为54.47%。pH从2增加到6时,分离率先增大后减小,且在pH=4时达到最大,为71.34%。两种金属离子的竞争效应随pH及PMA浓度的增加先增强后减弱,在pH=5,PMA浓度为200 mg/L时,混合溶液中两种离子竞争效应最强。外加Na2SO4对分离率有较大影响,随着n(Na2SO4)增大分离率增加,随后基本保持不变,在n(Na2SO4)=0.06mol/L时,分离率达到最大值,为97.677%。加入Na2SO4减弱了Zn2+的竞争络合能力,有利于两种金属离子的分离。 展开更多
关键词 pb2+ zn2+ 丙烯酸-马来酸酐共聚物 超滤 选择性分离 竞争络合
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Genesis of the Maoping carbonate-hosted Pb–Zn deposit,northeastern Yunnan Province,China:evidences from geology and C–O–S–Pb isotopes 被引量:3
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作者 Yufan He Tao Wu +3 位作者 Zhilong Huang Lin Ye Ping Deng Zhenzhong Xiang 《Acta Geochimica》 EI CAS CSCD 2020年第5期782-796,共15页
The Maoping Pb-Zn deposit(~3 Mt Pb+Zn reserves with grades of 12-30 wt%)is one of the largest Pb-Zn deposits in the Sichuan-Yunnan-Guizhou(SYG)metallogenic province,which has contributed a tremendous amount of lead an... The Maoping Pb-Zn deposit(~3 Mt Pb+Zn reserves with grades of 12-30 wt%)is one of the largest Pb-Zn deposits in the Sichuan-Yunnan-Guizhou(SYG)metallogenic province,which has contributed a tremendous amount of lead and zinc resources for China.To obtain a further understanding of the sources of ore-forming materials and ore genesis of the deposit,S-Pb isotopes of sulfides and C-O isotopes of ore-stage calcites were systematically collected from representative orebodies at different elevations with a Finnigan MAT-253 mass spectrometer.The calcites separated from the sulfides of the NoⅠand NoⅡorebodies shared identical b13 CPDB values(-5.3 to-0.8‰)andδ18OSMOW values(+14.5 to+21.8‰)with those of the calcites in the SYG region,suggesting that CO2 in regional ore-forming fluids possibly had a homologous C-O source that originated from a ternary mixture of the dissolution of marine carbonate rocks,degassing process of the Emeishan mantle plume,and dehydroxylation of sedimentary organic matter.The No.Ⅰ-1 and No.Ⅰ-2 orebody was hosted in the same strata,but the sulfur source of No.Ⅰ-1 orebody(+13.1 to+19.0‰)with equilibrated sulfur fractionation(δ34Sspbaierite-<δ34Sgalena)and No.Ⅰ-2 orebody(+18.0 to+21.8‰)with sulfur equilibrium fractionation(δ34Sspnaierite>δ34-Sgalena)were different.They were derived from the allopatry thermochemical sulfate reduction(TSR)of overlying Carboniferous sulfates in the ore-hosting strata and local TSR of sulfates in the ore-bearing Upper Devonian Zaige Formation,respectively.The narrow and uniform Pb isotopic ratios of single galena grains collected from sulfides with 206Pb/204Pb of 18.713-18.759,207Pb/204Pb of 15.772-15.776 and 208Pb/204Pb of39.383-39.467 indicate a well-mixed metal source(s)that consist of Proterozoic Kunyang and Huili Group basement rocks and Devonian to Middle Permian ore-hosting sedimentary rocks.Besides,the late Permian Emeishan basalts are difficult to contribute metals for regional Pb-Zn mineralization despite a closely spatial relationship with the distribution of the Pb-Zn deposit.This is supported by Pb isotopic ratios plotting above the average upper crustal Pb evolution curves and staying far away from that of the agecorrected Emeishan basalts.Hence,taking into account of the similarities in tectonic setting,ore-hosting rock,ore assemblage,wall rock alteration,ore-controlling structure,and ore-forming materials and the differences in relationship with regional magmatism,fluid inclusion characteristic and ore grade between the Maoping deposit and typical MVT Pb-Zn deposit,the ore genesis of the Maoping deposit should be an MVT like Pb-Zn deposit. 展开更多
