通过对东北地区污染农田黑土剖面的取样调查分析,对重金属Cd、Pb、Cu、Zn在农田黑土中的污染状况及其迁移特征进行了对比研究,并就BCR(the Comm un ity Bureau of R eference)连续提取法在农田土壤重金属污染评估中的应用进行了探讨。...通过对东北地区污染农田黑土剖面的取样调查分析,对重金属Cd、Pb、Cu、Zn在农田黑土中的污染状况及其迁移特征进行了对比研究,并就BCR(the Comm un ity Bureau of R eference)连续提取法在农田土壤重金属污染评估中的应用进行了探讨。结果表明,重金属的迁移率大小依次为:Cd>Cu>Pb>Zn,Cd的酸可溶态占全量的比率高于其它重金属。Pb的酸可提取态浓度随土壤深度增加而增大,公路附近土壤中Pb、Cu及城市郊区土壤中Cd、Pb和Zn的氧化物结合态含量均随土壤深度的增加而升高,已存在向下迁移的趋势。4种重金属有机结合态在采样区土壤中基本都表现为耕层高于非耕层。研究表明,应用BCR连续提取法有助于确定土壤重金属污染以及重金属向下迁移状况,借助该法可以有效、可靠地对土壤重金属污染进行评估。展开更多
Reconstruction of trace metal pollution histories and sources may help us to regulate current pollutant discharge. This is especially important for the highland lakes in southwestern China, which are facing trace meta...Reconstruction of trace metal pollution histories and sources may help us to regulate current pollutant discharge. This is especially important for the highland lakes in southwestern China, which are facing trace metals pollution. We present sedimentary records of 11 metals accumulated in Yangzong Lake since the 1870＇s, a highland lake in southwestern China. Pollution of lead and zinc （Pb and Zn） was differentiated based on principal component analysis, geochemical normalization, and lead isotope ratios. Nearly all the metals as well as grain size composition show generally constant values before the mid-1980＇s, denoting stable detrital input in the catchment. Fluctuations in the concentrations of the metals as well as grain size composition since the mid-1980＇s indicate an increase in soil erosion with strengthened human disturbance in the catchment. After geochemical normalization, Pb and Zn showed constant values before 1990 AD and then a gradual increase in parallel with the variations in 2~spb/~~6pb and 2~7pb/2~6pb ratios, indicating that Pb and Zn pollution occurred. Combining the data of 20PPb/206Ppb and 207Pb/206Pb ratios in the sediments of Yangzong Lake, leaded gasoline, Pb-Zn ore and coal, and consumption or production historical trends, we deduced that the enhanced Pb and Zn pollution in Yangzong Lake is caused primarily by ore mining and refining.展开更多
文摘通过对东北地区污染农田黑土剖面的取样调查分析,对重金属Cd、Pb、Cu、Zn在农田黑土中的污染状况及其迁移特征进行了对比研究,并就BCR(the Comm un ity Bureau of R eference)连续提取法在农田土壤重金属污染评估中的应用进行了探讨。结果表明,重金属的迁移率大小依次为:Cd>Cu>Pb>Zn,Cd的酸可溶态占全量的比率高于其它重金属。Pb的酸可提取态浓度随土壤深度增加而增大,公路附近土壤中Pb、Cu及城市郊区土壤中Cd、Pb和Zn的氧化物结合态含量均随土壤深度的增加而升高,已存在向下迁移的趋势。4种重金属有机结合态在采样区土壤中基本都表现为耕层高于非耕层。研究表明,应用BCR连续提取法有助于确定土壤重金属污染以及重金属向下迁移状况,借助该法可以有效、可靠地对土壤重金属污染进行评估。
基金supported by the Nanjing Institute of Geography & Limnology, the Chinese Academy of Sciences(No.NIGLAS2011KXJ002)the National Basic Research Program (973) of China (No. 2010CB950201,2012CB956104)the National Natural Science Foundation of China (No. 40772204, 41072267)
文摘Reconstruction of trace metal pollution histories and sources may help us to regulate current pollutant discharge. This is especially important for the highland lakes in southwestern China, which are facing trace metals pollution. We present sedimentary records of 11 metals accumulated in Yangzong Lake since the 1870＇s, a highland lake in southwestern China. Pollution of lead and zinc （Pb and Zn） was differentiated based on principal component analysis, geochemical normalization, and lead isotope ratios. Nearly all the metals as well as grain size composition show generally constant values before the mid-1980＇s, denoting stable detrital input in the catchment. Fluctuations in the concentrations of the metals as well as grain size composition since the mid-1980＇s indicate an increase in soil erosion with strengthened human disturbance in the catchment. After geochemical normalization, Pb and Zn showed constant values before 1990 AD and then a gradual increase in parallel with the variations in 2~spb/~~6pb and 2~7pb/2~6pb ratios, indicating that Pb and Zn pollution occurred. Combining the data of 20PPb/206Ppb and 207Pb/206Pb ratios in the sediments of Yangzong Lake, leaded gasoline, Pb-Zn ore and coal, and consumption or production historical trends, we deduced that the enhanced Pb and Zn pollution in Yangzong Lake is caused primarily by ore mining and refining.
