A facile one-step co-precipitation method was demonstrated to fabricate amorphous sulfurcontaining calcium phosphate （SCP） nanoparticles, in which the sulfur group was in-situ introduced into calcium phosphate. The ...A facile one-step co-precipitation method was demonstrated to fabricate amorphous sulfurcontaining calcium phosphate （SCP） nanoparticles, in which the sulfur group was in-situ introduced into calcium phosphate. The resulting SCP exhibited a noticeable enhanced performance for Pb（II） removal in comparison with hydroxyapatite （HAP）, being capable of easily reducing 20 ppm of Pb（II） to below the acceptable standard for drinking water within less than 10 min. Remarkably, the saturated removal capacities of Pb（II） on SCP were as high as 1720.57 mg/g calculated by the Langmuir isotherm model, exceeding largely that of the previously reported absorbents. Significantly, SCP displayed highly selective removal ability toward Pb（II） ions in the presence of the competing metal ions （Ni（II）, Co（II）, Zn（II）, and Cd（II））. Further investigations indicated that such ultra-high removal efficiency and preferable affinity of Pb（II） ions on SCP may be reasonably ascribed to the formation of rodlike hydroxypyromorphite crystals on the surface of SCP via dissolution-precipitation and ion exchange reactions, accompanied by the presence of lead sulfide precipitates. High removal efficiency, fast removal kinetics and excellent selectivity toward Pb（II） made the obtained SCP material an ideal candidate for Pb（II） ions decontamination in practical application.展开更多
Based on the advantage of high surface area and strong adsorption ability of potassium hexatitanate whisker, a method to determine trace Pb(II) content by combining solid phase extraction with Flame atomic absorption ...Based on the advantage of high surface area and strong adsorption ability of potassium hexatitanate whisker, a method to determine trace Pb(II) content by combining solid phase extraction with Flame atomic absorption spectrometry (FAAS) was established. The adsorptive behavior of potassium hexatitanate whisker to Pb(II), primary influencing factors of adsorption and elution and effect of coexistence ions were investigated systemically. The optimal analytical conditions were discussed and examined. It was found that the adsorption rate of potassium hexatitanate whisker to Pb(II) was 100% at pH 4.0. Pb(II) could be eluted from potassium tetratitanate whisker with HCl (2mol/L) under boiling water for 30min. The detection limit was 5.75ng/mL, and relative standard deviation was 1.66% (n=9, CPb=2.0μg/mL).展开更多
In the present study we reported the feasibility of the Anethum graveolens as biosorbent to remove Pb(II) from aqueous solutions. Anethum graveolens was characterized by scanning electron microscopy and elemental anal...In the present study we reported the feasibility of the Anethum graveolens as biosorbent to remove Pb(II) from aqueous solutions. Anethum graveolens was characterized by scanning electron microscopy and elemental analysis. The ability of Anethum graveolens to adsorb Pb(II) was investigated by using batch adsorption procedure. The effects such as pH, contact time, adsorbate concentration and biosorbent dosage on the adsorption capacity were studied. The experimental data were analysed using various adsorption kinetic models viz., the pseudo-first and second-order equations, Bangham’s equation, intraparticle diffusion and Elovich models. Results show that the pseudo-second-order equation provides the best correlation for the biosorption process. The equilibrium nature of Pb(II) adsorption at 30℃ has been described by the Langmuir, Freundlich, Temkin and Redlich-Peterson isotherm models. The equilibrium data fit well on Langmuir isotherm. The monolayer adsorption capacity of Pb(II) onto Anethum graveolens as obtained from Langmuir isotherm at 30℃ was found to be 303 mg/g. This high adsorption capacity of Anethum graveolens places this biosorbent as one of the best adsorbents for removal of Pb(II) from aqueous effluents.展开更多