关键词 Maoping pbzn deposit ore-forming materials ore genesis MVT-like deposit
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甘肃厂坝-李家沟超大型铅锌矿床成矿金属来源——来自闪锌矿原位S-Pb和Zn同位素证据
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作者 魏然 王义天 +3 位作者 胡乔青 黄诗康 窦平 胡文荣 《矿床地质》 CAS CSCD 北大核心 2022年第4期722-740,共19页
甘肃厂坝-李家沟铅锌矿床位于西秦岭多金属成矿带内的西成矿集区,为矿集区内重要的超大型铅锌矿床。矿体赋存在中泥盆统安家岔组的白云石化大理岩及石英片岩中,其成因认识一直存在争议,主要分歧集中在是同生还是后生。文章对不同成矿阶... 甘肃厂坝-李家沟铅锌矿床位于西秦岭多金属成矿带内的西成矿集区,为矿集区内重要的超大型铅锌矿床。矿体赋存在中泥盆统安家岔组的白云石化大理岩及石英片岩中,其成因认识一直存在争议,主要分歧集中在是同生还是后生。文章对不同成矿阶段的闪锌矿,采用多接收电感耦合等离子体质谱(MC-ICP-MS)测定Zn同位素组成、采用激光剥蚀-多接收电感耦合等离子体质谱(LA-MC-ICP-MS)原位微区分析技术测定S、Pb同位素组成,示踪成矿物质来源,并分析矿物沉淀机制,为深入理解矿床成因提供新的精细证据。研究结果显示,Ⅰ、Ⅱ、Ⅲ三个成矿阶段闪锌矿的δ^(66)Zn分别为0.08‰~0.29‰,平均0.20‰;0.19‰~0.37‰,平均0.30‰;0.36‰~0.37‰,平均0.37‰。其中,Ⅰ阶段的闪锌矿δ^(34)SⅠ值为20.9‰~26.1‰,平均24.4‰;Ⅱ阶段的闪锌矿δ^(34)SⅡ值为12.2‰~21.9‰,平均19.1‰;Ⅲ阶段的闪锌矿δ^(34)SⅢ值为18.2‰~24.7‰,平均21.5‰。3个阶段的矿石矿物Pb同位素组成变化不大,^(206)Pb/^(204)Pb为17.922~18.013,^(207)Pb/^(204)Pb为15.567~15.647,^(208)Pb/^(204)Pb为37.990~38.266。δ^(66)Zn同位素值显示,成矿金属早期来源于围岩海相碳酸盐岩,由于混合了岩浆热液或者是瑞利分馏作用,在成矿作用中后期δ^(66)Zn同位素逐渐上升。δ^(34)S同位素值显示,早期硫源主要为地层中的硫酸盐,中后期的δ^(34)S同位素值降低,可能是成矿流体中岩浆热液中的S^(2-)成分逐渐增多导致,闪锌矿为硫酸盐通过TSR反应沉淀成矿。Pb同位素指示成矿物质来源于上地壳,并混入了部分古老的变质基底的成分。笔者研究发现,厂坝-李家沟铅锌矿的成矿机制为不同来源的流体混合,随着pH值、成矿流体的温度发生变化而沉淀成矿。 展开更多
关键词 地球化学 闪锌矿 zn同位素 原位S同位素 原位pb同位素 沉淀机制 厂坝-李家沟铅锌矿床
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Geochronology and geochemistry of magmatic rocks in the Dongzi–Changhanboluo Pb–Zn ore district in Chifeng,Inner Mongolia,and their relationship with metallogenesis
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作者 Hongjing Xie Yuwang Wang +2 位作者 Yunguo Zhang Wei Jiang Zhiyuan Sun 《Acta Geochimica》 EI CAS CSCD 2020年第5期668-697,共30页
Bulk-rock elements,isotopes,and zircon U–Pb ages are reported for magmatic rocks in the Dongzi–Changhanboluo Pb–Zn ore district in Chifeng,Inner Mongolia,China.Zircon U–Pb dating identified four stages of magmatis... Bulk-rock elements,isotopes,and zircon U–Pb ages are reported for magmatic rocks in the Dongzi–Changhanboluo Pb–Zn ore district in Chifeng,Inner Mongolia,China.Zircon U–Pb dating identified four stages of magmatism:Late Silurian gabbroic diorite(*420 Ma),Middle Permian monzonite(*274 Ma),Late Jurassic quartz porphyry and ignimbrite,breccia tuff(153–158 Ma)and Early Cretaceous andesitic porphyrite(*127 Ma).Integrating field observations,geochronology,and element and isotope geochemistry indicated a complex petrogenetic history of the magmatic rocks.The gabbroic diorite may have been sourced from EM1-type mantle.The source of the monzonite may have been mantle metasomatized by melt from the subducting plate.The Jurassic volcaniclastic rocks formed in a medium-pressure,high-temperature environment,possibly in the background of crustal thickening in a syncollisional stage and an early postcollisional stage.During this process,shaly sedimentary rocks were brought into the deep crust and heated,followed by the rapid isostatic uplift of the crust,which caused partial melting of the sedimentary rocks.Quartz monzonite porphyry and quartz porphyry formed by partial melting of mantle metasomatized by subducted sediments,but the quartz porphyry experienced high-degree differentiation and evolution.The andesitic porphyrite has characteristics similar to those of Permian monzonite,indicating that its source area was also the zone of mantle metasomatized by subducted sediment.The late Silurian and Permian magmatic rocks in this area most likely formed against a continental arc background related to the subduction of the Paleo-Asian Ocean Plate beneath the North China Plate.The Late Jurassic magmatic rocks suggest that the northern margin of the North China Craton may have been in a postcollisional setting during the Late Jurassic,with no obvious crustal thinning.The Cretaceous andesitic porphyrite may have formed against the background of lithospheric extension and thinning.According to the comprehensive analysis of geological characteristics,diagenetic and metallogenic epochs,and Pb isotope data,the formation of ore bodies in the Dongzi–Changhanboluo ore district was closely related to the Jurassic quartz porphyry. 展开更多
关键词 pbzn ore district Chifeng Zircon U–pb dating Sr–Nd–pb isotope Relationship with metallogenesis
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pH和Cu^(2+)Zn^(2+)对两种可变电荷土壤中吸附态Pb解吸行为的影响 被引量:10
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作者 杨金燕 杨肖娥 +3 位作者 何振立 李廷强 章明奎 申屠佳丽 《农业环境科学学报》 CAS CSCD 北大核心 2005年第3期469-475,共7页
采用连续解吸法对两种可变电荷土壤中吸附态Pb的解吸行为进行研究。结果表明,红砂土和黄筋泥的Pb2+吸附量和解吸量都随Pb2+加入量的增加而增加。红砂土和黄筋泥对Pb的吸附等温线可用Langmuir模型来描述,最大吸附量(Xm)分别为10899和6195... 采用连续解吸法对两种可变电荷土壤中吸附态Pb的解吸行为进行研究。结果表明,红砂土和黄筋泥的Pb2+吸附量和解吸量都随Pb2+加入量的增加而增加。红砂土和黄筋泥对Pb的吸附等温线可用Langmuir模型来描述,最大吸附量(Xm)分别为10899和6195mg·kg-1。pH对吸附态Pb的解吸影响较大,解吸量随pH升高而降低。当pH≤2.00时2种土壤吸附态Pb2+的解吸率很高,接近100%;当pH由2.00上升至4.00时,解吸率呈直线下降;至pH>4.00时2种土壤吸附态Pb2+的解吸率均降至很低的水平。Cu2+和Zn2+的加入可增加土壤吸附态Pb2+的解吸,其中Cu2+对Pb2+解吸作用较Zn2+大。铜加入量从0到20mmol·L-1,红砂土和黄筋泥吸附Pb2+的解吸率分别从9.6%和15.9%增加到83.8%和98.2%,锌加入量从0到20mmol·L-1,2种土壤吸附Pb2+的解吸率则分别增加到81.2%和89.9%。 展开更多
关键词 pb CU zn PH 可变电荷土壤 吸附-解吸
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与长途输送和当地污染物排放有关的大气悬浮物中的Cd/Pb和Zn/Pb比例特征(英文)
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作者 Shih-Chieh Hsu Shaw Chen Liu Ru-Ting Hsu 《干旱区资源与环境》 CSSCI CSCD 2004年第S1期97-103,共7页
Along with windblown dust, large quantities of pollutants are annually brought out of the continental by the westerlies in winter and spring; thereafter they are partly subjected to transport by northeastern monsoon w... Along with windblown dust, large quantities of pollutants are annually brought out of the continental by the westerlies in winter and spring; thereafter they are partly subjected to transport by northeastern monsoon winds to Taiwan. Both PM10 and PM2.5 aerosols collected from northern Taiwan from February 2002 to March 2003 were determined for three heavy metals, namely Pb, Cd and Zn, to characterize the heavy metal compositions between long-range transported and local aerosols and to evaluate their contributions of long-range transport during the northeastern monsoon season. Low