In this research dobera leaves (DL), an agricultural waste, available in large quantity in south region of Saudi Arabia, were used as low-cost adsorbent for removal of metal ions such as Pb(II). Batch operation was us...In this research dobera leaves (DL), an agricultural waste, available in large quantity in south region of Saudi Arabia, were used as low-cost adsorbent for removal of metal ions such as Pb(II). Batch operation was used to study the equilibrium behavior of DL. The effects of initial concentration of Pb(II), solution pH, contact time and adsorbent dose were evaluated. To study the kinetics of adsorption of Pb(II) onto DL, pseudo-first-order, pseudo-second-order and intra-particle diffusion were used. Adsorption process undergoes pseudo-second-order kinetic as proved by the high value of R2. Furthermore, to design the equilibrium data of adsorption of process, four adsorption isotherm models such as Langmuir, Freundlich Temkin and Dubinin-Radushkevich (D-R) were used. It is found that Langmuir equation has the highest value of R2 (0.999) compared with other models. In presences of a mixture of Pb(II)/Ni(II), DL were found to be selective for Pb(II) ions with a high adsorptive capacity of 83 mg/g and show favorable adsorption with RL < 1. In addition, preliminary results indicate that DL are very effective adsorbent for the removal of Pb(II) ions (>90%) from drinking water with less competition of other ions present in water.展开更多
This work examined the removal of Pb(II) using a chitosan derivative (SB, synthesized from benzaldehyde) assisted by a magnetic field. The adsorption capacity for Pb(II) was investigated. It was found that 1) the pH a...This work examined the removal of Pb(II) using a chitosan derivative (SB, synthesized from benzaldehyde) assisted by a magnetic field. The adsorption capacity for Pb(II) was investigated. It was found that 1) the pH and concentration of the ion solution, as well as exposure time and strength of magnetic field, affected the degree of adsorption;and 2) studies of the adsorption isotherms and kinetics of ions onto SB revealed that SB showed enhanced adsorption capacity towards Pb(II) ions in a magnetic field compared with magnetically untreated samples. The Langmuir and Freundlich isotherm were applied to describe the experimental adsorption, and the maximum adsorption capacity of SB for Pb(II) was 2.5040 mg/g, when assisted by a magnetic field of 480 kA/m.展开更多
Chemical compositions of natural zeolites, porcelanite (opal-CT) and local sands were determined by X-ray fluorescence (XRF) and correlated with their Pb(II) removal efficiencies. Zeolites and porcelanite were from th...Chemical compositions of natural zeolites, porcelanite (opal-CT) and local sands were determined by X-ray fluorescence (XRF) and correlated with their Pb(II) removal efficiencies. Zeolites and porcelanite were from the Mikawer, Aritain and Hannon areas in Jordan. Sands (white, red and yellow) were from the United Arab Emirates (UAE). The effect of Pb(II) concentration and zeolite dosage on removal efficiency was investigated at 25.0°C using the batch equilibrium method. Commercial kaolinite, silica and alumina were also studied for comparison. Removal efficiencies, in mg Pb(II)/g adsorbent, were: 76.9, 52.7 and 42.1 for Hannon, Mikawer and Aritain zeolites, respectively;58.2 for porcelanite;29.7, 11.0 and 8.5 for yellow, red and white sand, respectively;7.2, 3.3 and 1.3 for kaolinite, silica and alumina, respectively. XRF data indicate that adsorbents with intermediate molar ratios of Si/Al, in the range 2.70 - 2.93, are most efficient in Pb(II) removal. Scanning electron microscope (SEM) images of adsorbents suggest that morphology, in addition to chemical composition, plays a key role. In particular, a combination of factors, including shapes and sizes of crystals, channels in zeolites and pores in porcelanite, appear to favor removal of Pb(II).展开更多
In this study, the modified rice bran was tested to remove Pb(II) from water. Batch experiments were carried out to evaluate the adsorption characteristics of the modified rice bran for Pb(II) removal from aqueous sol...In this study, the modified rice bran was tested to remove Pb(II) from water. Batch experiments were carried out to evaluate the adsorption characteristics of the modified rice bran for Pb(II) removal from aqueous solutions. The adsorption isotherms, thermodynamic parameters, kinetics, pH effect, and desorbability were examined. The results show that the maximum adsorption capacity of the modified rice bran was approximately 70.8 mg Pb(II)/g absorbent at temperature of 25℃ and at the initial Pb(II) concentration of 400 mg/L and pH 7.0. And the adsorption isotherm data could be well fitted by both Langmuir equation and Freundlich equation. Thermodynamic studies confirmed that the process was spontaneous and endothermic. The adsorbed amounts of Pb(II) tend to increase with the increase of pH. The adsorption kinetic data can be satisfactorily described by either of the power functions and simple Elovich equations. The desorbability of Pb(II) is about 15-20%, and it is relatively difficult for the adsorbed Pb(II) to be desorbed. The relatively low cost and high capabilities of the rice bran make it potentially attractive adsorbent for the removal of Pb(II) from wastewater.展开更多