Cd/Pb (0.017) and Zn/Pb (1.82) ratios were measured in aerosols during the Asian dust period, in which the sources of ambient aerosols are dominated by long-range transport. By contrast, high Cd/Pb(0.030) and Zn/Pb (3.44) ratios were measured during the summer monsoon season, in which local pollutant emissions dominate the sources of heavy metals. Such characteristic Cd/Pb and Zn/Pb ratios appear to be successfully applied to identify the pollutants originated from the long-range transport or local emissions. 展开更多
关键词 污染物排放 大气悬浮物 pbzn 英文 长途 PM2.5-10 ICP-MS Regression SPATIAL HighC
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咪唑-菲咯啉-苯氧乙酸锌、铅配合物的合成,结构及与DNA的相互作用(英文) 被引量:4
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作者 沈伟 胡未极 +1 位作者 吴小勇 赵国良 《无机化学学报》 SCIE CAS CSCD 北大核心 2016年第6期1101-1110,共10页
以2-4-(1H-咪唑-2-[4,5-f][1,10]菲咯啉基)苯氧乙酸(HPIMPHC)和2-2-(1H-咪唑-2-[4,5-f][1,10]菲咯啉基)苯氧乙酸(HOIMPHC)为配体,水热合成了2种新型配合物[Zn(PIMPHC)_2]_n(1)和{[Pb(OIMPHC)_2]·4H_2O}_n(2)。配合物1属正交晶系,... 以2-4-(1H-咪唑-2-[4,5-f][1,10]菲咯啉基)苯氧乙酸(HPIMPHC)和2-2-(1H-咪唑-2-[4,5-f][1,10]菲咯啉基)苯氧乙酸(HOIMPHC)为配体,水热合成了2种新型配合物[Zn(PIMPHC)_2]_n(1)和{[Pb(OIMPHC)_2]·4H_2O}_n(2)。配合物1属正交晶系,空间群为Pbcn;Zn(Ⅱ)的配位数为6,配位构型为变形的八面体,形成2D网状结构。配合物2属单斜晶系,空间群为P21/n;Pb(Ⅱ)的配位数为7,配位构型为变形的五角双锥,形成2D网状结构。荧光光谱的结果表明,配合物与DNA的相互作用强于配体。 展开更多
关键词 2-4-(1H-咪唑-2-[4 5-f][1 10]菲咯啉基)苯氧乙酸 2-2-(1H-咪唑-2-[4 5-f][1 10]菲咯啉基)苯氧乙酸 zn(Ⅱ) pb(Ⅱ) DNA作用
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ICP-AES测定多目标水地球化学普查样品中的14种微量元素 被引量:4
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作者 程泽 阿拉木斯 +1 位作者 苏金华 谭玉娟 《光谱实验室》 CAS CSCD 2006年第1期130-132,共3页
采用IRIS Intrepid II SXP ICP光谱仪,对地球化学普查水样中Ba、Be、Cd、Co、Cr、Cu、Fe、 Mn、Mo、Ni、P、Pb、Sr和Zn等元素的测量条件进行了探讨,优化了实验条件,进行了大批量实际样品的测定。方法简便,快速。检出限、精密度和准确度... 采用IRIS Intrepid II SXP ICP光谱仪,对地球化学普查水样中Ba、Be、Cd、Co、Cr、Cu、Fe、 Mn、Mo、Ni、P、Pb、Sr和Zn等元素的测量条件进行了探讨,优化了实验条件,进行了大批量实际样品的测定。方法简便,快速。检出限、精密度和准确度均符合质量管理的要求。 展开更多
关键词 电感耦合等离子体-原子发射光谱法 地球化学普查水 BA Bo Cd Co Cr Cu Fe Mn MO Ni P pb Sr zn
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The genetic relationship between Habo alkaline intrusion and its surrounding deposits, Yunnan Province, China: geological and S–Pb isotopic evidences 被引量:1
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作者 Zhongneng Meng Qian Zhang +3 位作者 Lin Ye Yupin Liu Jiangbo Lan Dapeng Wang 《Acta Geochimica》 EI CAS CSCD 2016年第4期391-407,共17页
The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits ... The Habo alkaline intrusion, which is located in the south of the Sanjiang area, Yunnan Province, China, is a typical Cenozoic alkaline intrusion. There are a series of small to medium-sized Au and Pb-(Zn) deposits around this intrusion. Those deposits are spatially associated with the Habo alkaline intrusion. (1) The δ^34S values of sulfides from Au deposits range from -1.91‰ to 2.69 ‰, which are similar to those of Pb-(Zn) deposits (-3.82 ‰ to -0.05 ‰) and both indicate a much greater contribution from magma. (2) The Habo alkaline intrusion has relatively homogeneous Pb isotopic compositions with ^206pb/^204pb ranging from 18.608 to 18.761, ^207pb/^204pb from 15.572 to 15.722 and ^20spb/^204pb from 38.599 to 39.110. These Pb isotope ratios are similar to those of Au deposits, whose ^206pb/^204pb