Influence of Hg(II) and Pb(II) ions on C-Phycocyanin (C-PC) from cyanobacteria Spirulina platensis was investigated using Fluorescence spectroscopy. Fluorescence measurements demonstrate quenching of C-PC emission by ...Influence of Hg(II) and Pb(II) ions on C-Phycocyanin (C-PC) from cyanobacteria Spirulina platensis was investigated using Fluorescence spectroscopy. Fluorescence measurements demonstrate quenching of C-PC emission by Hg(II) and Pb(II), and blue shifts in the fluorescence spectra. The effect of DNA on the fluorescence of Hg(II)-and Pb(II)-C-PC (from Spirulina platensis) complexes was also studied. It was shown that the fluorescence intensity of Hg-C-PC after addition of DNA gave rise to the fluorescence buildup. At the same time, addition of DNA to the Pb(II)-C-PC complexes showed no such effect. In the case of Hg(II)-C-PC, fluorescence intensity significantly decreases in time, while for Pb(II)-C-PC, decrease of the fluorescence intensity is not significant, but blue shift of the peak takes place.展开更多
文摘A facile one-step co-precipitation method was demonstrated to fabricate amorphous sulfurcontaining calcium phosphate （SCP） nanoparticles, in which the sulfur group was in-situ introduced into calcium phosphate. The resulting SCP exhibited a noticeable enhanced performance for Pb（II） removal in comparison with hydroxyapatite （HAP）, being capable of easily reducing 20 ppm of Pb（II） to below the acceptable standard for drinking water within less than 10 min. Remarkably, the saturated removal capacities of Pb（II） on SCP were as high as 1720.57 mg/g calculated by the Langmuir isotherm model, exceeding largely that of the previously reported absorbents. Significantly, SCP displayed highly selective removal ability toward Pb（II） ions in the presence of the competing metal ions （Ni（II）, Co（II）, Zn（II）, and Cd（II））. Further investigations indicated that such ultra-high removal efficiency and preferable affinity of Pb（II） ions on SCP may be reasonably ascribed to the formation of rodlike hydroxypyromorphite crystals on the surface of SCP via dissolution-precipitation and ion exchange reactions, accompanied by the presence of lead sulfide precipitates. High removal efficiency, fast removal kinetics and excellent selectivity toward Pb（II） made the obtained SCP material an ideal candidate for Pb（II） ions decontamination in practical application.
基金Science and Technical Department Innovation Fund and Graduate Student Innovation Project of Jiangsu Province.
文摘Based on the advantage of high surface area and strong adsorption ability of potassium hexatitanate whisker, a method to determine trace Pb(II) content by combining solid phase extraction with Flame atomic absorption spectrometry (FAAS) was established. The adsorptive behavior of potassium hexatitanate whisker to Pb(II), primary influencing factors of adsorption and elution and effect of coexistence ions were investigated systemically. The optimal analytical conditions were discussed and examined. It was found that the adsorption rate of potassium hexatitanate whisker to Pb(II) was 100% at pH 4.0. Pb(II) could be eluted from potassium tetratitanate whisker with HCl (2mol/L) under boiling water for 30min. The detection limit was 5.75ng/mL, and relative standard deviation was 1.66% (n=9, CPb=2.0μg/mL).
文摘In the present study we reported the feasibility of the Anethum graveolens as biosorbent to remove Pb(II) from aqueous solutions. Anethum graveolens was characterized by scanning electron microscopy and elemental analysis. The ability of Anethum graveolens to adsorb Pb(II) was investigated by using batch adsorption procedure. The effects such as pH, contact time, adsorbate concentration and biosorbent dosage on the adsorption capacity were studied. The experimental data were analysed using various adsorption kinetic models viz., the pseudo-first and second-order equations, Bangham’s equation, intraparticle diffusion and Elovich models. Results show that the pseudo-second-order equation provides the best correlation for the biosorption process. The equilibrium nature of Pb(II) adsorption at 30℃ has been described by the Langmuir, Freundlich, Temkin and Redlich-Peterson isotherm models. The equilibrium data fit well on Langmuir isotherm. The monolayer adsorption capacity of Pb(II) onto Anethum graveolens as obtained from Langmuir isotherm at 30℃ was found to be 303 mg/g. This high adsorption capacity of Anethum graveolens places this biosorbent as one of the best adsorbents for removal of Pb(II) from aqueous effluents.