range from 18.564 to 18.734, ^20Tpb/^20apb from 15.582 to 15.738 and ^208pb/^204pb from 38.592 to 39.319. Pb ratios in both the intrusion and Au deposits suggest that Pb mainly derived from the depth, probably represents a mixture of mantle and crust. Pb-(Zn) deposits, however, show a decentralized trait, and most of them are similar to that of the alkaline intrusion with ^206pb/^204pb ranging from 18.523 to 18.648, ^207pb/^204pb from 15.599 to 15.802, and ^20spb/^204pb from 38.659 to 39.206. (3) In the plumbotectonic diagram ^20Tpb/^204pb versus ^206pb/^204pb, almost all of Au and Pb-(Zn) deposits have the same projection area with the Habo alkaline intrusion, which indicates that those deposits almost share the same source with the alkaline intrusion. (4) Isotopic age of the Habo alkaline intrusion is 36-33 Ma, which is similar to that of Beiya, whose ore- related alkaline porphyries age is 38-31 Ma and molybdenite Re-Os age is 36.9 Ma. Therefore, along with S-Pb isotope traits, we suggest that the Habo Au and Pb-(Zn) deposits should be typically Ailaoshan-Red RiverCenozoicalkaline-related deposits and ore-forming ages of these deposits should be later than that of the Habo alkaline intrusion. 展开更多
关键词 The Habo Au and intrusion ore genesis S-pb materials pb-zn deposits - Alkaline isotope analyses - Source
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0.2Pb(Zn_(1/3)Nb_(2/3))O_3-0.8Pb(Zr_(0.5),Ti_(0.5))O_3(1-x)(Ni_(51.5)Mn_(25)Ga_(23.5))x固溶体系磁电性能研究
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作者 仲麒 张铭 +5 位作者 邓浩亮 郑木鹏 胡州 侯育冬 朱满康 严辉 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2013年第S1期201-203,共3页
采用传统的固相烧结法合成了0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3(1-x)(Ni51.5Mn25Ga23.5)x复合体系陶瓷。XRD结果表明,随着Ni51.5Mn25Ga23.5(NMG)掺入,Ni51.5Mn25Ga23.5先溶于0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3中,后NMG... 采用传统的固相烧结法合成了0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3(1-x)(Ni51.5Mn25Ga23.5)x复合体系陶瓷。XRD结果表明,随着Ni51.5Mn25Ga23.5(NMG)掺入,Ni51.5Mn25Ga23.5先溶于0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3中,后NMG量超过5%不溶于复合体系中,使得0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3的峰位向右偏移;铁电性能测试结果表明,0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3(1-x)(Ni51.5Mn25Ga23.5)x复合体系陶瓷随着Ni51.5Mn25Ga23.5的掺入量的增加矫顽场E先降低后增加,剩余极化强度Pr逐渐降低,这与XRD的测试结果相一致;磁性测试结果表明,0.2Pb(Zn1/3Nb2/3)O3-0.8Pb(Zr0.5,Ti0.5)O3(1-x)(Ni51.5Mn25Ga23.5)x随着Ni51.5Mn25Ga23.5掺入量的增加,以独立相析出在复合体系中,剩余磁化强度Mr逐渐增大。 展开更多
关键词 0.2pb(zn1/3Nb2/3)O3-0.8pb(Zr0.5 Ti0.5)O3 Ni51.5Mn25Ga23.5 固相烧结 复合材料
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弛豫铁电体结构起伏与弛豫性研究
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作者 张栋杰 姚熹 《化学学报》 SCIE CAS CSCD 北大核心 2005年第12期1095-1099,i003,共6页
制备了铅基弛豫铁电体0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3和Pb(Zn1/3Nb2/3)O3基陶瓷.铅基弛豫铁电体PMNT,PZN基陶瓷弛豫过程可用局域冻结模型描述.在微畴-宏畴转变过程中,弛豫铁电体产生结构起伏;在相同的频率条件下,弛豫铁电体的结构起伏... 制备了铅基弛豫铁电体0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3和Pb(Zn1/3Nb2/3)O3基陶瓷.铅基弛豫铁电体PMNT,PZN基陶瓷弛豫过程可用局域冻结模型描述.在微畴-宏畴转变过程中,弛豫铁电体产生结构起伏;在相同的频率条件下,弛豫铁电体的结构起伏程度越大,弛豫程度越低.在微畴-宏畴转变过程中,随微畴的增大,弛豫铁电体的弛豫特性减弱或消失. 展开更多
关键词 pb(zn1/3NB2/3)O3 起伏 体结构 弛豫铁电体 Pzn基陶瓷 转变过程 微畴-宏畴 PMNT 模型描述 弛豫过程 频率条件 铅基
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