文摘In this research dobera leaves (DL), an agricultural waste, available in large quantity in south region of Saudi Arabia, were used as low-cost adsorbent for removal of metal ions such as Pb(II). Batch operation was used to study the equilibrium behavior of DL. The effects of initial concentration of Pb(II), solution pH, contact time and adsorbent dose were evaluated. To study the kinetics of adsorption of Pb(II) onto DL, pseudo-first-order, pseudo-second-order and intra-particle diffusion were used. Adsorption process undergoes pseudo-second-order kinetic as proved by the high value of R2. Furthermore, to design the equilibrium data of adsorption of process, four adsorption isotherm models such as Langmuir, Freundlich Temkin and Dubinin-Radushkevich (D-R) were used. It is found that Langmuir equation has the highest value of R2 (0.999) compared with other models. In presences of a mixture of Pb(II)/Ni(II), DL were found to be selective for Pb(II) ions with a high adsorptive capacity of 83 mg/g and show favorable adsorption with RL < 1. In addition, preliminary results indicate that DL are very effective adsorbent for the removal of Pb(II) ions (>90%) from drinking water with less competition of other ions present in water.
文摘This work examined the removal of Pb(II) using a chitosan derivative (SB, synthesized from benzaldehyde) assisted by a magnetic field. The adsorption capacity for Pb(II) was investigated. It was found that 1) the pH and concentration of the ion solution, as well as exposure time and strength of magnetic field, affected the degree of adsorption;and 2) studies of the adsorption isotherms and kinetics of ions onto SB revealed that SB showed enhanced adsorption capacity towards Pb(II) ions in a magnetic field compared with magnetically untreated samples. The Langmuir and Freundlich isotherm were applied to describe the experimental adsorption, and the maximum adsorption capacity of SB for Pb(II) was 2.5040 mg/g, when assisted by a magnetic field of 480 kA/m.
文摘Chemical compositions of natural zeolites, porcelanite (opal-CT) and local sands were determined by X-ray fluorescence (XRF) and correlated with their Pb(II) removal efficiencies. Zeolites and porcelanite were from the Mikawer, Aritain and Hannon areas in Jordan. Sands (white, red and yellow) were from the United Arab Emirates (UAE). The effect of Pb(II) concentration and zeolite dosage on removal efficiency was investigated at 25.0°C using the batch equilibrium method. Commercial kaolinite, silica and alumina were also studied for comparison. Removal efficiencies, in mg Pb(II)/g adsorbent, were: 76.9, 52.7 and 42.1 for Hannon, Mikawer and Aritain zeolites, respectively;58.2 for porcelanite;29.7, 11.0 and 8.5 for yellow, red and white sand, respectively;7.2, 3.3 and 1.3 for kaolinite, silica and alumina, respectively. XRF data indicate that adsorbents with intermediate molar ratios of Si/Al, in the range 2.70 - 2.93, are most efficient in Pb(II) removal. Scanning electron microscope (SEM) images of adsorbents suggest that morphology, in addition to chemical composition, plays a key role. In particular, a combination of factors, including shapes and sizes of crystals, channels in zeolites and pores in porcelanite, appear to favor removal of Pb(II).
文摘In this study, the modified rice bran was tested to remove Pb(II) from water. Batch experiments were carried out to evaluate the adsorption characteristics of the modified rice bran for Pb(II) removal from aqueous solutions. The adsorption isotherms, thermodynamic parameters, kinetics, pH effect, and desorbability were examined. The results show that the maximum adsorption capacity of the modified rice bran was approximately 70.8 mg Pb(II)/g absorbent at temperature of 25℃ and at the initial Pb(II) concentration of 400 mg/L and pH 7.0. And the adsorption isotherm data could be well fitted by both Langmuir equation and Freundlich equation. Thermodynamic studies confirmed that the process was spontaneous and endothermic. The adsorbed amounts of Pb(II) tend to increase with the increase of pH. The adsorption kinetic data can be satisfactorily described by either of the power functions and simple Elovich equations. The desorbability of Pb(II) is about 15-20%, and it is relatively difficult for the adsorbed Pb(II) to be desorbed. The relatively low cost and high capabilities of the rice bran make it potentially attractive adsorbent for the removal of Pb(II) from wastewater.
文摘Influence of Hg(II) and Pb(II) ions on C-Phycocyanin (C-PC) from cyanobacteria Spirulina platensis was investigated using Fluorescence spectroscopy. Fluorescence measurements demonstrate quenching of C-PC emission by Hg(II) and Pb(II), and blue shifts in the fluorescence spectra. The effect of DNA on the fluorescence of Hg(II)-and Pb(II)-C-PC (from Spirulina platensis) complexes was also studied. It was shown that the fluorescence intensity of Hg-C-PC after addition of DNA gave rise to the fluorescence buildup. At the same time, addition of DNA to the Pb(II)-C-PC complexes showed no such effect. In the case of Hg(II)-C-PC, fluorescence intensity significantly decreases in time, while for Pb(II)-C-PC, decrease of the fluorescence intensity is not significant, but blue shift of the peak takes place.
